CAS: 89171-23-3; Potassium Tetrakis(Perfluorophenyl)Borate

该化合物是有机有机体化合物,其结构和特性独特,包括一种钾和一种四基(pentabrophy)聚苯基阴离子,其中对碳原子进行了四氟苯基阴离子的协调,将之分为四氟苯基共聚物组,有机溶剂的热稳定性和溶性较高,使其在各种化学应用中有用,包括作为有机合成的试剂和某些反应的催化剂;高电阴性氟素的出现,有助于其强大的电子抽取特性,可影响再活性和稳定性;此外,四基氮(pentabrofroflobybybenty)博拉底经常用于制作离子液体和作为电化学研究的辅助电解剂,其独特特性使它在学术研究和工业应用中,特别是在材料科学和有机化学领域,成为有价值的化合物.

英文名称Potassium Tetrakis(Perfluorophenyl)Borate
中文名称四(五氟苯)硼酸钾盐
IUPAC名称potassium tetrakis(perfluorophenyl)borate
其它别名四-(五氟苯)硼酸钾盐; Potassium Tetrakis(Pentafluorophenyl)Borate
CAS编号89171-23-3
MFCD编号:MFCD06797410
分子式:C24BF20K
分子量:718.13
产品CID: 1912882
产品分类有机原料→材料科学→光刻胶材料→光致产酸剂

相似结构搜索
InChIKey: GYBHRIJOPWTIKA-UHFFFAOYSA-N
GYBHRIJOPWTIKA-UHFFFAOYSA-N…
计算化学: 氢键受体数*氢键供体数0.0可旋转键数4.0

相似化合物

149213-65-0 25776-12-9 14680-77-4

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H315-H319-H335
防范说明P261-P264-P271-P280-P302+P352-P304+P340-P362-P405-P501
危险品标志Xi
安全声明H303+H313+H333

合成工艺路线路线简述

2797-28-6 = 89171-23-3
反应条件:1.1 Reagents: Potassium Fluoride Solvents: Methanol; 15 Min,Rt
标题:Silanol-Based Pincer Pt(Ii) Complexes: Synthesis,Structure,And Unusual Reactivity
作者:Korshin,Edward E.; Leitus,Gregory; Shimon,Linda J. W.; Konstantinovski,Leonid; Milstein,David
参考文献:Inorganic Chemistry 日期:2008 卷标:47(16) 页码:7177-7189]

344-04-7 = 89171-23-3
反应条件:1.1 Reagents: 1-Bromopropane,Magnesium Solvents: Diethyl Ether; 1 H,Reflux; 4 H,Reflux1.2 Reagents: Sodium Tetrafluoroborate; 12 H,Reflux1.3 Reagents: Potassium Bromide Solvents: Water
标题:Mechanochemical Synthesis Of Triphenylmethylium And Triphenylcyclopropenylium Tetrakis(Pentafluorophenyl)Borates
作者:Makhaev,V. D.; Galiullin,A. N.; Faingol'D,E. E.; Bravaya,N. M.; Petrova,L. A.
参考文献:Russian Chemical Bulletin 日期:2014 卷标:63(3) 页码:651-656]

79230-20-9 + 178233-71-1 = 89171-23-3
反应条件:1.1 Reagents: Sodium Azide Solvents: Ethanol; 12 H,Rt -> 80 °C1.2 Reagents: Potassium Chloride Solvents: Water
标题:Shelf-Stable (E)- And (Z)-Vinyl-λ3-Chlorane: A Stereospecific Hyper-Vinylating Agent
作者:Watanabe,Yuichiro; Takagi,Taisei; Miyamoto,Kazunori; Kanazawa,Junichiro; Uchiyama,Masanobu
参考文献:Organic Letters 日期:2020 卷标:22(9) 页码:3469-3473]

344-04-7 = 89171-23-3
反应条件:1.1 Reagents: Butyllithium Solvents: Diethyl Ether,Hexane; 70 Min,-78 °C1.2 Reagents: Boron Trichloride; 50 Min,-78 °C; 20 H,Rt1.3 Reagents: Potassium Chloride Solvents: Water; 1 H
标题:Intramolecular Halogen Stabilization Of Silylium Ions Directs Gearing Dynamics
作者:Romanato,Paola; Duttwyler,Simon; Linden,Anthony; Baldridge,Kim K.; Siegel,Jay S.
参考文献:Journal Of The American Chemical Society 日期:2010 卷标:132(23) 页码:7828-7829]

344-04-7 = 89171-23-3
反应条件:1.1 Reagents: Butyllithium Solvents: Diethyl Ether,Hexane; 30 Min,-72 °C; 1.5 H,-72 °C1.2 Reagents: Boron Trichloride Solvents: Hexane; 20 Min; 1 H,-72 °C; 16 H,Rt1.3 Reagents: Potassium Chloride Solvents: Water; 2 H,Rt
标题:Converting Non-Strained γ-Valerolactone And Derivatives Into Sustainable Polythioesters Via Isomerization-Driven Cationic Ring-Opening Polymerization Of Thionolactone Intermediate
作者:Xia,Yongliang; Yuan,Pengjun; Zhang,Yanping; Sun,Yangyang; Hong,Miao
参考文献:Angewandte Chemie 日期:2023 卷标:62(14)]

