N,N-二甲基-1,3-二氨基丙烷置于de-A19 53 263 Catalyst 氢气体系中,140.0 °C,8.0 Mpa 条件下,反应生成 3,3'-亚氨基双(N,N-二甲基丙胺) 参考文献:[de] Verfahren Zur Erhöhung Der Raum-Zeit-Ausbeute (Rza) In Einem Verfahren Zur Herstellung Eines Symmetrischen Sekundären Amins Method For Increasing The Space-Time Yield In A Process Used For The Production Of A Symmetric Secondary Amine[fr] Procede Pour Augmenter Le Rendement Spatio-Temporel (Rza) Dans Un Processus De Production D'Une Amine Secondaire Symetrique 标题:[de] Verfahren Zur Erhöhung Der Raum-Zeit-Ausbeute (Rza) In Einem Verfahren Zur Herstellung Eines Symmetrischen Sekundären Amins Method For Increasing The Space-Time Yield In A Process Used For The Production Of A Symmetric Secondary Amine[fr] Procede Pour Augmenter Le Rendement Spatio-Temporel (Rza) Dans Un Processus De Production D'Une Amine Secondaire Symetrique 摘要:通过在50至250oc温度范围内,在5至350巴绝对压力范围内,通过在氢气和催化剂存在下将一种一级胺转化为对称二级胺的方法,以提高空间-时间产量(rza),方法是在保持温度不变的情况下降低绝对压力.
专利号:US-9951096-B2 优先权日:2008-08-22 标 题 :Catalysts and methods for polymer synthesis 发明人:ALLEN SCOTT D; CHERIAN ANNA E; SIMONEAU CHRIS A; FARMER JAY J; COATES GEOFFREY W; GRIDNEV ALEXEI; LAPOINTE ROBERT E 权利人:SAUDI ARAMCO TECH CO 摘要:The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.
专利号:US-2023111600-A1 优先权日:2019-12-17 标题 :Polymeric fatty acid compounds for the treatment of fibrous amino acid-based substrates, especially hair 发明人:WAGNER ROLAND; STREICHER KATHARINA; ROHMANN LAURA; WENSKE CHRISTIAN; HAVELI SHRUTISAGAR DATTATRAYA 权利人:MOMENTIVE PERFORMANCE MAT GMBH 摘要:The present invention is directed at mono-, di- or polyquaternary ammonium compounds of the formula (I) wherein x is 1 to 50, and F can be the same or different and is represented by the general formula (II) wherein at least one of the optionally substituted and optionally functional-group-containing hydrocarbon radicals R 1 , R 2 , R 3 , R 4 or R 5 contains at least one estolide moiety comprising two or more ester or amide moieties. The invention also relates to a process for the synthesis of such compounds, the use of the compounds in cosmetic formulations for skin and hair care, cosmetic compositions for the treatment of fibers, and compositions containing one or more of the compounds for the treatment of hair.
专利号:US-4348536-A 优先权日:1975-05-28 标 题 :Odorless catalysts for the synthesis of polyurethanes 发明人:BLAHAK JOHANNES; HUEBNER HANS; KOSTER JOHANNES; MEINERS HANS J; THOMAS HEINZ 权利人:BAYER AG 摘要:The instant invention is directed to novel compounds and the use thereof in producing polyurethane resins. The compounds generally correspond to the following formula: wherein n is an integer of from 1 to 5, R is a C1-C5 alkyl group Y is a C1-C5 alkyl group or a and Z is a where n=0 or 1, X is -O- or and R' is an aliphatic group having from 1 to 15 carbon atoms and may contain ester, ether, or amide groups or tertiary nitrogen and, when m=0, R' may be a hydrogen atom.
专利号:WO-2024104923-A1 优先权日:2022-11-16 标 题 :Manganese- and iron-containing catalysts comprising an imine ligand for the synthesis of polyurethanes 发明人:SCHAUB THOMAS; JOOST MAXIMILIAN; SALA OLIVER; RUDDIGKEIT MIRIAM; POELTL JOERG; BOKERN STEFAN; KAMM MARINA; HASHMI A STEPHEN K; OCANSEY EDWARD 权利人:BASF SE 摘要:The present invention relates to a process for the production of a polyurethane comprising the application of a manganese- and iron-containing catalysts wherein the catalyst comprises at least on imine ligand, which is defined by the general formula (I). The catalysts comprise a salicylaldehyde based imine according to the general formula (II) as an imine ligand. The present invention is further directed to a polyol component comprising a catalyst according to the invention, and a polyurethane produced according to such a process.
专利号:US-2013102730-A1 优先权日:2010-04-02 标 题:Polyamine-containing polymers and methods of synthesis and use 发明人:JOST ROBERT W; ULUDAG HASAN; BOLUK MEHMET YAMAN 权利人:JOST ROBERT W; ULUDAG HASAN; BOLUK MEHMET YAMAN; ALBERTA INNOVATES TECHNOLOGY FUTURES 摘要:The present invention relates to polyamine-containing polymers and methods of their synthesis and use. The polymer may be hydroxyethylcellulose, dextran, poly(vinyl alcohol) or poly(methyl acrylate).
专利号:US-2009227701-A1 优先权日:2004-08-19 标题:Water-soluble, radiation-curable products and use thereof 发明人:KRUEGER CHRISTIAN; BRUCHMANN BERND; HEES ULRIKE; KLUGE MICHAEL; DIELEMAN CEDRIC; WEISER JUERGEN 权利人:BASF AG 摘要:Water soluble radiation curable products (A) obtainable by mixingn mixing with or without reaction of at least one hyperbranched polyurethane (a) with at least one photoinitiator (b) or by synthesis of at least one hyperbranched polyurethane (a) in the presence of at least one photoinitiator (b),n nare used to produce aqueous inks for the ink jet process.
[参考文献]: Bogumi Brycki, Et Al. Synthesis, Spectroscopic And Theoretical Studies Of New Dimeric Quaternary Alkylammonium Conjugates Of Sterols. Molecules. 2014 Jul 3;19(7):9419-34. [参考文献]: Xiaochun Han, Et Al. Design, Synthesis And Biological Evaluation Of A Novel Class Of Anticancer Agents: Anthracenylisoxazole Lexitropsin Conjugates. Bioorg Med Chem. 2009 Feb 15;17(4):1671-80.
合成参考文献
摘要:Mase, N., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 193.