4,4,4-Trifluoro-1-(2-Thienyl)-1,3-Butanedione Enol 以 水 用作溶剂,化学反应生成2-噻吩甲酰三氟丙酮 参考文献:The Reactions Of Zinc(II) With 1,3-Diketones In Aqueous Solution. Catalysis By Cacodylic Acid During Complex Formation 标题:The Reactions Of Zinc(II) With 1,3-Diketones In Aqueous Solution. Catalysis By Cacodylic Acid During Complex Formation 摘要:The Reactions Of Zinc(II) With Three 1,3-Diketones Have Been Investigated In Aqueous Solution At 25-Degrees-C And An Ionic Strength Of 0.5 Mol Dm-3 Naclo4. The Catalytic Effect Of Cacodylic Acid On The Reactions Of Zinc(II) With Pentane-2,4-Dione Has Been Demonstrated. In Addition,The Effect Of Cacodylic Acid On The Hydrolysis Of The Nickel(II) And Copper(II) Triglycine Complexes Has Been Investigated. Doi:10.1039/dt9930000313
专利号:WO-2014197940-A1 优先权日:2013-06-12 标题 :One step assembly of metal-polyphenol complexes for versatile film and particle engineering 发明人:CARUSO FRANK; EJIMA HIROTAKA; RICHARDSON JOSEPH JACOB; VAN KOEVERDEN MARTIN PETER 权利人:UNIV MELBOURNE 摘要:Engineered articles have a wide variety of applications due to the ability to vary their properties by variations in the functionality of the layers in the article walls and in the material (if any) contained in the core of the article. In particular, articles of this type such as capsules are of significant interest for a number of applications especially in the medical field where they have found to have uses as vehicles for drug and vaccine delivery. In addition the capsules have potential applications as diagnostics and in bio sensing research. The present invention relates to an improved method of forming a film or network on a substrate from contacting said substrate with a polyphenol compound and a metallic cation or a mixture of metallic cations for less than 30 minutes, which method can be utilised for the rapid synthesis of articles of this type.
专利号:US-2025051642-A1 优先权日:2021-12-16 标 题 :Microjet reactor based synthesis of nanophosphors 发明人:BERENDS ANNE CLAIRE; VAN DE HAAR MARIE ANNE; WERNER JAN; KRATZ NADJA; VETTER STEFAN; NICKEL ALENA; VOLK CAROLINE 权利人:SEABOROUGH IP I B V 摘要:There is provided a method of making luminescent nanoparticles of the type A2-xO3:Lnx, wherein A is one or more of yttrium, scandium, aluminium, gallium, or a lanthanide; Ln is at least one lanthanide; and 0 专利号:US-9650621-B2 优先权日:2012-10-12 标 题:Proteolytic inactivation of select proteins in bacterial extracts for improved expression 发明人:THANOS CHRISTOPHER D; MURRAY CHRISTOPHER J; YANG JUNHAO; STEPHENSON HEATHER 权利人:SUTRO BIOPHARMA INC 摘要:The present disclosure provides modified proteins that are capable of being cleaved by the protease OmpT1. The proteins can be modified in an exposed surface motif to incorporate OmpT1 cleavage sites. Also provided are nucleic acids encoding the modified proteins, bacterial cells that express the modified proteins, and cell free synthesis systems containing modified RF1. The disclosure further provides methods for reducing the deleterious activity of a modified protein in a cell free synthesis system by contacting the modified protein with OmpT1. Also provided are methods for reducing RF1 competition at an amber codon in the cell free synthesis system, and methods for expressing a protein in the cell free synthesis system. The modified proteins of the invention can be used to increase the yield of proteins having non-natural amino acids incorporated at an amber codon.
专利号:US-6407103-B2 优先权日:1998-04-21 标 题:Indeno [1,2-c] pyrazol-4-ones and their uses 发明人:NUGIEL DAVID A; CARINI DAVID J; DI MEO SUSAN V; YUE EDDY W 权利人:BRISTOL MYERS SQUIBB PHARMA CO 摘要:The present invention relates to the synthesis of a new class of indeno[1,2-c]pyrazol-4-ones of formula (I):that are potent inhibitors of the class of enzymes known as cyclin dependent kinases, which relate to the catalytic subunits cdk1-9 and their regulatory subunits know as cyclins A-H.This invention also provides a novel method of treating cancer or other proliferative diseases by administering a therapeutically effective amount of one of these compounds or a pharmaceutically acceptable salt form thereof. Alternatively, one can treat cancer or other proliferative diseases by administering a therapeutically effective combination of one of the compounds of the present invention and one or more other known anti-cancer or anti-proliferative agents.
专利号:US-7687635-B2 优先权日:2002-01-22 标 题:Metal complexes useful in metathesis and other reactions 发明人:VERPOORT FRANCIS WALTER CORNELIUS; DE CLERCQ BOB 权利人:TELENE S A S 摘要:This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.
专利号:EP-4198105-A1 优先权日:2021-12-16 标 题:Microjet reactor based synthesis of nanophosphors
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合成参考文献
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