CAS: 80528-41-2; 2,6-Bis((Bis(Pyridin-2-Ylmethyl)Amino)Methyl)-4-Methylphenol

该化合物是一种专门的有机化合物,以甲基和二(2-丙基甲基)氨基组替代的中苯酚核心,其结构包含多种氮捐献地,使其成为协调化学的多用途螺旋,特别是在形成稳定的金属综合体方面.该化合物的僵硬但功能化框架增强了其在催化应用,分子识别和超分子组装方面的效用.

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63671-68-1 353779-31-4 1609403-53-3

上下游产品

CAS号50-00-0 甲醛 | CAS号106-44-5 对甲酚 | CAS号1539-42-0 2,2'-二吡啶甲基胺 | CAS号5862-32-8 2,6-双(氯甲基)-4-甲基苯酚 | CAS号91-04-3 2-羟基-5-甲基间苯二甲醇

合成工艺路线路线简述

    📜2-羟基-5-甲基间苯二甲醇置于盐酸,三乙胺体系中,用 四氢呋喃,二氯甲烷 作为反应溶剂,化学反应 120.0H,反应生成 2,6-双{[双(2-吡啶基甲基)氨基]甲基}-4-甲基苯酚
    参考文献:Synthesis And Properties Of A Heterobimetallic Iron-Manganese Complex And Its Comparison With Homobimetallic Analogues
    标题:Synthesis And Properties Of A Heterobimetallic Iron-Manganese Complex And Its Comparison With Homobimetallic Analogues
    摘要:Heterobimetallic Cofactors Containing One Manganese And One Iron Ion Have Recently Been Found Within The Di-Metal Carboxylate Protein Family. Herein We Report The Synthesis And Characterization Of Three Binuclear Metal Complexes With Fe-Fe,Mn-Mn,And Fe-Mn Metal Composition. All Three Complexes Use The Same Ligand Framework,The Bpmp Ligand (Hbpmp=2,6-Bis[(Bis (-2-Pyridylmethyl)Amine) Methyl]-4-Methylphenol)) With Two Additional Acetate Ligands Bridging The Two Metals. In Terms Of Stability Towards Metal Exchange,The Fe-Mn Is More Stable Than The Mn-Mn Complex But Less Stable Than The Fe-Fe Complex. Cyclic Voltammetry Shows That The Fe-Mn Complex Behaves Markedly Different Than The Homobimetallic Complexes. The Fe-Mn Complex Also Shows Higher Reactivity With O-2 Than Both The Fe-Fe And The Mn-Mn Counterparts.
    DOI:10.1016/j.Ica.2019.03.029

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    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Min Su Han, Et Al. Naked-Eye Detection Of Phosphate Ions In Water At Physiological Ph: A Remarkably Selective And Easy-To-Assemble Colorimetric Phosphate-Sensing Probe. Angew Chem Int Ed Engl. 2002 Oct 18;41(20):3809-11.

    合成参考文献


    参考文献:10.1007/978-3-662-62470-8_269
    摘要:Pardasani RT, Pardasani P. Magnetic properties of phosphate bridged nickel(II) complex with phosphodiester. 2021. In: Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 3.
    参考文献:10.1007/s00775-005-0635-7
    摘要:Lanznaster M, Neves A, Bortoluzzi AJ, Aires VVE, Szpoganicz B, Terenzi H, Severino PC, Fuller JM, Drew SC, Gahan LR, Hanson GR, Riley MJ, Schenk G. A new heterobinuclear FeIIICuII complex with a single terminal FeIII–O(phenolate) bond. Relevance to purple acid phosphatases and nucleases. JBIC Journal of Biological Inorganic Chemistry. 2005 Apr 21;10(4):319–32. doi: 10.1007/s00775-005-0635-7.
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