CAS: 38641-94-0; Glyphosate (Isopropylammonium)

该化合物是一种广泛使用的除草剂,主要以其活性成分 ----甘草酸盐 ----闻名于世,其特征是它对哺乳动物和鸟类的毒性较低,但它引起了环境和健康方面的关注,导致人们不断辩论其安全和潜在致癌影响.该物质在水中溶解,可以有效地应用于各种配方,包括液体浓缩物和颗粒.此外,甘草的功效可能受到诸如pH,温度和表面活性剂在配方中的存在等因素的影响,这些因素增加了植物组织的吸收.

结构式图片

相似化合物

1071-83-6 5994-61-6 285978-24-7

欧盟法规

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CAS号1071-83-6 草甘膦 | CAS号75-31-0 异丙胺

合成工艺路线路线简述

  • 合成目标产物 N-(Phosphonomethyl)Glycine 2-Propylamine (1:1) 主要起始原料 Glyphosate And Isopropylamine
  • (文献来源)合成步骤主要原料 Glyphosate 和 Isopropylamine
草甘膦,异丙胺 以 水 作为反应溶剂,化学反应 0.5H,以99%的收率获得产物草甘膦异丙胺盐
参考文献: Method For The Synthesis Of N-(Phosphonomethyl)Glycine[fr] Procédé De Synthèse De N-(Phosphonométhyl)Glycine
标题: Method For The Synthesis Of N-(Phosphonomethyl)Glycine[fr] Procédé De Synthèse De N-(Phosphonométhyl)Glycine
摘要:本发明涉及一种合成n-(膦甲基)甘氨酸或其所选衍生物(包括其盐,膦酸酯或膦酸酯盐)的方法,其中包括以下步骤: • A)在酸催化剂的存在下,形成反应混合物,该混合物包括2,5-二酮哌嗪,甲醛和一种包含一个或多个p-O-P酐基团的化合物,该酐基团具有一个p原子在氧化状态(+ Iii)和另一个p原子在氧化状态(+ Iii)或(+ V),以形成n,N'-双膦甲基-2,5-二酮哌嗪,其单至四膦酸酯,N,N'-双膦甲基-2,5-二酮哌嗪的脱水形式以及其脱水形式的膦酸酯; • B)水解所述的n,N'-双膦甲基-2,5-二酮哌嗪,其脱水形式或其膦酸酯,以获得n-(膦甲基)甘氨酸或其所选衍生物(包括其盐,膦酸酯和膦酸酯盐).

海关参考信息

专利信息


专利号:US-9999223-B2
优先权日:2008-05-21
标 题 :Herbicidal composition comprising glyphosate, glufosinate or their salts
发明人:SIEVERNICH BERND; MOBERG WILLIAM KARL; SIMON ANJA; WALTER HELMUT; EVANS RICHARD R
权利人:BASF SE
摘要:The present invention relates to a herbicidal composition which comprises:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, and b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone]. nn The present invention relates in particular to a herbicidal composition comprising:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone], and c) at least one further herbicide C, which is selected from the herbicide groups C.1 to C.8:n C.1 herbicides of the group of acetolactate synthase inhibitors (ALS inhibitors), C.2 herbicides of the group of protoporphyrinogen oxidase inhibitors (PPO inhibitors), C.3 herbicides of the group of auxines, C.4 herbicides of the group of 4-hydroxyphenyl-pyruvate-dioxygenase inhibitors (HPPD inhibitors), C.5 herbicides of the group of phytoene desaturase inhibitors (PDS inhibitors), C.6 herbicides of the group of photosystem II inhibitors (PSII inhibitors), C.7 herbicides of the group of microtubulin inhibitors, and C.8 herbicides of the group of inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors).

专利号:US-7375058-B2
优先权日:2001-09-14
标 题:Herbicidal mixtures based on 3-phenyluracils
发明人:ZAGAR CYRILL; SIEVERNICH BERND; QUAKENBUSH LAURA; EVANS RICHARD R; LANDES MAX; NEWSOM LARRY J; ORTLIP CHARLES L; WITSCHEL MATTHIAS; LANDES ANDREAS
权利人:BASF AG
摘要:Herbidically active compositions, comprising: A) at least one phenyluracil compound of the formula (I); in which the variables R 1 -R 7 are as defined in the claims, and/or at least one of its agriculturally acceptable salts; and at least one further active compound, selected from B) herbicides of classes b1) to b15): b1) lipid biosynthesis inhibitors; b2) acetolactate synthase inhibitors (ALS inhibitors); b3) photosynthesis inhibitors; b4) protoporphyrinogen-IX oxidase inhibitors; b5) bleacher herbicides; b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7) glutamine synthetase inhibitors; b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9) mitose inhibitors; b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11) cellulose biosynthesis inhibitors; b12) decoupler herbicides; b13) auxin herbicides; b14) auxin transport inhibitors; b15) other herbicides selected from the group consisting of benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin, methyldymron, etobenzanid, fosamine, metam, pyributicarb, oxaziclomefone, dazomet, triaziflam and methyl bromide; and safeners selected from: benoxacor, cloquintocet, cyometrinil, dichlormid, dicyclonon, dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, mefenpyr, mephenate, naplithalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane and oxabetrinil, the agriculturally acceptable salts of the active compounds B and C and the agriculturally acceptable derivatives of the active compounds B and C, provided they have a carboxyl group

