CAS: 88223-35-2; 2-Bromo-9,9-Dibutyl-9H-Fluorene

• 英文名称2-Bromo-9,9-Dibutyl-9H-Fluorene
• 中文名称2-溴-9,9-二丁基芴
• IUPAC名称2-bromo-9,9-dibutyl-9H-fluorene
• 其它别名2-Bromo-9,9'-Dibutylfluorene; 2-Bromo-9,9-Dibutylfluorene; 2-Bromo-9,9-Di-N-Butylfluorene; 2-Bromo-9,9-Dibutyl-9H-Fluorene; C21H25Br; 2-Bromo-9,9-Di-N-Butylfluoren; 2-Bromo-
• CAS编号88223-35-2
• MFCD编号:MFCD12031333
• EINECS号:835-327-5
• 分子式:C21H25Br分子量:357.33
• 产品CID: 1891640
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: AVCNDQUBVOMMSL-UHFFFAOYSA-N
• InChI=1S/C21H25Br/c1-3-5-13-21(14-6-4-2)19-10-8-7-9-17(19)18-12-11-16(22)15-20(18)21/h7-12,15H,3-6,13-14H2,1-2H3
• 计算化学: 氢键受体数*氢键供体数*可旋转键数6.0

物理性质

• 熔点55 °C
• 沸点434.6°C at 760 mmHg
• 闪点207.715 °C
• 密度1.175 g/cm3
• LogP:7.096
• 外观形态白色至几乎白色粉末至晶体
• 储存条件密封, 常温干燥保存

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Warning(警告)
• 危险描述H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• 危险品标志Xi

欧盟法规

上下游产品

合成工艺路线路线简述

• 15069-42-8 = 88223-35-2
  反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Acetone; 3 H,80 °C
  标题:Diphenylamino End-Capped Oligofluorenes With Enhanced Functional Properties For Blue Light Emission: Synthesis And Structure-Property Relationships
  作者:Li,Zhong Hui; Et Al
  参考文献:Chemistry - A European Journal 日期:2005 卷标:11(11) 页码:3285-3293]
  
  1133-80-8 = 88223-35-2
  反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Tetrabutylammonium Bromide Solvents: Dimethyl Sulfoxide,Water; Rt; 3 H,Rt
  标题:A Generic And Effective Strategy For Highly Effective "Intrinsic" Molecular Luminescence In The Condensed State
  作者:Zhu,Yakun; Et Al
  参考文献:Journal Of Materials Chemistry C: Materials For Optical And Electronic Devices 日期:2013 卷标:1(34) 页码:5277-5284]
  
  1133-80-8 + 26602-89-1 = 88223-35-2
  反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: Potassium Iodide Solvents: Dimethyl Sulfoxide; Rt -> 10 °C; 45 Min,10 °C; 10 °C -> 20 °C; Overnight,20 °C
  标题:Substitution Of Carbazole Modified Fluorenes As π-Extension In Ru(Ii) Complex-Influence On Performance Of Dye-Sensitized Solar Cells
  作者:Chandrasekharam,Malapaka; Et Al
  参考文献:Advances In Optoelectronics 日期:2011 卷标:963068]
  
  86-73-7 = 88223-35-2
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Dimethyl Sulfoxide
  标题:New Bithiazole-Functionalized Organic Photosensitizers For Dye-Sensitized Solar Cells
  作者:Lai,Lai-Fan; Et Al
  参考文献:Dyes And Pigments 日期:2013 卷标:96(2) 页码:516-524]
  
  86-73-7 = 88223-35-2
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Dimethyl Sulfoxide; Overnight,90 °C2.1 Reagents: N-Bromosuccinimide Solvents: Acetone; 3 H,80 °C
  标题:The Synthesis,Photophysical And Electrochemical Properties Of A Series Of Novel 3,8,13-Substituted Triindole Derivatives
  作者:Zhu,Tianhao; Et Al
  参考文献:Dyes And Pigments 日期:2012 卷标:95(3) 页码:679-688]
  
  86-73-7 = 88223-35-2
  反应条件:1.1 Reagents: Bromine Solvents: Dimethylformamide; 2 H,Cooled2.1 Reagents: Sodium Tert-Butoxide Solvents: Tetrahydrofuran; 12 H,Rt -> Reflux
  标题:Synthesis And Properties Of N-(9,9-Dibutyl-9H-Fluoren-2-Yl) Phenanthren-9-Amine
  作者:Liu,Hui
  参考文献:Guangzhou Huagong 日期:2015 卷标:43(16) 页码:114-115]
  
