2,6-二硝基甲苯置于ruthenium On Carbon,氢气体系中,90.0 °C,1.5 Mpa 条件下,反应生成 2-甲基-3-硝基苯胺 参考文献:Selective Partial Hydrogenation Of Dinitrobenzenes To Nitroanilines Catalyzed By Ru/c 标题:Selective Partial Hydrogenation Of Dinitrobenzenes To Nitroanilines Catalyzed By Ru/c 摘要:发现ru/c是一种高效的催化剂,在温和条件下对一系列二硝基苯进行选择性部分氢化,得到相应的高选择性硝基苯胺.此外,本研究还探讨了二硝基苯的其他取代基对部分氢化的影响. DOI:10.1246/cl.2008.974
专利号:EP-1919850-B1 优先权日:2005-08-11 标题:Nitro substituted alpha-olefin synthesis catalysts 发明人:ADELMAN DOUGLAS J; IONKIN ALEX SEREGY 权利人:DU PONT 摘要:Iron, cobalt, chromium or vanadium complexes of 2,6-pyridinedicarboxaldehydes diimines and 2,6-diacylpyridines diimines which are suitable for catalyzing the oligomerization of ethylene to alpha-olefins exhibit more prolonged catalytic activity if aryl groups attached to the imino carbon atom(s) are substituted with at least one nitro group.
专利号:DE-202024103926-U1 优先权日:2024-07-13 标题 :Composition and system for the synthesis of zirconocene dichloride catalyst for the production of indiacene A and indiacene B
专利号:RU-2147579-C1 优先权日:1993-07-02 标题 :Derivatives of acylated aminophenylsulfonylurea and method of their synthesis
专利号:US-7696246-B2 优先权日:1999-08-27 标题:Bicyclic androgen and progesterone receptor modulator compounds and methods 发明人:ZHI LIN; VAN OEVEREN CORNELIS ARJAN; MARTINBOROUGH ESTHER 权利人:LIGAND PHARM INC 摘要:The present invention is directed to compounds, pharmaceutical compositions, and methods for modulating processes mediated by AR and PR. More particularly, the invention relates to nonsteroidal compounds and compositions that are high affinity, high specificity agonists, partial agonists (i.e., partial activators and/or tissue-specific activators) and antagonists for AR and PR. Also provided are methods of making such compounds and pharmaceutical compositions, as well as critical intermediates used in their synthesis.
专利号:CN-112778125-A 优先权日:2021-02-01 标题:A kind of aryl phenolic compound and its synthesis method and application
[参考文献]: C Faller, Et Al. Voltammetric Determination Of Ioxynil And 2-Methyl-3-Nitroaniline Using C(18) Modified Carbon Paste Electrodes. Anal Bioanal Chem. 1996 Sep;356(3-4):279-83. [参考文献]: P M Bradley, Et Al. Microbial Transformation Of Nitroaromatics In Surface Soils And Aquifer Materials. Appl Environ Microbiol. 1994 Jun;60(6):2170-5. [参考文献]: V I Kaledin, Et Al. [参考文献]: Dokl Akad Nauk. 1996 May;348(1):129-31.
合成参考文献
摘要:Joule, J. A., Science of Synthesis Knowledge Updates, (2010) 2, 176. 摘要:Sharma, U.; Kumar, R.; Gupta, S. S.; Chandra, D., Science of Synthesis Knowledge Updates, (2022) 2, 80. 参考文献:10.1107/s1600536810043461 摘要:Bingöl Alpaslan Y, Alaman Ağar A, Işık S. 1-[(E)-(2-Methyl-3-nitro-phen-yl)imino-meth-yl]-2-naphthol. Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 06;66(Pt 12):o3052.