专利号:US-2010190794-A1
优先权日:2007-06-12
标 题:Herbicidally Active Composition
发明人:HUPE EIKE; MOBERG WILLIAM KARL; REINHARD ROBERT; SIEVERNICH BERND; KIBLER ELMAR
权利人:BASF SE
摘要:The present invention relates to herbicidally active compositions comprising at least one piperazinedione compound of the formula I n n n n n n n n n n n n in which: n R x , R y are each hydrogen or together are a chemical bond; n R 1 is cyano or nitro; n R 2 is hydrogen, fluorine, chlorine, C 1 -C 2 -alkyl, ethenyl or C 1 -C 2 -alkoxy; n R 3 is fluorine or hydrogen; n R 4 is methyl; n R 5 is hydrogen, methyl or ethyl; n R 6 is hydrogen, methyl or ethyl; and n R 7 is hydrogen or halogen; n and at least one further active compound selected from the group consisting of n b1) lipid biosynthesis inhibitors; n b2) acetolactate synthase inhibitors (ALS inhibitors); n b3) photosynthesis inhibitors; n b4) protoporphyrinogen-IX oxidase inhibitors, n b5) bleacher herbicides; n b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); n b7) glutamine synthetase inhibitors; n b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); n b9) mitose inhibitors; n b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); n b11) cellulose biosynthesis inhibitors; n b12) decoupler herbicides; n b13) auxin herbicides; n b14) auxin transport inhibitors; n b15) other herbicides, and n C) safeners.

专利号:WO-2020126584-A1
优先权日:2018-12-18
标 题 :Herbicidal combinations
发明人:KRAUS HELMUT; ZAGAR CYRILL; SEISER TOBIAS; BESSAI JOHANNES; DIMITRIADI TATJANA; BLAKEN MATTHEW; LANDES ANDREAS; GRIVEAU YANNICK; REID DANIELLE; VAN THIELEN NOCHA; BROWN JEFFREY; PETERS JDAVID
权利人:BASF AGROCHEMICAL PRODUCTS BV
摘要:The present invention relates to herbicidally active combinations comprising a herbicide A and at least one herbicide B, wherein the herbicide A is R-imazamox, any non-racemic mixture of R- imazamox and S-imazamox, wherein the proportion of R-imazamox is at least 80% by weight, or an agriculturally acceptable salt or ester thereof; and the at least one herbicide B is selected from the groups b1) to b15): b1)lipid biosynthesis inhibitors; b2)acetolactate synthase inhibitors (ALS inhibitors); b3)photosynthesis inhibitors; b4)protoporphyrinogen-IX oxidase inhibitors; b5)bleacher herbicides; b6)enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7)glutamine synthetase inhibitors; b8)7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9)mitosis inhibitors; b10)inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11)cellulose biosynthesis inhibitors; b12)decoupler herbicides; b13)synthetic auxins; b14)auxin transport inhibitors; and b15)other herbicides.

专利号:US-2021163451-A1
优先权日:2018-05-16
标题:Methods and compositions for substituted 2,5-diketopiperazine analogs
发明人:DING YOUSONG; JIANG GUANGDE
权利人:UNIV FLORIDA
摘要:Thaxtomins are phytotoxic secondary metabolites produced in plant pathogenic Streptomyces strains and have received considerable interests as bioherbicides. A cell-free, biocombinatorial approach was developed to produce a thaxtomin library for herbicide development. Combination of biosynthetic enzymes led to the production of 136 substituted 2,5-diketopiperazines, thaxtomin D, thaxtomin B and thaxtomin A analogs in a single pot. Furthermore, rational engineering of TxtA allowed the synthesis of azido-containing thaxtomin analog. Selected unnatural thaxtomins demonstrated improved herbicidal activities. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

专利号:UA-101891-C2
优先权日:2011-10-31
标题 :ELECTRIC DISCHARGE METHOD FOR SYNTHESIS OF CARBON NANOMATERIALS
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合成参考文献


摘要:Yakkyoku. Pharmacy., 36(387), 1985
摘要:O'Neil, M.J. (ed.). The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. Cambridge, UK: Royal Society of Chemistry, 2013., p. 834
摘要:Goldfrank, L.R., Goldfrank's Toxicologic Emergencies 9th Ed. 2011., McGraw-Hill, New York, N.Y., p. 1508
摘要:
摘要:Tomlin CDS, ed. Glyphosate (1071-83-6). In: The e-Pesticide Manual, 13th Edition Version 3.2 (2005-06). Surrey UK, British Crop Protection Council.
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