  86-73-7 = 88223-35-2
  反应条件:1.1 Reagents: Propylene Carbonate,N-Bromosuccinimide; 60 °C2.1 Reagents: Potassium Hydroxide,Potassium Iodide Solvents: Dimethyl Sulfoxide; 60 °C
  标题:Blue-Light-Emitting Multifunctional Triphenylamine-Centered Starburst Quinolines: Synthesis,Electrochemical And Photophysical Properties
  作者:Jiang,Peng; Et Al
  参考文献:Organic & Biomolecular Chemistry 日期:2012 卷标:10(24) 页码:4704-4711]
  
  15069-42-8 = 88223-35-2
  反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Acetone; Overnight,80 °C
  标题:Synthesis And Structure-Property Relationships Of Symmetric Ambipolar Quaterfluorene-Containing Oxadiazole As A Central Core And Diphenylamine As End-Capping Moieties
  作者:Yang,Fan; Et Al
  参考文献:Australian Journal Of Chemistry 日期:2008 卷标:61(7) 页码:541-546]
  
  15069-42-8 = 88223-35-2
  反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Acetone; 3 H,80 °C
  标题:The Synthesis,Photophysical And Electrochemical Properties Of A Series Of Novel 3,8,13-Substituted Triindole Derivatives
  作者:Zhu,Tianhao; Et Al
  参考文献:Dyes And Pigments 日期:2012 卷标:95(3) 页码:679-688]
  
  1133-80-8 = 88223-35-2
  反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Tetrabutylammonium Bromide Solvents: Dimethyl Sulfoxide,Water; 30 Min,0 °C1.2 6 H,Rt
  标题:Triindolo-Truxene Derivatives: Design,Synthesis,And Fine-Tuning Of Electronic Properties And Molecular Assembly Through Molecular Engineering
  作者:Chen,Jun-Bo; Et Al
  参考文献:Chemistry - A European Journal 日期:2019 卷标:25(5) 页码:1293-1299]
  
  1133-80-8 = 88223-35-2
  反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Benzyltriethylammonium Chloride,Tetrabutylammonium Chloride Solvents: Dimethyl Sulfoxide,Water; 12 H,100 °C
  标题:Novel Star-Shaped Triphenylamine-Based Molecular Glasses And Their Use In Ofets
  作者:Sonntag,Martin; Et Al
  参考文献:Chemistry Of Materials 日期:2005 卷标:17(11) 页码:3031-3039]
  
  1133-80-8 = 88223-35-2
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Dimethyl Sulfoxide; Rt -> 90 °C; 5 H,90 °C; 90 °C -> Rt1.2 Solvents: Water; Rt
  标题:Generation And Spectroscopic Profiles Of Stable Multiarylaminium Radical Cations Bridged By Fluorenes
  作者:Chang,Chao-Che; Et Al
  参考文献:Organic Letters 日期:2011 卷标:13(10) 页码:2702-2705]
  
  86-73-7 = 88223-35-2
  反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Dimethylformamide; 1 H,Rt2.1 Reagents: N-Bromosuccinimide Solvents: Propylene Carbonate; 57 °C; 30 Min,60 °C
  标题:A Study Of Two Thermostable Nlo Chromophores With Different π-Electron Bridges Using Fluorene As The Donor
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  参考文献:New Journal Of Chemistry 日期:2015 卷标:39(2) 页码:1038-1044]
  
  1133-80-8 = 88223-35-2 [标题:Reaction Conditions
  标题:Porphyrin Sensitizers With Modified Indoline Donors For Dye-Sensitized Solar Cells
  作者:Song,Heli; Et Al
  参考文献:Journal Of Materials Chemistry C: Materials For Optical And Electronic Devices 日期:2018 卷标:6(15) 页码:3927-3936]
  
  86-73-7 = 88223-35-2
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Dimethyl Sulfoxide; Overnight,90 °C2.1 Reagents: N-Bromosuccinimide Solvents: Acetone; 3 H,80 °C
  标题:Diphenylamino End-Capped Oligofluorenes With Enhanced Functional Properties For Blue Light Emission: Synthesis And Structure-Property Relationships
  作者:Li,Zhong Hui; Et Al
  参考文献:Chemistry - A European Journal 日期:2005 卷标:11(11) 页码:3285-3293]
  
  86-73-7 = 88223-35-2
  反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Propylene Carbonate; 2 Min,60 °C2.1 Reagents: Potassium Hydroxide Catalysts: Potassium Iodide Solvents: Dimethyl Sulfoxide; Rt; 1 H,Rt
  标题:A "Turn-On" Fluorescent Sensor For Ultrasensitive Detection Of Melamine Based On A New Fluorescence Probe And Aunps
  作者:Lu,Qiujun; Et Al
  参考文献:Analyst (Cambridge 日期:2015 卷标:140(4) 页码:1155-1160

海关参考信息

• 2902600000-乙苯
  2902700000-异丙基苯
  2901100000-饱和无环烃
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