CAS: 54039-38-2; Bis(Pentamethylcyclopentadienyl)Zirconium(Iv) Dichloride
该化合物是一个过渡性金属复合体,其特点是为核心金属原子,其特征为二甲基环戊二烯基(Cp*),其二甲基环戊二烯基(Cp*)具有大容量和电子含量,具有重要的消毒和电子效应,二氯化物成分表明存在两颗氯化离子,与中心协调.该复合体通常用于有机金属化学和催化,特别是用于聚醚聚合过程,因为它能够激活和稳定反应性中间体.Cp* 的悬浮性大部分悬浮能增强该复合体的稳定性并影响其再活性.此外,该化合物的特点往往是其溶性在有机溶剂中,因此适合各种合成应用.其独特的结构和特性使它在先进材料的开发以及金属-硬性相互作用的研究中成为有价值的前体.
- 英文名称Bis(Pentamethylcyclopentadienyl)Zirconium(Iv) Dichloride
- 中文名称十甲基二茂二氯化锆
- 其它别名Bis(1,2,3,4,5-pentamethylcyclopentadienyl)zirconiumdichloride; Bis(pentamethylcyclopentadienyl)zirconium dichloride; Bis(h5-pentamethylcyclopentadienyl)zirconiumdichloride; Decamethylzircon°Cene dichloride; Dichlorobis(pentamethylcyclopentadienyl)zirconium; Dichlorobis(h5-pentamethylcyclopentadienyl)zirconium
- CAS编号54039-38-2
- MFCD编号:MFCD00058849
- EINECS号:621-254-4
- 分子式:C20H30Cl2Zr分子量:432.58
- 产品CID: 2502098
- 产品分类有机原料 → 有机金属类化合物 → 有机锆
物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS05;
注释: Corrosion - 危险类别皮肤腐蚀 类别1B
严重眼损伤 类别1
金属腐蚀物 类别1
急性毒性 类别4(吸入)
急性毒性 类别4(经皮)
急性毒性 类别4(经口)
皮肤腐蚀 类别1C - 警示词Danger(危险)
- 危险描述H314 |造成严重皮肤灼伤和眼损伤.
H318 |造成严重眼损伤.
H290 |可能对金属造成腐蚀.
H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害. - 防范说明P260h-P301+P330+P331-P303+P361+P353-P305+P351+P338-P501a-P234-P260-P264-P270-P271-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501
- 危险等级8
- UN编号UN 3261 8/PG 2
- 危险品标志C
- 包装等级II
- 安全声明26-36/37/39-45
- 危险类别码34
- WGK Germany3
欧盟法规
C&L通报上下游产品
CAS号10026-11-6 四氯化锆 | CAS号116437-00-4 Cp'2Zr(°CH2CF3)2 | CAS号116436-98-7 Cp'2Zr(°C6F5)2 | CAS号51905-34-1 五甲基环戊二烯锂 | CAS号67108-80-9 双(五甲基环戊二烯基)二甲基锆(IV)合成工艺路线路线简述
专利信息
专利号:US-2008086013-A1
优先权日:2006-06-15
标 题:Carbometallation of alkynes and improved synthesis of uniquinones
发明人：LIPSHUTZ BRUCE H
权利人:UNIV CALIFORNIA
摘要:Methods for the carbometallation of alkynes are presented. Those are useful for the synthesis of CoQ 10 and other ubiquinones as well as for the synthesis of ubiquinol analogs.
专利号:US-2006167289-A1
优先权日:2003-12-05
标题 :Practical, cost-effective synthesis of ubiquinones
发明人：LIPSHUTZ BRUCE H; BERL VOLKER; SCHEIN KARIN; WETTERICH FRANK
权利人:ZYMES LLC
摘要:The present invention provides a convergent method for the synthesis of ubiquinones and ubiquinone analogues. Also provided are precursors of ubiquinones and their analogues that are useful in the methods of the invention. The invention further provides an improved method for the carboalumination of alkyne substrates.
专利号:WO-2023113033-A1
优先权日:2021-12-16
标题 :Gas diffusion electrode
发明人：KONDO SHOICHI; MAEDA SHINICHI; SHIGA NORIHITO
权利人:NISSAN CHEMICAL CORP
摘要:[Problem] The present invention addresses the problem of increasing the rate of reaction by controlling ammonium ions, which are generated by ammonia as the objective of the electrolytic synthesis of ammonia and protons that are supplied to the cathode, by means of the cathode and the cathode catalyst layer. [Solution] The present invention provides a gas diffusion electrode which is integrated with a catalyst layer that uses a material selected from the group consisting of cathode catalyst layer materials. Examples of the cathode catalyst layer materials include a fired body and an ionic liquid.
专利号:US-2009131705-A1
优先权日:2005-12-15
标 题 :Practical, Cost-Effective Synthesis of Ubiquinones
专利号:WO-2007078679-A2
优先权日:2005-12-15
标 题:Practical, cost-effective synthesis of ubiquinones
专利号:JP-4120709-B2
优先权日:1995-11-07
标 题:Synthesis of organic diurethanes and / or polyurethanes and their use for the production of diisocyanates and / or polyisocyanates
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1134/s0023158412040118
摘要:Sigaeva NN, Friesen AK, Nasibullin II, Ermolaev NL, Kolesov SV. Metallocene catalysis in the complex-radical polymerization of methyl methacrylate. Kinetics and Catalysis. 2012 Jul 26;53(4):470–6. doi: 10.1134/s0023158412040118.
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