CAS: 1072-33-9; Tridecylacetate

该化合物是一个清晰,无色的酯,有温和的水果味,通常用作香味成分和增塑剂. 化学上,它是三丁丙醇的乙酸酯酯酯,具有极强的稳定性和低挥发性,适合高温应用.其疏水性能确保其与非极质基质的兼容性,提高涂料,粘合剂和个人护理配方的性能.作为塑料,它能提高聚合系统的灵活性和耐久性,而不会损害耐热性. 在香气中,它起到长效固定作用,扩大气味特征.该化合物的毒性低,而且环境特征优于监管标准,为工业和化妆品应用提供了多种和可持续的选项.

结构式图片

上下游产品

1-Iodo°Ctane 5-iodopentyl acetate tridecan-1-ol acetic anhydride1-tridecene (+/-)-1,2-epoxytridecane

合成工艺路线路线简述

    📜(8E,10E)-8,10-Tridecadienylacetat 反应生成乙酸十三酯
    参考文献:Waters R. M.; Yoaden D. J.; Warthen J. D. Jr.,Org. Prep. And Proced. Int.,1978,10,No 1,5-8
    标题:Waters R. M.; Yoaden D. J.; Warthen J. D. Jr.,Org. Prep. And Proced. Int.,1978,10,No 1,5-8

    专利信息


    专利号:US-10202620-B2
    优先权日:2014-05-16
    标 题:Synthesis of olefinic alcohols via enzymatic terminal hydroxylation
    发明人:COELHO PEDRO; CHEN MIKE M Y; MEINHOLD PETER; CHO CATHERINE MEE-HIE; BUI VU; HEEL THOMAS
    权利人:PROVIVI INC
    摘要:In certain aspects, the present invention provides methods for producing terminally hydroxylated alkenes and alkynes by contacting an unsaturated or saturated hydrocarbon substrate with a hydroxylase enzyme. Exemplary terminal hydroxylases useful for carrying out the methods of the invention exhibit strong selectivity towards one terminal carbon of a hydrocarbon substrate and include, but are not limited to, non-heme diiron alkane monooxygenases, cytochromes P450 (e.g., cytochromes P450 of the CYP52 and CYP153 family), as well as long chain alkane hydroxylases. In some embodiments, the terminally hydroxylated alkene or alkyne is further converted to a terminal alkenal. In certain embodiments, terminally hydroxylated alkenes and alkynes are useful as insect pheromones which modify insect behavior. In other embodiments, terminally hydroxylated alkenes and alkynes are useful intermediates for producing pheromones via acetylation or oxidation of the alcohol moiety.

    专利号:US-12344573-B2
    优先权日:2018-07-16
    标题:Synthesis of straight-chain lepidopteran pheromones through one- or two-carbon homologation of fatty alkenes
    发明人:WAMPLER KEITH M; LEE CHOON WOO; ROZZELL DAVID
    权利人:PROVIVI INC
    摘要:Methods for the preparation of alkenes including insect pheromones are described. The methods include homologation reactions employing reagents such as 1,3-diesters, epoxides, cyanoacetates, and cyanide salts for elongation of starting materials and intermediates by one or two carbon atoms. The alkenes include insect pheromones useful in a number of agricultural applications.

    专利号:US-11155505-B2
    优先权日:2017-02-17
    标题 :Synthesis of pheromones and related materials via olefin metathesis
    发明人:WAMPLER KEITH M; BUI VU; ROZZELL DAVID; COELHO PEDRO; FLORUTI ARTHUR; ONDI LEVENTE; MEHDI HASAN; EROS GABOR
    权利人:PROVIVI INC
    摘要:Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.

    专利号:US-2023095259-A1
    优先权日:2020-06-01
    标 题:Synthesis of pheromone derivatives via z-selective olefin metathesis

    专利号:WO-2020018581-A1
    优先权日:2018-07-16
    标题 :Synthesis of straight-chain lepidopteran pheromones through one- or two- carbon homologation of fatty alkenes

    专利号:EP-3583088-B1
    优先权日:2017-02-17
    标 题:Synthesis of pheromones and related materials via olefin metathesis

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 32.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知