CAS: 1866-31-5; Allyl Cinnamate

上下游产品

cinnamoyl chloride allyl alcohol diethoxyphosphoryl-acetic acid ethyl ester benzaldehyde 2-Iodo-3-p-toluenesulphonylpropyl cinnamate 2-Bromo-3-p-toluenesulphonylpropyl cinnamate 4-Phenylbut-1-ene allylbenzene

1,3-Dichloro-2-Propyl Cinnamate置于sodium Iodide体系中,用 丁酮 用作溶剂,化学反应 48.0H,以98%的收率获得肉桂酸烯丙酯
参考文献:串联的finkelstein重排消除反应:烯丙基酯的直接合成路线
标题:串联的finkelstein重排消除反应:烯丙基酯的直接合成路线
摘要:烯丙基酯可以通过nai诱导的2-氯-1-(氯甲基)乙基酯的finkelstein重排消除反应获得.碘化钠可以在还原当量以下使用还原剂作为硫代硫酸钠使用.使用大多数已研究的各种酯均可获得高收率.所描述的方法避免了使用烯丙醇作为试剂.2-氯-1-(氯甲基)乙酯是由甘油制成的,甘油是生物柴油工业的主要副产品.还证实了碘作为水解烯丙基酯的试剂的有效性.
Doi:10.1016/j.Tet.2009.04.042

专利信息

专利号:US-9890132-B2
优先权日:2013-08-25
标 题 :Process for the preparation of anti-inflammatory aroylbenzofuran compounds
发明人：RAMANA CHEPURI VENKATA; KOMMAGALLA YADAGIRI; SRINIVAS KOLLURU
权利人:COUNCIL SCIENT IND RES; COUNCIL SCIENT IND RES
摘要:Disclosed herein an efficient process for synthesis of benzofuran analogs having anti-inflammatory activity which comprises, Ru-catalyzed branched and linear selective alkylation of aroylbenzofurans formula-I with alpha, beta unsaturated esters of formula-II via C—H activation in presence of base, additives and organic solvent at suitable temperature to give high yield of desired linear alkylated benzofuran compounds of formula-III or branched alkylated benzofuran compounds of formula-IV or mixture thereof.

专利号:US-7060471-B2
优先权日:2003-03-12
标题 :Stereoselective chemoenzymatic process for the preparation of optically enriched phenylglycidates as precursors of taxol side chain
发明人：ANAND NAVEEN; KAPOOR MUNISH; TANEJA SUBHASH CHANDRA; KOUL SURRINDER; SHARMA RATTAN LAL; QAZI GHULAM NABI
权利人:COUNCIL SCIENT IND RES
摘要:The present invention relates to a novel and efficient chemoenzymatic process of preparation of optically active trans alkyl phenylglycidates. The invention particularly discloses a novel process for the chemoenzymatic synthesis of two enantiomers of trans alkyl phenylglycidate i.e. alkyl(2S,3R)-phenylglycidate and alkyl(2R,3S)-phenylglycidate of formulae 7 and 8 respectively

专利号:US-8541598-B2
优先权日:2007-08-21
标 题 :Biodegradable solvents for the chemical industry
发明人：GATHERGOOD NICK; MORRISSEY SAIBH; PEGOT BRUCE
权利人:GATHERGOOD NICK; MORRISSEY SAIBH; PEGOT BRUCE; UNIV DUBLIN CITY
摘要:This invention relates to ionic liquid (ILs) solvents for chemical synthesis based on an alkyl-imidazolium cation core containing ionic liquids which have enhanced biodegradability and reduced toxicity relative to existing imidazolium bases ILs such as 1-butyl-3-methylimidazolium (bmmim) salts. Many of the described ILs produce a score of over 60% biodegradability over 28 days in a biodegradability test such as the Sturm Test, the Closed Bottle Test (OECD 301D) or the CO 2 Headspace Test (ISO 14593). The ILs of the invention comprise an alkyl substituted imidazolium cationic core having a —Câ•?OX— side chain in the 3-position of the imidazole ring, wherein Xâ•?O, NH, N or S and an associated counteranion characterized in that the —Câ•?OX side chain comprises at least one ether linkage. The biodegradable and non-toxic IL may be used as green solvents for the chemical, pharmaceutical, biofuel and biomass industries. The ILs of the invention are particularly useful in hydrogenation, pericyclic ad metathesis reactions.