CAS: 927-49-1; Undecan-6-One

• 英文名称Undecan-6-One
• 中文名称6-十一酮
• IUPAC名称undecan-6-one
• 其它别名Dipentyl Ketone; 6-Oxoundecane; Undecanone-(6); Amyl Ketone; Unii-8Jmd3E1Soo; 8Jmd3E1Soo; 6-Undecanone [fhfi]; Diamyl Ketone, Dipentyl Ketone
• CAS编号927-49-1
• MFCD编号:MFCD00009516
• EINECS号:213-150-9
• 分子式:C11H22O
• 分子量:170.29
• 产品CID: 1965980
• 产品分类有机原料→分子砌块→脂肪链类化合物

• 相似结构搜索
• 产品信息参考;;;
• InChIKey: ZPQAKYPOZRXKFA-UHFFFAOYSA-N
• InChI=1S/C11H22O/c1-3-5-7-9-11(12)10-8-6-4-2/h3-10H2,1-2H3…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数8.0

相似化合物

物理性质

• 熔点14.6 °C
• 沸点228 °C at 760 mmHg
• 闪点88°C
• 密度0.8±0.1 g/cm3
• PSA:17.07
• LogP:3.7161
• 折射率1.425
• 蒸汽压0.1±0.4 mmHg at 25°C
• 溶解性0.05 mg/mL at 25 °C
• 敏感性常温常压下稳定，避免强氧化剂 强还原剂接触
• 外观形态无色至淡黄色至浅橙色液体
• 储存条件储存在 室温
• 产品应用该化合物用于辅助液体膜的各种有机溶剂进行系统筛选.

MSDS等安全信息

• GHS符号GHS05
• 警示词Danger
• 危险描述H290-H314
• 防范说明P234-P260-P264-P280-P301+P330+P331-P304+P340-P363-P390-P405-P406-P501
• 危险等级4.1
• UN编号1325.0
• 危险品标志Xi
• 风险等级Irritant
• 包装等级Ⅲ
• 安全声明24/25
• 危险类别码R23/25
• WGK Germany3

上下游产品

合成工艺路线路线简述

• 947-31-9 = 927-49-1
  反应条件:1.1 Reagents: Phosphorodichloridic Acid,Phenyl Ester,Sodium Iodide Solvents: Benzene
  标题:Deketalization Induced By Phenyl Dichlorophosphate And Sodium Iodide
  作者:Liu,Hsing Jang; Uy,Shu Yuan
  参考文献:Synthetic Communications 日期:1986 卷标:16(11) 页码:1357-61]
  
  23708-56-7 = 927-49-1
  反应条件:1.1 Catalysts: Iridium(2+),Triaqua[(1,2,3,4,5-η)-1,2,3,4,5-Pentamethyl-2,4-Cyclopentadien-1-Yl...,Iridium(2+),Triaqua[(1,2,3,4,5-η)-1,2,3,4,5-Pentamethyl-2,4-Cyclopentadien-1-Yl... (Reaction Products With Bipyridinyl-Containing Silyl Polymers),2,2′-Bipyridine,6,6′-Bis(Methoxymethoxy)-5,5′-Bis(Triethoxysilyl)-,Polymer Wit... (Deprotected),2,2′-Bipyridine,6,6′-Bis(Methoxymethoxy)-5,5′-Bis(Triethoxysilyl)-,Polymer Wit... (Deprotected,Reaction Products With Iridium Complex) Solvents: Toluene; 6 H,130 °C
  标题:Solid Catalyst Used For Dehydrogenation Reaction Of Alcohols And Formic Acid,And Method For Producing A Carbonyl Compound And Hydrogen Using The Same
  参考文献:Japan]
  
  5849-09-2 = 927-49-1
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Cerium Bromide Solvents: Ethanol; Rt; 15 Min,40 °C1.2 Reagents: Sodium Thiosulfate Solvents: Ethyl Acetate,Water; Rt
  标题:Fenton-Like Chemistry Enables Catalytic Oxidative Desulfurization Of Thioacetals And Thioketals With Hydrogen Peroxide
  作者:Zhao,Guodong; Wang,Yaxin; Wang,Cheng; Lei,Haimin; Yi,Bingqing; Et Al
  参考文献:Green Chemistry 日期:2022 卷标:24(10) 页码:4041-4049]
  