2797-28-6 = 89171-23-3
反应条件:1.1 Reagents: Potassium Chloride; Rt
标题:Synthesis,Characterization And Biological And Catalytic Activities Of Propionitrile: Ligated Transition Metal Complexes With [b(C6F5)4] As Counter Anion
作者:Ajlouni,Abdulaziz M.; Hijazi,Ahmed K.; Taha,Ziyad A.; Al-Momani,Waleed; Okour,Areen; Et Al
参考文献:Catalysis Letters 日期:2019 卷标:149(8) 页码:2317-2324]

118611-98-6 = 89171-23-3
反应条件:1.1 Reagents: Potassium Bis(Trimethylsilyl)Amide Solvents: Benzene-D6; 5 Min,Rt
标题:Enabling And Probing Oxidative Addition And Reductive Elimination At A Group 14 Metal Center: Cleavage And Functionalization Of E-H Bonds By A Bis(Boryl)Stannylene
作者:Protchenko,Andrey V.; Bates,Joshua I.; Saleh,Liban M. A.; Blake,Matthew P.; Schwarz,Andrew D.; Et Al
参考文献:Journal Of The American Chemical Society 日期:2016 卷标:138(13) 页码:4555-4564]

47855-94-7 = 89171-23-3 + 7782-42-5
反应条件:1.1 Reagents: Graphite,Compd. With Potassium (8:1); 30 Min,Rt
标题:From A (Silatrigerma)Cyclobutenylium Ion To A (Silatrigerma)Cyclobutenyl Radical And Back
作者:Lee,Vladimir Ya.; Ito,Yuki; Gapurenko,Olga A.; Minyaev,Ruslan M.; Gornitzka,Heinz; Et Al
参考文献:Journal Of The American Chemical Society 日期:2020 卷标:142(38) 页码:16455-16460

溴五氟苯置于正丁基锂,三氯化硼,Potassium Chloride体系中,用乙醚,正己烷,水作为反应溶剂,化学反应 23.17H,以76%的收率获得产物四-(五氟苯)硼酸钾盐
参考文献:Competition Between π-Arene And Lone-Pair Halogen Coordination Of Silylium Ions
标题:Competition Between π-Arene And Lone-Pair Halogen Coordination Of Silylium Ions
摘要:In 2,6-Diarylphenylsir(2) Cations,The 2,6-Diarylphenyl (M-Terphenyl) Scaffold Blocks Incoming Nucleophiles And Stabilizes The Positive Charge At Silicon By Lateral Ring Interactions. Direct Ortho-Halogen And Pi-Electron-Rich Face Coordination To Silicon Has Been Seen. For A Series Of Cations Bearing 2,6-Difluoro-2',6'-Dimethyl-X(N)-Substituted Rings,The Relative Contribution Of These Two Modes Of Stabilization Has Been Assessed. Direct Coordination From An Aryl Fluoride Is Found To Be Comparable To That From The Mesityl Pi-Face.
DOI:10.1021/ja2040392

专利信息

专利号:US-9663594-B2
优先权日:2014-05-15
标题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports
发明人：HLAVINKA MARK L
权利人:CHEVRON PHILLIPS CHEMICAL CO LP; CHEVRON PHILIPS CHEMICAL COMPANY LP
摘要:Disclosed herein are methods of making bis(phenol) ligand compounds and transition metal bis(phenolate) compounds. The transition metal bis(phenolate) compounds can be used as components in catalyst systems for the polymerization of olefins.

专利号:EP-3143006-A1
优先权日:2014-05-15
标题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports

专利号:US-9394387-B2
优先权日:2014-05-15
标题:Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports

专利号:US-2015329652-A1
优先权日:2014-05-15
标题 :Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports

专利号:US-2016289351-A1
优先权日:2014-05-15
标题:Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports

专利号:EP-3143006-B1
优先权日:2014-05-15
标题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports

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合成参考文献

摘要:March, T. L.; Duggan, P. J., Science of Synthesis Knowledge Updates, (2014) 1, 392.
摘要:Łaźny, R.; Nodzewska, A., Science of Synthesis Knowledge Updates, (2012) 3, 468.
摘要:Łaźny, R.; Nodzewska, A., Science of Synthesis Knowledge Updates, (2012) 3, 469.
摘要:Rueda-Becerril, M.; Sammis, G. M., Science of Synthesis Knowledge Updates, (2017) 2, 215.
摘要:Pitts, C. R.; Lectka, T., Science of Synthesis Knowledge Updates, (2017) 2, 393.