CAS: 695162-89-1; (11Br)-4-Hydroxy-2,6-Bis(4-Nitrophenyl)Dinaphtho[2,1-D:1',2'-F][1,3,2]Dioxaphosphepine 4-Oxide

该化合物是一个复杂的有机磷化合物,其特点是其独特的结构框架包括二氧磷基.该化合物具有多种芳香硝基苯替代成分,有助于其潜在的电子特性和再活性.氢氧基化合物的存在表明,它可能表现出氢联结能力,影响其溶性以及与其他分子的相互作用.硝基化合物可增强该化合物的电回电特性,有可能影响其在各种化学环境中的稳定性和再活动性.这些化合物经常因其在材料科学,药物和有机合成中间体的应用而受到研究.11bR的指定表明,具体的立体化学在确定化合物的生物活动和与生物目标的相互作用方面也可能发挥关键作用.

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    专利信息


    专利号:US-7517828-B2
    优先权日:2003-04-25
    标 题 :Chiral broensted acid catalyst for asymmetric synthesis and method of asymmetric synthesis with the catalyst
    发明人:AKIYAMA TAKAHIKO
    权利人:TOAGOSEI CO LTD
    摘要:A compound usable as an asymmetric synthesis catalyst which can be easily synthesized without using any metal such as a lanthanoid group element; a method of asymmetric synthesis with the compound; and a chiral compound obtained by the asymmetric synthesis method. A Broensted acid is used as a catalyst in asymmetric synthesis, the chiral Broensted acid being represented by formula (1) below or formula (3) below. The asymmetric synthesis method employs the catalyst. Asymmetric synthesis with the catalyst gives a chiral compound.

    专利号:US-2006276329-A1
    优先权日:2003-04-25
    标题:Asymmetric synthesis catalyst based on chiral brsnsted acid and method of asymmetric synthesis with the catalyst

    专利号:EP-1623971-A1
    优先权日:2003-04-25
    标 题:Asymmetric-synthesis catalyst based on chiral broensted acid and method of asymmetric synthesis with the catalyst

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    合成参考文献


    摘要:Schneider, C.; Sickert, M., Science of Synthesis Knowledge Updates, (2017) 3, 420.
    摘要:Lin, L. L.; Liu, X. H.; Feng, X. M., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 1, 471.
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