  = 927-49-1
  反应条件:1.1 Catalysts: Manganese Oxide (Mno2),Alumina; 673 K
  标题:Catalytic Ketonization Over Oxide Catalysts
  作者:Glinski,M.; Koziol,A.; Lomot,D.; Kaszkur,Z.
  参考文献:Applied Catalysis 日期:2007 卷标:323 页码:77-85]
  
  = 927-49-1
  反应条件:1.1 Catalysts: Manganese Oxide (Mno2),Alumina; 673 - 698 K
  标题:Catalytic Ketonization Over Oxide Catalysts. Part Ix. Single Step Synthesis Of Aliphatic Saturated And Unsaturated C11 - C13 Ketones From Carboxylic Acids
  作者:Glinski,M.; Gibka,J.
  参考文献:Polish Journal Of Chemistry 日期:2004 卷标:78(2) 页码:299-302]
  
  693-25-4 = 927-49-1 [标题:Reaction Conditions
  标题:Iron Catalyzed Cross-Coupling Reactions Of Acyl Chlorides With Grignard Reagents. A Mild,General,And Convenient Synthesis Of Aliphatic And Aromatic Ketones
  作者:Fiandanese,V.; Marchese,G.; Martina,V.; Ronzini,L.
  参考文献:Tetrahedron Letters 日期:1984 卷标:25(42) 页码:4805-8]
  
  23708-56-7 = 927-49-1
  反应条件:1.1 Catalysts: Benzophenone,Sodium Tert-Butoxide Solvents: Toluene; 18 H,110 °C
  标题:Efficient And Eco-Compatible Transition Metal-Free Oppenauer-Type Oxidation Of Alcohols
  作者:Ballester,Jorge; Caminade,Anne-Marie; Majoral,Jean-Pierre; Taillefer,Marc; Ouali,Armelle
  参考文献:Catalysis Communications 日期:2014 卷标:47 页码:58-62]
  
  145070-63-9 = 927-49-1
  反应条件:1.1 Reagents: P-Toluenesulfonic Acid1.2 Reagents: Piperidine1.3 Reagents: Dowex 50W
  标题:Dendritic Aliphatic Polyethers As High-Loading Soluble Supports For Carbonyl Compounds And Parallel Membrane Separation Techniques
  作者:Haag,Rainer; Sunder,Alexander; Hebel,Andre; Roller,Sebastian
  参考文献:Journal Of Combinatorial Chemistry 日期:2002 卷标:4(2) 页码:112-119]
  
  23708-56-7 = 927-49-1
  反应条件:1.1 Catalysts: Iridium(2+),Triaqua[(1,2,3,4,5-η)-1,2,3,4,5-Pentamethyl-2,4-Cyclopentadien-1-Yl... (Ligand-Containing Organosilica Complexes),2,2′-Bipyridine,6,6′-Bis(Methoxymethoxy)-5,5′-Bis(Triethoxysilyl)-,Polymer Wit... (Deprotected,Ir Complexes) Solvents: Toluene; 18 H,Reflux
  标题:Iridium Complex Immobilized On Custom-Designed Periodic Mesoporous Organosilica As Reusable Catalyst For The Dehydrogenative Oxidation Of Alcohols
  作者:Shimizu,Mineyuki; Michikawa,Kumiko; Maegawa,Yoshifumi; Inagaki,Shinji; Fujita,Ken-Ichi
  参考文献:Acs Applied Nano Materials 日期:2020 卷标:3(3) 页码:2527-2535]
  
  5849-09-2 = 927-49-1
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Cerium Bromide Solvents: Ethanol; 10 Min,Rt1.2 Reagents: Sodium Thiosulfate Solvents: Water
  标题:Green Preparation Of Carbonyl Compounds By Conversion Of 1,3-Dithiane Derivatives
  参考文献:China]
  
  = 927-49-1
  反应条件:1.1 Catalysts: Palladium Solvents: Toluene; 40 H,120 °C
  标题:α-Alkylation Of Ketones By Trialkylamines Under Heterogeneous Pd/c Catalysis
  作者:Yoon,Il Chul; Kim,Tae Gyun; Cho,Chan Sik
  参考文献:Organometallics 日期:2014 卷标:33(7) 页码:1890-1892]
  
  104169-13-3 = 927-49-1
  反应条件:1.1 Reagents: Silver Nitrate Solvents: Acetonitrile,Water1.2 Reagents: Triethylamine
  标题:Nonacidic And Highly Chemoselective Protection Of The Carbonyl Function. 3-Methylbenzothiazolines As A Base- And Acid-Resistant Protected Form For The Carbonyl Groups
  作者:Chikashita,Hidenori; Komazawa,Shunichiro; Ishimoto,Nishiki; Inoue,Koji; Itoh,Kazuyoshi
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:1989 卷标:62(4) 页码:1215-25]
  
