CAS: 615-36-1; 2-Bromoaniline

上下游产品

CAS号577-19-5 邻溴硝基苯 | CAS号244205-40-1 2-溴苯硼酸 | CAS号915920-68-2 2-(2-bromopheno... | CAS号15426-16-1 2,2’-二溴偶氮苯 | CAS号1164112-16-6 2-(2-bromopheny... | CAS号583-53-9 1,2-二溴苯 | CAS号3302-39-4 1-Azido-2-bromo... | CAS号6165-68-0 2-噻吩硼酸 | CAS号71687-81-5 N-Benzyl-2-brom... | CAS号111400-80-7 2-(2-bromopheny... | CAS号106183-35-1 2-(2-bromopheny... | CAS号1072901-09-7 N1-(2-(二甲基氨基)苯基... | CAS号108238-11-5 4-(4-aminopheny... | CAS号106047-18-1 2-吡啶-4-苯胺 | CAS号10448-07-4 Benzenediazoniu... | CAS号104988-73-0 2-(3-Quinolinyl... | CAS号104919-70-2 ethyl N-(2-brom... | CAS号106183-47-5 2-diazonio-1-(2... | CAS号574-39-0 9-乙酰基咔唑

邻碘溴苯置于2,2'-联吡啶,Sodium Azide,水,Palladium Diacetate,N,N-二异丙基乙胺体系中,用 二甲基亚砜 作为反应溶剂,以42 %的收率获得产物2-溴苯胺
参考文献:Photoexcitation Of Distinct Divalent Palladium Complexes In Cross‐coupling Amination Under Air
标题:Photoexcitation Of Distinct Divalent Palladium Complexes In Cross‐coupling Amination Under Air
摘要:摘要开发兼具光催化剂和交叉偶联催化剂功能的金属配合物仍然是一个具有挑战性的研究课题.迄今为止,钯(0)激发态过渡金属催化碳-碳键构建的研究已取得进展,在室温下可实现烷基/芳基卤化物与零价钯(pd0)的氧化加成.相比之下,二价钯(pdii)的类似过程则是上坡和内热的.我们首次报道了二价钯可以作为光吸收物种,在空气中经过双重激发实现碳-氮(c-N)交叉耦合.利用醋酸钯作为光催化剂和交叉偶联催化剂,可在室温下将不同取代的芳基卤化物用于温和的选择性交叉偶联胺化反应.密度泛函理论研究和机理研究有助于深入了解反应机理.
DOI:10.1002/anie.202314508

专利信息

专利号:US-11873305-B2
优先权日:2020-06-30
标题 :Processes for synthesis of substituted indole intermediates for the synthesis of serd compounds
发明人：ZHANG HAIMING; XU JIE; WUITSCHIK GEORG; ANGELAUD REMY; HEROLD SEBASTIAN; STUTZ ALFRED; BRUETSCH TOBIAS; BURKHARD JOHANNES
权利人:GENENTECH INC; HOFFMANN LA ROCHE
摘要:Provided herein are processes for the preparation of indolyl intermediates using Wenker Synthesis for the total synthesis of SERD compounds useful in the treatment of cancer.

专利号:US-7713446-B2
优先权日:2004-06-28
标 题:Synthesis of nanofibers of polyaniline and substituted derivatives
发明人：EPSTEIN ARTHUR J; CHIOU NAN-RONG
权利人:OHIO STATE UNIVERISTY
摘要:Novel, simple methods are presented directed to the synthesis of nanofibers of polyaniline and substituted derivatives. The production of these fibers is achieved via various methods by controlling the concentration of aniline monomer or substituted aniline derivatives or an oxidant in the reaction medium and maintaining said concentration at a level much lower than conventional polyaniline synthesis methods. Methods are disclosed relating to the use of a permeable membrane to control the release of a monomer and/or oxidant as well as a bulk polymerization method.

专利号:US-10487070-B2
优先权日:2016-04-13
标 题:Process for preparing intermediates useful in the synthesis of antifungal drugs
发明人：BERTOLINI GIORGIO; COLLI CORRADO; SADA MARA; COLOMBO FEDERICA
权利人:OLON SPA; OLSON S P A
摘要:Subject-matter of the invention is a process for preparing intermediates useful in the synthesis of drugs, for example antifungal drugs, such as efinaconazole. Subject-matter of the invention are also such novel synthesis intermediates and the use thereof.

专利号:WO-9410327-A1
优先权日:1992-10-28
标 题 :Enzymatic synthesis of polyaniline
发明人：ZEMEL HAYA; QUINN JOHN F
权利人:ALLIED SIGNAL INC
摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.

专利号:US-5420237-A
优先权日:1991-08-29
标 题:Enzymatic synthesis of polyaniline
发明人：ZEMEL HAYA; QUINN JOHN F
权利人:ALLIED SIGNAL INC
摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.

专利号:US-6737504-B2
优先权日:2001-07-30
标 题 :Synthesis of substituted poly(aniline)s
发明人：FREUND MICHAEL S; SHOJI EIICHI
权利人:CALIFORNIA INST OF TECHN
摘要:A method for preparing a wide range of substituted poly(aniline)s from a single precursor is described. The method uses a variety of reactions, including a boron activation/electrophilic displacement reaction resulting in ipso-substitution. The ability to tune the properties of poly(aniline) through the generation of new structures is useful in numerous fields ranging from polymer-based electronics to sensors.