CAS: 3404-61-3; 3-Methyl-1-Hexene

该化合物是一种含有分子式C7H14的分链烷,其特点是第一个碳的双联,第三个碳的甲基替代物的特征是二联,该化合物通常用作有机合成的中间体,特别是在特殊化学品,聚合物和香味的生产中.其结构具有终端高温的反活动特征,适合添加和聚合反应.分环烷链会增加消毒效应,影响催化工艺中的选择性.3-甲基丙烯-1-乙烯因其在标准条件下的适度波动和稳定性而得到估价,确保工业应用的一贯性.适当处理要求在惰性大气中储存防止过早聚合.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号106815-04-7 6-Iodo-3-methyl... | CAS号859183-70-3 2-ethoxy-1-brom... | CAS号592-44-9 1,2-Hexadiene | CAS号77-78-1 硫酸二甲酯 | CAS号107-81-3 2-溴戊烷 | CAS号917-57-7 vinyllithium | CAS号589-34-4 3-甲基己烷 | CAS号2550-21-2 3-甲基-2-己酮 | CAS号2313-65-7 3-甲基-2-己醇 | CAS号589-34-4 3-甲基己烷

合成工艺路线路线简述

    📜3-Methyl-Hexadien-(1,3)置于三乙醇胺,[ruii(2,2'-Bipyrazyl)2(4,4'-Dichloro-2,2'-Bipyridyl)]Cl2,Thermophilic Old Yellow Enzyme,Paraquat Dichloride体系中,用 乙醇,水 用作溶剂,化学反应 4.0H,以73%的收率获得3-甲基-1-己烯
    参考文献:Light-Driven Biocatalytic Reduction Of α,β-Unsaturated Compounds By Ene Reductases Employing Transition Metal Complexes As Photosensitizers
    标题:Light-Driven Biocatalytic Reduction Of α,β-Unsaturated Compounds By Ene Reductases Employing Transition Metal Complexes As Photosensitizers
    摘要:在工业规模生物氢化过程中,使用含有黄素辅酶的生物催化剂(如旧黄酶)时,高效且成本效益高的烟酰胺辅因子再生至关重要.
    Doi:10.1039/c5Cy01642H

    海关参考信息

    专利信息


    专利号:US-6444820-B1
    优先权日:1995-04-07
    标题:Process for the manufacture of camptothecin derivatives
    发明人:HENEGAR KEVIN E; SIH JOHN C
    摘要:This invention discloses and claims novel intermediates and procedures for the synthesis of camptothecin derivatives, such as irinotecan, and other compounds related to the synthesis of CPT-11. Related procedures and compounds are also disclosed, such as a novel method of making mappicine.

    专利号:US-10669160-B2
    优先权日:2018-04-30
    标题:Heterogeneous wet synthesis process for preparation of high purity tungsten pentahalide
    发明人:LIU YUMIN; LI FENG; WAN ZHIWEN; FAFARD CLAUDIA; WIESE STEFAN; HUSSON GUILLAUME; NIKIFOROV GRIGORY; SUI BIN; GIRARD JEAN-MARC
    权利人:AIR LIQUIDE; AIR LIQUIDE AMERICAN
    摘要:Synthesis of tungsten pentahalide compositions having low impurity profiles are disclosed. The specific impurity profile permits deposition of high purity tungsten-containing films using vapor deposition processes or other semiconductor manufacturing processes without introduction of performance-impacting contaminants.

    专利号:US-9080119-B2
    优先权日:2011-11-10
    标 题:Synthesis of high caloric fuels and chemicals including pentanol from coal, natural gas, and biomass
    发明人:HENRI JOHN; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT
    权利人:PIONEER ENERGY INC; Pioneer Energy
    摘要:In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.

    专利号:US-9611186-B2
    优先权日:2011-11-10
    标 题 :Synthesis of high caloric fuels and chemicals via ketene and diketene intermediates
    发明人:HENRI JOHN; ZYGMUNT JAN; BERGGREN MARK; ZUBRIN ROBERT
    权利人:PIONEER ENERGY INC; Pioneer Energy
    摘要:In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.

    专利号:US-9988349-B2
    优先权日:2014-01-03
    标 题:Direct stereospecific synthesis of unprotected aziridines from olefins
    发明人:ESS DANIEL HALSELL; FALCK JOHN RUSSELL; JAT JAWAHAR LAL; KURTI LASZLO
    权利人:ESS DANIEL HALSELL; FALCK JOHN RUSSELL; JAT JAWAHAR LAL; KURTI LASZLO
    摘要:A method for the direct stereospecific conversion of structurally diverse mono-, di-, tri- and tetra-substituted olefins to N—H, N-alkyl, N-cycloalkyl, or N-aralkyl aziridines using a hydroxylamine amination agent with transition metal catalyst. The method is operationally simple (i.e., one-pot), scalable and fast at ambient temperature.

    专利号:US-4061685-A
    优先权日:1975-02-07
    标题 :Catalytic synthesis of phenols
    发明人:WEIGERT FRANK JULIAN
    权利人:DU PONT
    摘要:A phenol is produced by heating water and a cyclic or acyclic alkane or alkene of 6-10 carbon atoms at a temperature of 350 DEG to 700 DEG C in the presence of a metal oxide catalyst. Exemplary is the heating of water and cyclohexane in a nitrogen atmosphere and in the presence of ZnO/TiO2 to produce phenol.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:The Synthesis Of α-Azidoesters And Geminal Triazides
    作者:Philipp Klahn,Hellmuth Erhardt,Andreas Kotthaus,Stefan F. Kirsch |发布日期:2014.7.21
    摘要:Representatives Of This Novel Class Of Triazide Compounds: Despite Their High Nitrogen Content, The Geminal Triazides Are Easy To Handle, Even When Preparative‐scale Syntheses Are Performed. (Caution: These Procedures Still Require Protective Measures!) The Triazides Are Now Broadly Available For Further Studies Regarding Their Properties And Reactivity. Furthermore, We Show How The Method Can Be Used To

    合成参考文献


    摘要:van Leeuwen, P. W. N. M., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 417.
    摘要:Bronger, R. P. J.; Kamer, P. C. J.; Vogt, D., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 1, 32.
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