CAS: 77425-85-5; Trimethyl(Tributylstannylmethyl)Silane

该化合物是一种有机锡化合物,具有独特的结构特征,结合三丁基锡和三甲基硅酸酯组,主要用于有机合成,作为选择性当年和转解反应的试剂,在各种反应条件下保持稳定,与一系列功能组的兼容性使它成为准备复杂的有机金属框架的宝贵中间体.锡和硅基聚醚的存在增强了其在交叉相联和碳碳-碳联结形成反应中的多功能性.由于有机锡化合物具有潜在的毒性,建议谨慎处理.建议在惰性条件下适当储存,以保持其再活性和储量寿命.

英文名称Trimethyl(Tributylstannylmethyl)Silane
中文名称三正丁基(三甲基甲硅烷基甲基)锡
其它别名Silane,trimethyl[(tributylstannyl)methyl]- (9CI); (Tributylstannyl)(trimethylsilyl)methane; [(Trimethylsilyl)methyl]tributyltin
CAS编号77425-85-5
MFCD编号:MFCD00015689
分子式:C16H38SiSn分子量:377.27
产品CID: 1768158
产品分类化学试剂 → 硅烷试剂

相似结构搜索
产品信息参考
InChIKey: IOKUELHTFOPLKK-UHFFFAOYSA-N
1S/C4H11Si.3C4H9.Sn/c1-5(2,3)4;3*1-3-4-2;/h1H2,2-4H3;3*1,3-4H2,2H3;
计算化学: 氢键受体数*氢键供体数*可旋转键数11.0

MSDS等安全信息

警示词warning
危险描述H303 May be harmful if swallowed+H313 Skin contact may be harmful+H333 Inhalation may be harmful to the body
防范说明P264Thoroughly clean after treatmentP280Wear protective gloves/Wear protective clothing/Wear protective goggles/Wear a protective maskP305If it enters the eyesP351Rinse carefully with water for a few minutesP338Remove the contact lens(If any)And easy to operate,Continue flushingP337If eye irritation persistsP313Obtain medical advice/care
UN编号3146
安全声明26-36/37/39
危险类别码20/21/22-36/37/38

上下游产品

tributyltin chloride magnesium Chloromethyltrimethylsilane chloro-trimethyl-silane1,1-Diphenylethylene non-1-ene 4-vinylbenzyl chloride trimethylsilylmethyllithium

合成工艺路线路线简述

合成目标产物 Tri-N-Butyl(Trimethylsilylmethyl)Tin 主要起始原料 Tributyltin Chloride And Magnesium And Chloromethyltrimethylsilane
(文献来源)合成步骤主要原料 Tributyltin Chloride 和 Magnesium 和 Chloromethyltrimethylsilane

📜氯甲基三甲基硅烷,三丁基锡锂以90%的收率获得产物
参考文献:Seitz D. E.; Zapata A.,Tetrahedron Lett.,1980,21,No 36,3451-3454
标题:Seitz D. E.; Zapata A.,Tetrahedron Lett.,1980,21,No 36,3451-3454