CAS: 6651-36-1; (Cyclohex-1-En-1-Yloxy)Trimethylsilane

相似化合物

18448-47-0 22972-51-6 6838-67-1

上下游产品

CAS号75-77-4 三甲基氯硅烷 | CAS号108-94-1 环己酮 | CAS号27607-77-8 三氟甲磺酸三甲基硅酯 | CAS号63408-33-3 2-trimethylsily... | CAS号34880-70-1 1-甲氧基-1-三甲基硅基丙烯 | CAS号31469-15-5 1-甲氧基-2-甲基-1-(三... | CAS号14627-81-7 magnesium,2-met... | CAS号4071-88-9 三甲基硅乙酸乙酯 | CAS号16029-98-4 三甲基碘硅烷 | CAS号120-92-3 环戊酮 | CAS号1080-41-7 2-diethoxyphosp... | CAS号111729-78-3 2-[(4-bromophen... | CAS号3580-38-9 2-苯甲酰环己酮 | CAS号533-60-8 2-羟基环己酮 | CAS号124-04-9 己二酸 | CAS号108-94-1 环己酮 | CAS号930-68-7 环己烯酮 | CAS号53638-19-0 2-trimethylsily... | CAS号4883-67-4 2-硝基环己酮 | CAS号517-25-9 三硝基甲烷

2-溴环己酮置于(Trimethylsilyl)Manganese Pentacarbonyl体系中,化学反应 2.0H,以88%的收率获得产物1-环己烯氧基三甲基硅烷
参考文献:Reactions Of (Co)5Mnsi(Ch3)3 With .Alpha.-Bromo Carbonyl And Related Organic Compounds. Facile Reductive Silylation
标题:Reactions Of (Co)5Mnsi(Ch3)3 With .Alpha.-Bromo Carbonyl And Related Organic Compounds. Facile Reductive Silylation
摘要:
DOI:10.1021/jo00218A030

专利信息

专利号:US-5821387-A
优先权日:1997-12-22
标题 :Polyarenes from aryl ketones with application to synthesis of crisnatol mesylate
发明人：ARCHIBALD THOMAS G; BARNARD JAMES C; HUANG DER-SHING
权利人:AEROJET GENERAL CO
摘要:Alkyl-substituted polyarenes of the formula ##STR1## in which R is alkyl and Ar res is an aryl residue, are prepared from aryl ketones by reaction of the latter with 1-cyclohexenyloxytrimethylsilane in the presence of a Friedel-Crafts catalyst. When R is methyl and Ar res is a naphthyl residue, the reaction serves as a step in a reaction scheme leading to crisnatol mesylate, a pharmaceutical useful in the treatment of brain cancer.

专利号:US-5414074-A
优先权日:1992-09-25
标题:Synthesis of C-glycosylated compounds with the use of a mild, iodine-catalyzed reaction
发明人：KOREEDA MASATO; HOUSTON TODD A
权利人:UNIV MICHIGAN
摘要:The invention concerns C-glycosylated derivatives of soft carbon nucleophile compounds, particularly compounds which contain acid-labile structural units. The invention further concerns a mild, cost-effective, non-hazardous and stereoselective method of general application employing a glycal as a glycosyulating agent and iodine as a catalyst for the preparation of C-glycosylated soft carbon nucleophile compounds.

专利号:EP-1756029-B1
优先权日:2004-04-08
标 题:Novel compounds, the preparation and the use thereof for a regiospesific synthesis of perfluor(alkyl) group heterocycles
发明人：EL KHARRAT SALEM; LAURENT PHILIPPE; BLANCOU HUBERT
权利人:CENTRE NAT RECH SCIENT; UNIV MONTPELLIER II
摘要:The invention relates to compounds of formula (1), wherein Z is a hydrogen or halogen atom; R'F is a perfluoroalkyl group CnF2n+1 in which n is an integer ranging from 1 to 12; R is in an ortho, meta or para position and represents an electron donor group, an electron attracting group, an aryl group or a heteroaryl group with the provision that R is an aryl or a heteroaryl. A method for preparing the inventive compounds (1) and a method for preparing heterocyclic compounds therefrom are also disclosed.

专利号:SU-1735300-A1
优先权日:1990-01-22
标题 :Method for synthesis of s-trimethylsilyl esters of dithio- or tetrathiophosphoric acids

专利号:WO-9407899-A1
优先权日:1992-09-25
标 题:Synthesis of c-glycosylated compounds with the use of a mild, iodine-catalyzed reaction

专利号:WO-2005102980-A1
优先权日:2004-04-08
标题 :Novel compounds, the preparation and the use thereof for a regiospesific synthesis of perfluor(alkyl) group heterocycles