CAS: 335-27-3; Perfluoro-1,3-Dimethylcyclohexane
该化合物是一种全氟化合物,其特点是1和3个位置有两组甲基环环,完全用氟原子取代,具有独特的特性,包括高热稳定性,化学惰性,低表面张力等,氟原子的存在增强了其疏水和疏脂特性,使其在特殊涂层,润滑剂等各种应用中有用,并在某些配方中作为表面活性剂.此外,全氟化合物具有耐降解性,引起人们对其持久性和潜在生物累积性的环境关切,该化合物通常不易燃,具有低波动性,有助于其在一系列条件下的稳定.然而,由于全氟物质对环境的影响,监管审查增加了,促进了对更安全的替代品的研究.
- 英文名称Perfluoro-1,3-Dimethylcyclohexane
- 中文名称全氟-1,3-二甲基环己烷
- IUPAC名称1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)cyclohexane
- 其它别名1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)-cyclohexan; perfluoro-1,3-dimethylcyclohexane; perfluoro(1,3-dimethylcyclohexane); decafluoro-1,3-bis(trifluoromethyl)cyclohexane
- CAS编号335-27-3
- MFCD编号:MFCD00001469
- EINECS号:206-386-9
- FDA UNII编号:Q1Y54IOL0P
- 分子式:C8F16分子量:400.06
- 产品CID: 1331366
- 产品分类有机原料 → 烃类化合物及其衍生物 → 烃类卤化物
物理性质
MSDS等安全信息
欧盟法规
REACH注册ECHA物质ECHA物质C&L通报REACH预注册上下游产品
CAS号327-76-4 2,4-双三氟甲基氯苯 | CAS号108-38-3 间二甲苯 | CAS号402-31-3 间二三氟甲苯 | CAS号108-67-8 均三甲苯 | CAS号638-04-0 顺-1,3-二甲基环己烷 | CAS号368-77-4 间三氟甲基苯腈合成工艺路线路线简述
- 合成目标产物 Perfluoro-1,3-Dimethylcyclohexane 主要起始原料 1,3-Bis(Trifluoromethyl)-Benzene
- (文献来源)合成步骤主要原料 1,3-Bis(Trifluoromethyl)-Benzene
📜间二三氟甲苯置于cobalt (Iii) Fluoride,氮体系中,化学反应生成 全氟-1,3-二甲基环己烷
参考文献:中试植物合成-全氟正庚烷,全氟二甲基环己烷和高沸点碳氟化合物油
标题:中试植物合成-全氟正庚烷,全氟二甲基环己烷和高沸点碳氟化合物油
摘要:
DOI:10.1021/ie50447A618
海关参考信息
- 2903399090-其他无环烃卤化衍生物
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-6596884-B2
优先权日:1998-06-29
标 题:Synthesis of hydrogen peroxide
发明人：BECKMAN ERIC J; HANCU DAN
权利人:UNIV PITTSBURGH
摘要:A method for synthesizing hydrogen peroxide comprises the steps of: synthesizing an analog of anthraquinone that is miscible or soluble in carbon dioxide; reacting the analog of anthraquinone with hydrogen in carbon dioxide to produce a corresponding analog of tetrahydroquinone; and reacting the analog of tetrahydroquinone with oxygen to produce the hydrogen peroxide and regenerate the analog of anthraquinone. A chemical compound having the formula: n wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 are independently, the same or different, H, R C , or R S R C , wherein R S is a spacer group and R C is a fluoroalkyl group, a fluoroether group, a silicone group, an alkylene oxide group, a fluorinated acrylate group, or a phosphazine group, and wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 is not H.
专利号:US-6656446-B1
优先权日:1999-04-29
标题:Synthesis of hydrogen peroxide
发明人：BECKMAN ERIC J; HANCU DAN
权利人:UNIV PITTSBURGH
摘要:A method for synthesizing hydrogen peroxide comprises the step of: mixing an analog of a secondary alcohol that is soluble with carbon dioxide with a free radical initiator and oxygen in carbon dioxide to generate hydrogen peroxide. Another method of synthesizing hydrogen peroxide comprises the step of: mixing hydrogen, oxygen and a CO 2 -philic catalyst in carbon dioxide phase. The CO 2 -philic catalyst is soluble or miscible in carbon dioxide and is suitable to catalyze the reaction of hydrogen and oxygen to produce hydrogen peroxide. The method also comprises the step of reacting the hydrogen and oxygen to produce hydrogen peroxide.
专利号:WO-0066489-A1
优先权日:1999-04-29
标 题:Synthesis of hydrogen peroxide
专利号:US-4369128-A
优先权日:1980-04-22
标题 :Catalyst for oxidation
发明人：MOSELEY FRED; DYER PAUL N
权利人:AIR PROD & CHEM
摘要:A catalyst suitable for use in the synthesis of hydrogen peroxide from hydrogen and oxygen is prepared by bringing hydrogen and oxygen into contact with a liquid mixture comprising a fluorocarbon and/or halofluorocarbon and water containing bis(tri(pentafluorophenyl)phosphine) palladium dichloride. When the reaction mixture is allowed to stand the catalyst appears as a black film at the interface of the organic and aqueous phases. The black film is almost totally insoluble in aqueous hydrogen peroxide.
专利号:US-2002110516-A1
优先权日:1998-06-29
标题:Synthesis of hydrogen peroxide
专利号:US-2001007045-A1
优先权日:1998-06-29
标 题 :Synthesis of hydrogen peroxide
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118
摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775
摘要:de Figueiredo, R. M., Science of Synthesis: Knowledge Updates, (2024) 2, 275.
参考文献:10.1007/s00216-006-0514-2
摘要:Khan Malek CG. Laser processing for bio-microfluidics applications (part I). Analytical and Bioanalytical Chemistry. 2006 Jun 14;385(8):1351–61. doi: 10.1007/s00216-006-0514-2.
参考文献:10.1039/c1pp05034f
摘要:Wenska G, Taras-Goślińska K, Łukaszewicz A, Burdziński G, Koput J, Maciejewski A. Mechanism and dynamics of intramolecular triplet state decay of 1-propyl-4-thiouracil and its α-methyl-substituted derivatives studied in perfluoro-1,3-dimethylcyclohexane. Photochemical & Photobiological Sciences. 2011 Aug;10(8):1294–302. doi: 10.1039/c1pp05034f.
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