CAS: 286-28-2; 7-Thiabicyclo[4.1.0]Heptane

该化合物是一个双环有机化合物,其独特结构的特征是,在双环框架内含有硫磺原子;该化合物的特点是七人环状系统,其中碳原子之一被硫磺原子取代,使其具有独特性能;硫磺原子的存在可以影响该化合物的再活性和稳定性,使其往往比其仅含碳的对应物更极极极化.7-Thiabicyloo[4.0]heptane通常无色,可粉色至黄色液体或固体,视温度和压力条件而定.已知该化合物在有机合成中的潜在用途,以及作为各种化学化合物开发过程中的一个构件.该化合物独特的结构特征还可能带来有趣的生物活动,使其成为医药化学的一个主题.然而,对其特定再活性,生物特性和潜在应用进行详细研究,对于全面了解其在各个领域的用途至关重要.

结构式图片

欧盟法规

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上下游产品

CAS号286-20-4 环氧环己烷 | CAS号13461-16-0 1,3-二甲基咪唑烷-2-硫酮 | CAS号60211-88-3 trans-1-iodo-2-... | CAS号110-83-8 环己烯 | CAS号333-20-0 硫氰酸钾 | CAS号16166-53-3 (+/-)-trans-1-m... | CAS号60211-89-4 (1R,2R)-1-iodo-... | CAS号17628-72-7 (R)-(-)-2-甲氧基-3-苯乙醇 | CAS号86853-20-5 racem.-bis-(tra... | CAS号2242-72-0 dodecahydro-thi... | CAS号2164-87-6 4,5-Tetramethyl... | CAS号21386-28-7 7λ4-thiabicyclo... | CAS号67-71-0 二甲基砜 | CAS号109-79-5 正丁硫醇

合成工艺路线路线简述

    氧化环己烯置于amberlite Ira-400 Supported Thiocyanate体系中,用 环己烷 用作溶剂,化学反应 14.0H,以82%的收率获得环己硫醚
    参考文献:使用聚合物负载的硫氰酸酯在温和和非水性条件下从环氧乙烷合成硫杂丙烷
    标题:使用聚合物负载的硫氰酸酯在温和和非水性条件下从环氧乙烷合成硫杂丙烷
    摘要:摘要 使用聚合物负载的硫氰酸盐,在温和的非水条件下,环氧乙烷可以有效地转化为其相应的硫杂丙烷.聚合物试剂是可再生的.
    Doi:10.1080/00397919608003817

    海关参考信息

    专利信息


    专利号:CN-115515998-A
    优先权日:2020-05-06
    标题 :Synthesis of Polyurethanes by Chain Growth Copolymerization

    专利号:JP-2005505648-A
    优先权日:2001-10-11
    标 题:Synthesis of chain-linked polymeric sulfide compounds and their use in rubber composition

    专利号:JP-2007238639-A
    优先权日:2006-03-03
    标 题:Synthesis of polytrithiocarbonate by alternating copolymerization of episulfide and carbon disulfide

    专利号:US-6831072-B2
    优先权日:1999-10-29
    标题 :Compositions and methods of synthesis and use of novel nucleic acid structures
    发明人:ERITJA RAMON; GARCIA RAMON GUEIMIL
    权利人:CYGENE INC
    摘要:The present invention is directed to a method to produce 8-amino-2'deoxyadenosine by treating 8-azido-2'deoxyadenosine with an aqueous solution of methylamine or dimethylamine.

    专利号:US-6806307-B2
    优先权日:2001-10-11
    标题 :Synthesis and use of chain-coupled polymeric sulfide compounds in rubber formulations
    发明人:HOGAN TERRENCE E; HERGENROTHER WILLIAM L
    权利人:BRIDGESTONE CORP
    摘要:The invention provides chain-coupled polymeric sulfide compounds for use as the elastomeric component in vulcanizable elastomeric compositions comprising silica, carbon black or mixtures thereof. In particular, the invention provides anionically polymerized polymers having polymer chain living ends that are functionalized with sulfide groups and coupled together by a metal or nonmetal atom. The chain-coupled polymeric sulfide compounds have an initial high viscosity for ease of handling prior to compounding, a stable viscosity during storage, and a decreased compound viscosity for better filler dispersion and improved mixing efficiency. The invention further provides a pneumatic tire having at least one component produced from the vulcanizable elastomeric composition of the invention. A tire tread produced from vulcanized elastomers exhibiting these improved properties will exhibit reduced hysteresis resulting in an increase in rebound and improved rolling resistance and wet traction.

    专利号:JP-4326949-B2
    优先权日:2001-10-11
    标 题:Synthesis of chain-linked polymeric sulfide compounds and their use in rubber composition
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    主要参考文献

    参考标题:Benzyne-Induced Ring Opening Reaction Of Thiiranes. Efficient Synthesis Of Phenyl Vinyl Sulfides
    作者:Juzo Nakayama,Satoshi Takeue,Masamatsu Hoshino |发布日期:1984.1
    摘要:A Series Of Thiiranes React With Benzyne To Provide An Efficient Synthesis Of Phenyl Vinyl Sulfides. The Reaction Is Stereospecific, Thus Producing Cis-(Phenylthio)-Stilbene From Cis-2,3-Diphenylthiirane And Trans-(Phenylthio)Stilbene From Trans-2,3-Diphenylthiirane.

    合成参考文献


    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 844.
    摘要:Hapiot, F.; Monflier, E., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 788.
    摘要:Cellnik, T.; Jo, W.; Healy, A., Science of Synthesis: Knowledge Updates, (2024) 2, 353.
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