CAS: 2652-38-2; Diethoxy(Methyl)(Octyl)Silane

相似化合物

85712-15-8 13501-76-3 18132-63-3

上下游产品

CAS号2031-62-1 甲基二乙氧基硅烷 | CAS号111-66-0 1-辛烯 | CAS号64-17-5 乙醇 | CAS号14799-93-0 二氯(甲基)正辛基硅烷 | CAS号111-87-5 正辛醇

📜甲基二乙氧基硅烷,辛烯置于nickel(II) 2-Ethylhexanoate,2,3-双(2,6-二异丙苯亚氨基)丁烷体系中,用 Neat (No Solvent) 用作溶剂,化学反应 6.0H,以86%的收率获得辛基甲基二乙氧基硅烷
参考文献:使用叔硅烷与α-二胺镍催化剂进行烯烃加氢硅烷化.氧化还原活性配体促进了铂催化剂的独特机理途径
标题:使用叔硅烷与α-二胺镍催化剂进行烯烃加氢硅烷化.氧化还原活性配体促进了铂催化剂的独特机理途径
摘要:容易获得的α二亚胺配体的组合,((氩n = C(me)中)2的ar = 2,6-我镨2-C 6 ħ 3),(的ipr Di)与空气中稳定的镍(II)二(羧酸盐)产生了高活性催化剂,该催化剂对烯烃与多种工业上相关的叔烷氧基和甲硅烷氧基取代的硅烷的氢化硅烷化反应表现出抗马尔科夫尼科夫选择性.连续变化方法与化学计量学研究的结合,正式将氢化镍(i)二聚体[(ipr Di)nih] 2鉴定为还原羧酸盐配体后形成的镍化合物.用于1-辛烯与(eto)的氢化硅烷化3 Sih,[ni] 1/2 [1-辛烯] [(eto)3 Sih]的速率定律与氘标记研究相结合可确定氢化镍二聚体的解离作用,然后快速且可逆地将烯烃插入(ipr Di )nih,与限制周转的c-Si键形成一致.1-辛烯与三乙氧基硅烷的氢化硅烷化反应是有机硅工业中以> 5 000 000 Kg /年的规模进行的反应,以10 G的规模进行,对于所需产物的收率为96%,选择性为>
Doi:10.1021/acscatal.6B01134

专利信息

专利号:US-11033507-B2
优先权日:2013-12-19
标 题 :Method of synthesis of silica vesicles and use thereof
发明人：YU CHENGZHONG; MITTER NEENA; ZHANG JUN
权利人:UNIV QUEENSLAND
摘要:The invention relates, in part, to a method of producing silica vesicles including under controlled conditions to thereby heavily influence the morphology and characteristics of the vesicles. The vesicles are shown to be effective as delivery agents for chemical and biological agents. They are also shown to be useful in methods of treatment and as components of an immunogenic composition.

专利号:US-2022355262-A1
优先权日:2019-07-22
标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites
发明人：SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI
权利人:KROSSLINKER PTE LTD
摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.

专利号:US-2018193278-A1
优先权日:2013-12-19
标题 :Method of synthesis of silica vesicles and use thereof

专利号:CN-105980447-A
优先权日:2013-12-19
标题:Synthesis method and application of silica vesicle