  71-36-3 = 927-49-1
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Palladium,Aluminum Hydroxide Solvents: Toluene; 48 H,80 °C
  标题:Recyclable Palladium Catalyst For Highly Selective α-Alkylation Of Ketones With Alcohols
  作者:Kwon,Min Serk; Kim,Namdu; Seo,Seong Hyeok; Park,In Soo; Cheedrala,Ravi Kumar; Et Al
  参考文献:Angewandte Chemie 日期:2005 卷标:44(42) 页码:6913-6915]
  
  77075-86-6 = 927-49-1
  反应条件:1.1 Reagents: Sulfuric Acid,Sodium Dichromate
  标题:The Reaction Of (Phenyldimethylsilyl)Dichloromethyllithium With Organoboranes. A Synthesis Of α-Hydroxyorganosilanes And Ketones
  作者:Rosario,Osvaldo; Sandoval,Sydia; Larson,Gerald L.
  参考文献:Synthetic Communications 日期:1980 卷标:10(11) 页码:813-19]
  
  2966758-33-6 = 927-49-1
  反应条件:1.1 Reagents: 4-Nitrophthalonitrile Solvents: Acetonitrile,Water; 48 H
  标题:Oxidative Cleavage Of Ketoximes To Ketones Using Photoexcited Nitroarenes
  作者:Gottemann,Lucas T.; Wiesler,Stefan; Sarpong,Richmond
  参考文献:Chemrxiv 日期:2023 卷标:1 页码:1-13]
  
  = 927-49-1
  反应条件:1.1 Catalysts: 2,4,6-Tris(1-Methylethyl)Benzenethiol,Iridium(1+),[5,5′-Bis(Trifluoromethyl)-2,2′-Bipyridine-Kn1,Kn1′]Bis[3,5-Difluor...,Phosphonium,Tetrabutyl-,Diphenyl Phosphate (1:1) Solvents: (Trifluoromethyl)Benzene; 24 H,Rt
  标题:A Redox Strategy For Light-Driven,Out-Of-Equilibrium Isomerizations And Application To Catalytic C-C Bond Cleavage Reactions
  作者:Ota,Eisuke; Wang,Huaiju; Frye,Nils Lennart; Knowles,Robert R.
  参考文献:Journal Of The American Chemical Society 日期:2019 卷标:141(4) 页码:1457-1462]
  
  23708-56-7 = 927-49-1
  反应条件:1.1 Reagents: Oxygen Catalysts: Tpap Solvents: Toluene
  标题:Preparation Of Aldehydes Or Ketones From Alcohols Using Oxygen In The Presence Of Catalytic Tetraalkylammonium Ruthenium Species.
  参考文献:United Kingdom]
  
  6378-65-0 = 927-49-1
  反应条件:1.1 Catalysts: Maleic Acid,Cerium Cobalt Lanthanum Manganese Potassium Strontium Tin Zirconium Oxide; 160 H,750 K
  标题:Catalyst For Catalytic Conversion Of Alcohols To Ketones And Method For Production Of Catalyst
  参考文献:Poland]
  
  57266-87-2 = 927-49-1
  反应条件:1.1 Reagents: Isopropanol,Oxygen Catalysts: Bis[ethyl 2-(Formyl-Ko)-3-(Oxo-Ko)Butanoato]Cobalt
  标题:Preparation Of Ketones
  参考文献:Japan]
  
  23708-56-7 = 927-49-1
  反应条件:1.1 Reagents: 4-[(Aminocarbonyl)Amino]-2,2,6,6-Tetramethyl-1-Piperidinyloxy (Silica Supported) Solvents: Acetone; 10 Min,Rt1.2 Reagents: Sodium Hypochlorite Solvents: Water; 0 °C; 12 H,0 °C
  标题:The Oxidation Of Alcohols In N-Oxyl-Immobilized Silica Gel/aqueous Naocl Disperse Systems. A Prominent Access To A Column-Flow System
  作者:Tanaka,Hideo; Chou,Jingyu; Mine,Machiko; Kuroboshi,Manabu
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:2004 卷标:77(9) 页码:1745-1755

海关参考信息

• 2912110000-甲醛
  2912120000-乙醛
  2914110000-丙酮
  2914120000-丁酮
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