CAS: 41756-77-8; Dihydrophaseic Acid
该化合物是一种自然形成的化合物,被归类为植物激素,具体而言,是一种亚丙酸衍生物,主要用于调节植物中的各种生理过程,包括种子开发,宿舍和应激反应;DA的特点是其在促进口服封闭方面的作用,从而帮助植物管理干旱条件下的水流失;DA的化学结构具有双循环框架,有助于其生物活动;典型地存在于各种植物物种中,特别是种子和叶叶中;二氢乙酸也有益于农业研究,因为它有可能用于提高植物对环境压力的抗御能力;CAS号(41756-77-8)用于化学数据库和监管环境中的识别;总的来说,DADP在植物生长和适应方面发挥着至关重要的作用,使其成为植物生理学和生物化学学的重要研究课题.
- 英文名称Dihydrophaseic Acid
- 中文名称二氢菜豆酸
- IUPAC名称(2Z,4E)-5-((1R,3S,5R,8S)-3,8-dihydroxy-1,5-dimethyl-6-oxabicyclo[3.2.1]octan-8-yl)-3-methylpenta-2,4-dienoic acid
- 其它别名(2Z,4E)-3-Methyl-5-[(1S)-1α-Hydroxy-2,6-Dimethyl-2α,6α-(Epoxymethano)-4β-Hydroxycyclohexane-1-Yl]-2,4-Pentadienoic Acid; (2Z,4E)-3-Methyl-5-[(1S)-1α-Hydroxy-2α,6α-(Epoxymethano)-2,6-Dimethyl-4β-Hydroxycyclohexane-1-Yl]-2,4-Pentadienoic Acid; Dihydrophaseic Acid; 2,4-Pentadienoic Acid, 5-[(1R,3S,5R,8S)-3,8-Dihydroxy-1,5-Dimethyl-6-Oxabicyclo[3.2.1]Oct-8-Yl]-3-Methyl-, (2Z,4E)-; (2Z,4E)-3-Methyl-5-[(1S)-1α-Hydroxy-2,6-Dimethyl-2α,6α-(Epoxymethano)-4β-Hydroxycyclohexane-1-Yl]-2,4-Pentadienoic Acid
- CAS编号41756-77-8
- MFCD编号:MFCD20260593
- 分子式:C15H22O5分子量:282.34
- 产品CID: 1431510
- 产品分类天然产物 → 倍半萜
物理性质
MSDS等安全信息
合成工艺路线路线简述
- 2365251-65-4 = 41756-77-8 + 850148-44-6
反应条件:1.1R:Lioh,S:H2O,S:Meoh,S:Dmf,Overnight,Rt1.2R:HCL,S:H2O,Neutralized
标题:Anti-Inflammatory Terpenes From Schefflera Rubriflora C. J. Tseng & G. Hoo With Their Tnf-α And Il-6 Inhibitory Activities
作者:By Li,Fenghua Et Al
参考文献:Phytochemistry (Elsevier 日期:2019 卷标:163 页码:23-32
📜在 水,Lithium Hydroxide体系中,用 甲醇,N,N-二甲基甲酰胺 作为反应溶剂,以12 Mg的收率获得产物二氢菜豆酸
参考文献:Anti-Inflammatory Terpenes From Schefflera Rubriflora C. J. Tseng & G. Hoo With Their Tnf-α And Il-6 Inhibitory Activities
标题:Anti-Inflammatory Terpenes From Schefflera Rubriflora C. J. Tseng & G. Hoo With Their Tnf-α And Il-6 Inhibitory Activities
摘要:The 95% Ethanol Extract And Its Etoac And N-Buoh Fractions Obtained From The Leaves And Twigs Of Schefflera Rubriflora C. J. Tseng & G. Hoo Showed Significant Inhibitory Activities (33.6%,35.7% And 40.6%,Respectively) Against Croton Oil-Induced Ear Inflammation In Mice. Bioactivity-Guided Isolation And Separation Gave Eight Previously Undescribed Terpenes Or Terpene Glycosides. Structural Elucidation Was Based On Uv,Ir,And NMR Spectroscopy,Ms,Experimental And Calculated Ecd Data,And Mosher'S Method. To Identify Anti-Inflammatory Components From The Extract,All The Compounds Were Evaluated For Tumor Necrosis Factor-Alpha (Tnf-Alpha) And Interleukine-6 (Il-6) Inhibitory Activities. Four Undescribed Compounds Inhibited Mrna Expression Of Tnf-Alpha And Il-6 With Ic50 Values Of 15.3-52.4 Mu M.
DOI:10.1016/j.Phytochem.2019.03.021
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2901241000-1,3-丁二烯
2905122000-异丙醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2025178999-A1
优先权日:2022-03-18
标 题:One step synthesis of 1-tetralone compounds and uses thereof in the preparation of (+)-tetralone abscisic acid (aba)
发明人：DIDDI NAVEEN; ABRAMS SUZANNE ROBERTA; LAI LEON
权利人:UNIV SASKATCHEWAN
摘要:The present application is related to a process for preparing 1-tetralone compounds such as compounds of Formula I by reacting a,; 3-unsaturated cyclic ketones that comprise two available hydrogens on the y carbon to the carbonyl with acrolein derivatives with heating in the presence of a suitable organic acid, a suitable organic amine base and suitable inert solvent. For example, the 1-tetralone compound is a tetralone derivative of abscisic acid (ABA).
