CAS: 1192-62-7; 2-Acetylfuran

相似化合物

95091-92-2 27948-61-4 112653-32-4

上下游产品

diazomethane furfural furan acetic anhydride 2-furan-2-yl-hexan-2-ol 2-acetylfuran-2-furoylhydrazone (E)-N'-(1-(furan-2-yl)ethylidene)isonicotinic hydrazide 2-(2-furyl)-6-methyl-4-quinolinecarboxylic acid

2-(1-氯乙基)呋喃置于4Na(1+)*6H(1+)*nimo6O24(10-)=na4H6Nimo6O24,氧气体系中,用 水,乙腈 用作溶剂,20.0 °C,101.33 Kpa 条件下,反应 12.0H,以86%的收率获得2-乙酰基呋喃
参考文献:使用空气和无光敏剂的无机配位镍催化剂,在可见光驱动下对有机氯化物进行光催化氧化.
标题:使用空气和无光敏剂的无机配位镍催化剂,在可见光驱动下对有机氯化物进行光催化氧化.
摘要:通过可见光进行工程光氧化还原触发的化学转化已成为有机合成领域的新兴领域.但是,大多数成熟的光催化剂都是基于与贵金属和有机配体有关的过渡金属络合物或光敏有机染料,大大阻碍了可以提供更好的稳定性和耐久性的纯无机分子光催化剂的开发.在这里,我们发现安德森多金属氧酸盐(pom)na 4 [nimo 6 O 18(oh)6 ](1)由纯的无机骨架组成,该骨架由中心的ni Ii核构建而成,并由六个mo Vi O 6支撑.无机支架/配体,可用作强大的光催化剂.在可见光(> 400 Nm)照射下,该化合物可以高效催化多种反应,包括氯化物与胺的氧化交叉偶联反应,以及使用分子氧的氯化物氧化,从而提供多种亚胺,醛和酮,分别具有高选择性和高收率.由于具有强大的无机骨架,该催化剂在催化过程中表现出出色的稳定性和可重复使用性,而催化活性几乎没有损失,因此提供了一种无需使用复杂的有机配体和昂贵的贵金属基光敏剂的替代方案.
Doi:10.1002/cctc.201800629

专利信息

专利号:WO-9805658-A1
优先权日:1996-08-07
标 题 :Synthesis of 2-(2-furoyl)-4(5)-(2-furanyl)-1h-imidazole and analogs thereof
发明人：RHO TAIKYUN; LANKIN MICHAEL E; SHIH DAVID H; LANKIN CLAIRE M
权利人:ALTEON INC
摘要:The present invention relates to a practical and facile synthesis of 2-(2-furoyl)-4(5)-(2-furanyl)-1H-imidazole (FFI) and analogs thereof. The synthesis utilizes a novel hydrazinium salt as an intermediate reaction product which facilitates the isolation of purified product in high yields.

专利号:US-5856511-A
优先权日:1996-08-07
标题 :Synthesis of 2-(2-furoyl)-4(5)-(2-furanyl)-1H-imidazole and analogs thereof
发明人：RHO TAIKYUN; LANKIN MICHAEL E; SHIH DAVID H; LANKIN CLAIRE M
权利人:ALTEON INC
摘要:The present invention relates to a practical and facile synthesis of 2-(2-furoyl)-4(5)-(2-furanyl)-1H-imidazole (FFI) and analogs thereof. The synthesis utilized a novel hydrazinium salt as an intermediate reaction product which facilitates the isolation of purified product in high yields.

专利号:US-6080860-A
优先权日:1992-08-31
标 题:Methods of making ureas and guanidines including, terazosin, prazosin, doxazosin, tiodazosin, trimazosin, quinazosin and bunazosin (exemplary of 2-substituted quinazoline compounds), and meobentine, and bethanidine and intermediates therefor
发明人：KARIMIAN KHASHAYAR; MURTHY KESHAVA; HALL DARREN
权利人:BRANTFORD CHEMICALSS INC
摘要:Novel methods for the synthesis of substituted ureas and guanidines including Terazosin, Prazosin, Doxazosin, Tiodazosin, Trimazosin, Quinasin and Bunazosin (exemplary of 2-amino substituted Quinazolines), Meobentine and Bethanidine and novel intermediates suitable for use in such methods of synthesis are taught.

专利号:US-4803287-A
优先权日:1986-04-16
标题 :Certain photochromic fulgide compounds and method for their synthesis
发明人：HIBINO JUNICHI; ANDO EIJI
权利人:AGENCY IND SCIENCE TECHN
摘要:The invention provides a photochromic material characterized by an improvnt in balance of the substituents in the conventional furylfulgides and represented by the general formula: ##STR1## (wherein R represents an alkyl chain having 5 to 31 carbon atoms). According to this molecular structure, a mutually appropriate steric hindrance is induced between the isopropylidence group and the long-chain alkyl group to make the regio isomer unstable, thus preventing the regio isomer from being by-produced while also inhibiting any isomerization reaction from occuring in the synthesis of the fulgide. Further, a good balance of hydrophilic part and hydrophobic part is produced to facilitate formation of a Langmuir-Blodgett film.

专利号:US-2025179033-A1
优先权日:2021-12-30
标 题 :New antiviral triazole derivatives, their synthesis and their use for treatment of mammalian viral infections
发明人：MAKAROV VADIM; RIABOVA OLGA; LANE THOMAS R; EKINS SEAN
权利人:COLLABORATIONS PHARMACEUTICALS INC; FEDERAL RES CENTER FUNDAMENTALS OF BIOTECHNOLOGY RUSSIAN ACADEMY OF SCIENCE
摘要:A family of triazole derivatives is described. Also described is the use of these triazole derivatives in treating or preventing viral infections, such as human immunodeficiency virus (HIV) infections, and the diseases caused by these infections, such as acquired immunodeficiency syndrome (AIDS). The triazole derivatives, for example, comprise a central triazole group with two substituents comprising an aryl or heteroaryl group. Exemplary derivatives showed excellent HIV inhibitory activity against both wild-type and selected mutant strains of HIV.

专利号:US-9458021-B2
优先权日:2013-07-27
标 题 :Sol-gel method for synthesis of nano-porous carbon
发明人：MITRA SHANTANU
权利人:FARAD POWER INC
摘要:The present patent application discloses a novel sol-gel process to synthesize a nano-porous solid carbon material—suitable for use in electrodes in energy storage applications—from a combination of liquid reagents that undergo a polymerization reaction to form a matrix.