9005-53-2 = 488-17-5 + 496-16-2 + 876-02-8 + 90-00-6 + 93-51-6 + 496-78-6 + 527-55-9 + 134-96-3 + 121-33-5 + 90-02-8 + 100-66-3 + 2785-89-9 + 24677-78-9 + 41438-18-0 + 2896-60-8 + 620-17-7 + 1515-95-3 + 100-52-7 + 452-86-8 反应条件:1.1 Catalysts: Choline Chloride,Imidazole; 150 °C 标题:Insights Into Alkaline Choline Chloride-Based Deep Eutectic Solvents Pretreatment For Populus Deltoides: Lignin Structural Features And Modification Mechanism 作者:Li,Haichao; Et Al 参考文献:International Journal Of Biological Macromolecules 日期:2021 卷标:193 页码:319-327
6-Acetoxy-6-Methylcyclohexa-2,4-Dienone置于硫酸体系中,化学反应生成 3-甲基苯邻二酚 参考文献:ber Die Thermische Umlagerung Von Chinolacetaten 标题:ber Die Thermische Umlagerung Von Chinolacetaten 摘要: DOI:10.1007/bf00901754
专利号:US-5200516-A 优先权日:1990-02-16 标 题:Synthesis of sugars from substituted and unsubstituted arene diols 发明人:HUDLICKY TOMAS 权利人:VIRGINIA TECH INTELL PROP 摘要:There are disclosed processes for the synthesis of substituted and unsubstituted arene diols useful in the further synthesis of sugars, sugar derivatives, chiral synthons or amino acids.
专利号:US-5306846-A 优先权日:1990-04-16 标 题:Synthesis of cyclitols from substituted arene diols 发明人:HUDLICKY THOMAS 权利人:VIRGINIA TECH INTELL PROP 摘要:There are disclosed novel processes for the synthesis of novel intermediates useful in the of further synthesis of cyclitols and derivatives thereof.
专利号:US-5488167-A 优先权日:1993-10-18 标题 :Synthesis of sphingosines 发明人:HUDLICKY TOMAS 权利人:VIRGINIA TECH INTELL PROP 摘要:Provided by the present invention is a process for the biocatalytic synthesis of optically pure sphingosines from achiral starting material. The stereoisomers of sphingosine are prepared from chiral arene diols using stereospecific reaction techniques to obtain the desired sphingosine or derivative thereof.
专利号:US-6242602-B1 优先权日:1999-03-29 标 题:One pot synthesis of 5,10-dihydrophenazine compounds and 5,10-substituted dihydrophenazines 发明人:GIRI PUNAM; BYKER HARLAN J; BAUMANN KELVIN L 权利人:GENTEX CORP 摘要:Dihydrophenazines and bis(dihydrophenazines) are prepared in high yield under commercially viable reaction conditions by reacting a catechol with a 1,2-diaminoaryl compound, wherein either the catechol or the 1,2-diaminoaryl compound is provided in at least 50% molar stoichiometric excess. The product may be oxidized to the corresponding phenazine, but is preferably derivatized at one or both of the 5,10-positions to form a monosubstituted or disubstituted dihydrophenazine or bis(dihydrophenazine). Most preferably, 5,10-dialkyl-5,10-dihydrophenazines are prepared starting from catechol and 1,2-diaminoaryl compound in a one pot synthesis. The products are useful as dyes, and in particular as chromophores in electrochromic systems.
专利号:US-2019153154-A1 优先权日:2015-08-20 标题 :Polymers of intrinsic microporosity (pims) containing locked spirobisindane structures and methods of synthesis of pims polymers 发明人:JIN JIANYONG; ZHANG JIAN 权利人:AUCKLAND UNISERVICES LTD 摘要:A method of increasing the rigidity of PIM homo- or co-polymers including repeating units containing at least one biscatechol monomer having a fused spiro-bisindane (SBI) ring system of Formula (I), the SBI ring system including a bicyclic spiro-carbon: (I) wherein each R1 can be the same or different, each R2 can be the same or different and wherein R1 and/or R2 are selected from any one or more of H; straight or branched, saturated or unsaturated lower C1-C6 alkyl groups, wherein the lower alkyl groups can include aromatic or non-aromatic ring structures; R3OR4, R3O(Câ•?O)R4, R3C(â•?O)OR4, or R3OH, wherein each of R3 and R4 are the same or different and are selected from straight or branched, saturated or unsaturated lower C1-C6 alkyl groups; and R5 and R represent suitable linking monomers, wherein the linking monomers can be the same or different and are preferably selected from any one or more tetrahalo aromatic monomers; and wherein the method includes the step of introducing an intra-molecular lock between C1 and C2 of the biscatechol monomer of Formul (I).
专利号:US-7456298-B2 优先权日:2002-06-03 标题:Synthesis of acetonides from aryl silanes 发明人:MCAULIFFE JOSEPH C; WHITED GREGORY M; SMITH WYATT CHARLES 权利人:GENENCOR INT 摘要:The present invention is related to cis-diols and biological methods of producing cis-diols. The present invention further relates to processes for subsequently converting such silane cis-diols to the more stable acetonide derivatives, as well as a process for converting silane cis-diols to the corresponding catechols and the compounds produced thereby. The present invention also provides chemical methods for the conversion of said silane cis-diols and acetonide compounds to epoxy, saturated and otherwise modified derivatives. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that is will not be used to interpret or limit the scope or meaning of the claims.
[参考文献]: L E Hüsken, Et Al. Integrated Bioproduction And Extraction Of 3-Methylcatechol. J Biotechnol. 2001 Jun 1;88(1):11-9. [参考文献]: Anna Andolfi, Et Al. Cyclobotryoxide, A Phytotoxic Metabolite Produced By The Plurivorous Pathogen Neofusicoccum Australe. J Nat Prod. 2012 Oct 26;75(10):1785-91. [参考文献]: E Koivunen, Et Al. Effects Of Plant Species, Stage Of Maturity, And Level Of Formic Acid Addition On Lipolysis, Lipid Content, And Fatty Acid Composition During Ensiling. J Anim Sci. 2015 Sep;93(9):4408-23. [参考文献]: Katarzyna Hupert-Kocurek, Et Al. Characterization Of Catechol 2,3-Dioxygenase From Planococcus Sp. Strain S5 Induced By High Phenol Concentration. Acta Biochim Pol. 2012;59(3):345-51. [参考文献]: Kristina M Mahan, Et Al. Selection For Growth On 3-Nitrotoluene By 2-Nitrotoluene-Utilizing Acidovorax Sp. Strain Js42 Identifies Nitroarene Dioxygenases With Altered Specificities. Appl Environ Microbiol. 2015 Jan;81(1):309-19.
合成参考文献
摘要:Sakya, S. M.; Yang, J., Science of Synthesis Knowledge Updates, (2012) 1, 227. 摘要:Vilhelmsen, M. H., Science of Synthesis Knowledge Updates, (2014) 2, 373. 摘要:Inamoto, K., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 2, 417. 摘要:Herter, S.; Turner, N. J., Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 3, 82. 摘要:Allen, C. C. R., Science of Synthesis: Biocatalysis in Organic Synthesis, (2015) 3, 9.