CAS: 3091-25-6; Octyltin Trichloride

该化合物是有机锡化合物,其特征是附于锡原子的辛基锡化合物,该化合物进一步与三个氯原子相协调,该化合物一般看起来无色,可粉黄液,以其高度稳定性和低挥发性而著称;八氯三氯化锡主要用作其他有机锡化合物合成的前体和各种化学反应的催化剂,特别是聚合物生产中的催化剂;由于碳氢化合物链长,该物质具有疏水特性,因此在需要水抗的用途中有用;然而,必须指出,有机锡化合物,包括三氯化锡化合物,可能有毒,并对环境造成危害,特别是对水生生物造成危害;因此,处理该物质需要采取适当的安全措施,以减少接触风险;其化学行为受到锡-氯联结的存在的影响,这些联结在水分时会进行水解,导致其他锡种的形成.

结构式图片

相似化合物

1118-46-3 3542-36-7

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

tri°Ctylaluminum hydrogenchloride °Ct-1-ene triethylamine hydr°Chloridedi-n-°Ctyltin dichloride n-°Ctyl-stannan °Ctyltin tris(iso°Ctyl thioglycollate) n-°Ctyl-tri-n-butyl-stannan

合成工艺路线路线简述

    📜三辛基铝 以 二丁醚 作为反应溶剂,化学反应生成 乙辛基三氯化锡
    参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.1,1.1.1.11,Page 117-121
    标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.1,1.1.1.11,Page 117-121

    海关参考信息

    专利信息


    专利号:WO-9212984-A1
    优先权日:1991-01-22
    标 题:Method for the direct synthesis of organo-tin chlorides, and the use of such chlorides
    发明人:MALGUZZI ROMUALDO; SANDRI MAURIZIO; ROSENTHAL MICHAEL; PUERZER ALBERT W
    权利人:BAERLOCHER GMBH
    摘要:The invention concerns a method of synthesizing directly organo-tin chlorides of the formula RnSnCl4-n, in which n = 1 or 2 and R is a straight-chain, branched-chain or cycloaliphatic alkyl rest with 4 to 18 C-atoms, by reacting tin(II)-chloride with alkyl chlorides. The method is characterized in that the reaction is carried out in the presence of amines of the general formula A: R1aN[(CH2CH2O)m CH2CH2OR2]3-a and/or substituted ammonium chlorides of the formula B: R1bN[(CH2CH2O)mCH2CH2OR2]4-b Cl in which a = 0, 1 or 2; b= 0, 1, 2 or 3; R1 is a straight-chain, branched-chain or cycloaliphatic alkyl group with 2 to 24 C-atoms, or an aryl, alkylaryl or substituted-aryl group, and if a = 2 or b = 2 or 3, the R1 groups may be the same or different; R2=H is a straight-chain or branched-chain alkyl group with 1 to 20 C-atoms, or an aryl, substituted-aryl or alkylaryl group; and m = 1 to 20. Organo-tin chlorides produced in this way are particularly suitable for use as intermediates in the preparation of thermostabilizers for PVC resins.

    专利号:US-12129358-B2
    优先权日:2020-02-24
    标题 :Alkyl-bridged tin-based thermal stabilizers for halogenated resins and synthesis and uses thereof
    发明人:ROSS KEVIN JOHN; NORRIS GENE KELLY
    权利人:PMC ORGANOMETALLIX INC
    摘要:The present invention relates to stabilizer composition for halogen-containing polymer. It has recently been found that tin-based thermal stabilizers with a bridging alkyl group between two tin centers are effective stabilizers while having effectively double the molecular weight of the corresponding non-alkyl bridged stabilizer. It is expected that ongoing experimentation will confirm that the alkyl bridged stabilizers have much lower volatility which leads to greater retention of the stabilizer in the finished article.

    专利号:WO-9222558-A2
    优先权日:1991-06-12
    标 题:Method for the direct synthesis of organo-tin chlorides, and their use

    专利号:EP-0557465-A1
    优先权日:1991-01-22
    标题 :Method for the direct synthesis of organo-tin chlorides, and the use of such chlorides

    专利号:DE-4119379-A1
    优先权日:1991-06-12
    标 题 :METHOD FOR THE DIRECT SYNTHESIS OF ORGANOZIN CHLORIDES AND THE USE THEREOF

    专利号:JP-H06504540-A
    优先权日:1991-01-22
    标题 :Methods for direct synthesis of organotin chlorides and their use

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Arzneimittel-Forschung. Drug Research., 19(934), 1969 []
    参考文献:10.1155/bca.2005.191
    摘要:Bychkov PV, Shekhovtsova TN, Milaeva ER. Inhibition of Horse Liver Alcohol Dehydrogenase byMethyltin Compounds. Bioinorganic Chemistry and Applications. 2005 Jan;3(3-4):191–9. doi: 10.1155/bca.2005.191.
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