CAS: 12037-65-9; Phosphanylidynetitanium

该化合物是一种无机化合物,由钛和磷组成,以其高热稳定性和化学抗药性著称;它具有六边形晶体结构,其硬性和耐耐受性具有价值;它用于高温陶瓷,抗腐蚀涂层等专门用途,并用作材料合成的前体;它的半导体特性使其与电子和光电子研究相关;该化合物在极端条件下的稳定性和与其他材料的兼容性使其更适合先进的工业和科学应用;适当处理是必要的,因为它与水分和氧化剂具有共活性.

结构式图片

合成工艺路线路线简述

    专利信息


    专利号:US-2024097109-A1
    优先权日:2021-02-11
    标 题:Bottom-Up, Scalable Synthesis Of Oxide-Based Sub-Nano And Nanofilaments And Nanofilament-Based Two-Dimensional Flakes And Mesoporous Powders
    发明人:BARSOUM MICHEL W; BADR HUSSEIN OSAMA
    权利人:UNIV DREXEL
    摘要:Provided are methods to convert—through a bottom-up approach—binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into lepidocrocitic nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can comprise nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances.

    专利号:WO-2022174264-A1
    优先权日:2021-02-11
    标题:Bottom-up, scalable synthesis of oxide-based sub-nano and nanofilaments and nanofilament-based two-dimensional flakes and mesoporous powders
    发明人:BADR HUSSEIN O; BARSOUM MICHEL W
    权利人:UNIV DREXEL
    摘要:Provided are methods to convert - through a bottom-up approach – binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can be C-containing anatase-based layers that are in turn comprised of nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances. Electrodes made from these materials performed well in energy systems. The materials also reduce the viability of some cancer cells. Also provided are mesoporous materials, devices, and related methods.

    专利号:EP-4291240-A1
    优先权日:2021-02-11
    标题 :Bottom-up, scalable synthesis of oxide-based sub-nano and nanofilaments and nanofilament-based two-dimensional flakes and mesoporous powders

    专利号:CN-117042802-A
    优先权日:2021-02-11
    标题 :Bottom-up scalable synthesis of oxide-based subnanofilaments and nanofilaments and nanofilament-based two-dimensional flakes and mesoporous powders

    专利号:CN-113388100-B
    优先权日:2021-05-28
    标题 :Catalyst system for synthesis of aliphatic-aromatic copolyesters and its application

    专利号:US-2023399760-A1
    优先权日:2022-06-09
    标 题:Electrochemical catalysts and manufacturing method thereof
    发明人:HWANG SEONG-JU; JIN XIAOYAN
    权利人:UNIV YONSEI IACF
    摘要:Proposed are an electrochemical catalyst that can replace platinum by being implemented into a two-dimensional metal nanosheet with a high specific surface area to fully use metal catalyst materials and metal phosphide catalyst materials with excellent electrical conductivity, simultaneously having a simple manufacturing process to facilitate mass synthesis to be capable of implementing an ultra-thin film and a large area to maximize the utilization of catalysts, and a manufacturing method thereof.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:L982: International Programme on Chemical Safety (IPCS) INCHEM (1996). Poison Information Monograph for Phosphine.
    摘要:A291: Singh S, Bhalla A, Verma SK, Kaur A, Gill K: Cytochrome-c oxidase inhibition in 26 aluminum phosphide poisoned patients. Clin Toxicol (Phila). 2006;44(2):155-8.
    摘要:L980: ATSDR - Agency for Toxic Substances and Disease Registry (2002). ToxFAQ for phosphine. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA).
    摘要:A292: Proudfoot AT: Aluminium and zinc phosphide poisoning. Clin Toxicol (Phila). 2009 Feb;47(2):89-100. doi: 10.1080/15563650802520675.
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