CAS: 14916-80-4; Oct-3-Yn-1-Ol

相似化合物

31333-13-8 51721-39-2 1002-28-4

上下游产品

CAS号85217-50-1 2-(°Ct-3-yn-1-y... | CAS号109-65-9 正溴丁烷 | CAS号927-74-2 3-丁炔-1-醇 | CAS号17689-03-1 lithium,hex-1-yne | CAS号110-75-8 乙烯(2-氯乙基)醚 | CAS号75-21-8 环氧乙烷 | CAS号42332-01-4 sodium butylace... | CAS号16930-95-3 2-庚炔酸乙酯 | CAS号74-95-3 二溴甲烷 | CAS号14675-05-9 1-vinyloxy-°Ct-3-yne | CAS号107071-79-4 8-pyridin-3-ylo... | CAS号35153-15-2 (Z)-9-十四碳烯-1-醇 | CAS号111-87-5 正辛醇 | CAS号18185-81-4 3-°Cten-1-ol | CAS号871-91-0 7-辛炔-1-醇 | CAS号68274-97-5 5-十烯-1-醇 | CAS号67446-07-5 (Z)-5-癸烯-1-基乙酸酯 | CAS号139140-57-1 tert-butyl-[8-(... | CAS号100419-71-4 4-methylbenzene... | CAS号56578-18-8 反-5-癸烯-1-醇

2-(3-octyn-1-Yloxy)Tetrahydro-2H-Pyran置于对甲苯磺酸体系中,用 甲醇,水 用作溶剂,以86%的收率获得3-辛炔-1-醇
参考文献:铂催化内部炔烃的氢甲硅烷基化:利用取代基效应实现高区域选择性
标题:铂催化内部炔烃的氢甲硅烷基化:利用取代基效应实现高区域选择性
摘要:经验法则:描述高产率标题反应的重点是理解控制该过程的区域选择性的因素(请参阅方案).电子,空间和官能团的性质都影响选择性,对它的理解允许选择性地形成三取代的乙烯基硅烷,这是用于合成立体确定的烯烃的合成上有用的化合物.
Doi:10.1002/anie.201108714

专利信息

专利号:US-4391984-A
优先权日:1980-05-26
标 题 :Alkynyl halide compounds and alkenyl acetate compounds therefrom
发明人：ISHIHARA TOSHINOBU; YAMAMOTO AKIRA; TAGUCHI KENICHI
权利人:SHINETSU CHEMICAL CO
摘要:The invention provides a novel method for the synthetic preparation of an ω-haloalkyne compound of the general formula R--C.tbd.C--CH 2 ) n X, in which X is a halogen atom, R is a monovalent hydrocarbon group and n is 4, 5 or 6, by the coupling reaction of a Grignard reagent RMgX' and an ω-halo-1-bromoalkyne compound of the formula X--CH 2 ) n C.tbd.C-Br. The ω-haloalkyne compound obtained in the above can be readily converted to the corresponding alkenyl acetate of the formula R--CHâ•?CH--CH 2 ) n OCOCH 3 by first acetylating and then partially hydrogenating in the presence of a Lindlar catalyst. In particular, 7, 11-hexadecadienyl acetate, which is a sexual pheromone compound of a noxious insect, is obtained in the same route of synthesis starting with the Grignard reagent of a 1-halo-3-octene and 1, 8-dibromo-1-octyne.