📜2-羟基-5-甲基间苯二甲醇置于盐酸,三乙胺体系中,用 四氢呋喃,二氯甲烷 作为反应溶剂,化学反应 120.0H,反应生成 2,6-双{[双(2-吡啶基甲基)氨基]甲基}-4-甲基苯酚
参考文献:Synthesis And Properties Of A Heterobimetallic Iron-Manganese Complex And Its Comparison With Homobimetallic Analogues
标题:Synthesis And Properties Of A Heterobimetallic Iron-Manganese Complex And Its Comparison With Homobimetallic Analogues
摘要:Heterobimetallic Cofactors Containing One Manganese And One Iron Ion Have Recently Been Found Within The Di-Metal Carboxylate Protein Family. Herein We Report The Synthesis And Characterization Of Three Binuclear Metal Complexes With Fe-Fe,Mn-Mn,And Fe-Mn Metal Composition. All Three Complexes Use The Same Ligand Framework,The Bpmp Ligand (Hbpmp=2,6-Bis[(Bis (-2-Pyridylmethyl)Amine) Methyl]-4-Methylphenol)) With Two Additional Acetate Ligands Bridging The Two Metals. In Terms Of Stability Towards Metal Exchange,The Fe-Mn Is More Stable Than The Mn-Mn Complex But Less Stable Than The Fe-Fe Complex. Cyclic Voltammetry Shows That The Fe-Mn Complex Behaves Markedly Different Than The Homobimetallic Complexes. The Fe-Mn Complex Also Shows Higher Reactivity With O-2 Than Both The Fe-Fe And The Mn-Mn Counterparts.
DOI:10.1016/j.Ica.2019.03.029