CAS: 474-40-8; (3S,4S,5S,9R,10S,13R,14R,17R)-17-((R,Z)-5-Isopropylhept-5-En-2-yl)-4,10,13-Trimethyl-2,3,4,5,6,9,10,11,12,13,14,15,16,17-Tetradecahydro-1H-Cyclopenta[a]Phenanthren-3-Ol

该化合物是一种化学化合物,被归类为类固醇,主要因其作为植物生长调节器的作用而得到承认,并且来自自然来源,特别是柑橘植物;类固醇具有典型的类固醇特征,包括有助于其生物活动的多环结构;Citrostadienol已知会影响植物中的各种生理过程,例如促进生长和增强对环境压力的抗力;其行动机制往往涉及荷尔蒙途径的调节,尤其是与助产物和有关的途径.此外,Citrostadienol由于具有提高作物产量和质量的潜力,因此对农业应用产生了兴趣.虽然主要在植物生物学方面研究,但正在进行的研究可能会探索其在其他领域的更广泛影响,包括药理学和生物化学化学学.许多化学物质,在以任何方式处理或应用Citrostadienol时,安全和监管因素至关重要.

结构式图片

MSDS等安全信息

    上下游产品

    4α-甲基-24-甲基-5α-胆甾-7-烯-3β-醇24-亚甲基-4-甲基胆(甾)-7-烯-3-醇 (3β,4α,5α)-4-Methylergosta-7,24(28)-Dien-3-Ol 1176-52-9
    Citrostadienol Acetate 63162-73-2
    Acetic Acid (3S,4S,5S,9R,10S,13R,14R,17R)-4,10,13-Trimethyl-17-((S)-1-Methyl-2-Oxo-Ethyl)-2,3,4,5,6,9,10,11,12,13,14,15,16,17-Tetradecahydro-1H-Cyclopenta[a]Phenanthren-3-Yl Ester 63109-20-6
    3β-Acetoxy-4α-Methyl-24-Oxo-5α-Cholesten-7 2364-32-1

    合成工艺路线路线简述

      📜Acetic Acid (3S,4S,5S,9R,10S,13R,14R,17R)-4,10,13-Trimethyl-17-((S)-1-Methyl-2-Oxo-Ethyl)-2,3,4,5,6,9,10,11,12,13,14,15,16,17-Tetradecahydro-1H-Cyclopenta[a]Phenanthren-3-Yl Ester置于palladium On Barium Sulfate 氢气,Potassium Carbonate,苯甲酸体系中,用 甲醇,乙酸乙酯,甲苯 作为反应溶剂,化学反应 2.0H,反应生成 柠檬二烯醇
      参考文献:Sucrow,W. Et Al.,Chemische Berichte,1977,Vol. 110,P. 1523-1531
      标题:Sucrow,W. Et Al.,Chemische Berichte,1977,Vol. 110,P. 1523-1531

      海关参考信息

      专利信息


      专利号:US-4923403-A
      优先权日:1984-08-16
      标题:Microbiological process for degradation of steroids
      发明人:FERREIRA NICOLAAS P
      权利人:SOUTH AFRICAN INVENTIONS
      摘要:A process for preparing 3a alpha -H-4 alpha -[3'-propionic acid]-5 alpha -hydroxy-7a beta -methyl-hexahydro-1-indanone- delta -lactone, having the formula for the chemical synthesis of a pharmaceutical steroid, which includes cultivating, in the presence of cholesterol, sitosterol, stigmasterol, or a mixture of sitosterol and sitostanol, a mutant of the parent species R. australis of the genus Rhodococcus.

      专利号:US-5166055-A
      优先权日:1987-12-23
      标 题:Microbiological preparation of 9-alpha-hydroxy-17-keto steroids
      发明人:SLIJKHUIS HARMEN; MARX ARTHUR F
      权利人:GIST BROCADES NV
      摘要:9 alpha -hydroxy-17-keto steroids are prepared by fermenting steroids having a C-17-side chain of 5-10 carbon atoms inclusive, with the novel Mycobacterium species CBS 482.86. Starting from various substrates containing a 5-10 C carbon chain on C-17, 9 alpha -hydroxyandrost-4-ene-3,17-dione, 7 alpha ,9 alpha ,12 alpha -trihydroxyandrost-4-ene-3,17-dione or 9 alpha -hydroxyandrost-4,11-diene-3,17-dione is obtained in high yield. The resulting compounds are useful intermediates in the synthesis of therapeutically important steroids, particularly corticosteroids.

      专利号:US-5298398-A
      优先权日:1987-12-23
      标题 :Preparation of 9-α-hydroxy-17-keto steroids using Mycobacterium species CBS 482.86
      发明人:SLIJKHUIS HARMEN; MARX ARTHUR F
      权利人:GIST BROCADES NV
      摘要:9 alpha -hydroxy-17-keto steroids are prepared by fermenting steroids having a C-17-side chain of 5-10 carbon atoms inclusive, with the novel Mycobacterium species CBS 482.86. Starting from various substrates containing a 5-10 C carbon chain on C-17, 9 alpha -hydroxyandrost-4-ene-3,17-dione, 7 alpha ,9 alpha ,12 alpha -trihydroxyandrost-4-ene-3,17-dione or 9 alpha -hydroxyandrost-4,11-diene-3,17-dione is obtained in high yield. The resulting compounds are useful intermediates in the synthesis of therapeutically important steroids, particularly corticosteroids.

      专利号:US-7105730-B1
      优先权日:1999-07-12
      标 题 :Nucleic acid molecules and other molecules associated with sterol synthesis and metabolism
      发明人:KARUNANANDAA BALASULOJINI; YU JAEHYUK; KISHORE GANESH M
      权利人:MONSANTO TECHNOLOGY LLC
      摘要:This invention relates to the field of biotechnology, particularly as it pertains to the production of sterols in a variety of host systems particularly plants. More specifically, the invention relates to nucleic acid molecules encoding proteins and fragments of proteins associated with sterol and phytosterol metabolism as well as the encoded proteins and fragments of proteins and antibodies capable of binding to them. The invention also relates to methods of using the nucleic acid molecules, fragments of the nucleic acid molecules, proteins, and fragments of proteins. The invention also relates to cells, organisms, particularly plants, or seeds, or progeny of plants, that have been manipulated to contain increased levels or overexpress at least one sterol or phytosterol compound.

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      📌 第三方产品分析报告

      ✅ COA系统入驻 | 共享模式

      合成参考文献


      参考文献:10.1007/s004250000417
      摘要:Sitbon F, Jonsson L. Sterol composition and growth of transgenic tobacco plants expressing type-1 and type-2 sterol methyltransferases. Planta. 2001 Mar;212(4):568–72. doi: 10.1007/s004250000417.
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