CAS: 13829-21-5; Decyltrichlorosilane

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CAS号872-05-9 正癸烯 | CAS号10026-04-7 四氯化硅 | CAS号17049-50-2 癸基溴化镁 | CAS号112-29-8 溴代正癸烷 | CAS号10025-78-2 三氯氢硅 | CAS号18414-75-0 decyl-trimethyl... | CAS号197842-38-9 10,10-dichlorod... | CAS号155940-67-3 10,10-dichlorod... | CAS号2943-73-9 正癸基三乙氧基硅烷

📜癸基溴置于magnesium,四氯化硅体系中,用 乙醚 用作溶剂,化学反应生成癸基三氯硅烷
参考文献:螺旋魔法.柔性杆螺旋聚硅烯的热驱动手性开关和螺旋感应反转
标题:螺旋魔法.柔性杆螺旋聚硅烯的热驱动手性开关和螺旋感应反转
摘要:一种理想的光学活性螺旋发色聚合物,包含柔性棒状硅主链和对映纯烷基侧链,聚{(S)-3,7-二甲基辛基-3-甲基丁基亚硅烷},在-20°经历热驱动螺旋-螺旋转变c 在异辛烷中.通过光谱分析圆二色性 (Cd) 和紫外吸收特性,可以定量表征转变特征,包括转变温度,转变宽度,右手和左手螺旋图案的数量,全局形状和螺距.这是基于棒状聚合物的独特性质,其中 Cd 波段在所有温度下都与相应的 Uv 波段轮廓完全匹配.而且,精细控制掺入共聚物中的额外手性亚硅烷单元的含量和手性允许在-64 至 +79 oc 范围内自由控制转变温度.分子力学计算表明势能曲线存在显着差异...
Doi:10.1021/ja9938581

专利信息

专利号:US-9379335-B2
优先权日:2012-04-08
标题:Benzodipyrrolidones and their polymers: synthesis and applications for organic electronics and optoelectronics
发明人：CUI WEIBIN; WUDL FRED
权利人:UNIV CALIFORNIA
摘要:Disclosed is the synthesis of benzodipyrrolidone and their polymers and small molecules for electronic and optoelectronic applications. Also disclosed are devices that incorporate such polymers and small molecules.

专利号:US-11033507-B2
优先权日:2013-12-19
标 题 :Method of synthesis of silica vesicles and use thereof
发明人：YU CHENGZHONG; MITTER NEENA; ZHANG JUN
权利人:UNIV QUEENSLAND
摘要:The invention relates, in part, to a method of producing silica vesicles including under controlled conditions to thereby heavily influence the morphology and characteristics of the vesicles. The vesicles are shown to be effective as delivery agents for chemical and biological agents. They are also shown to be useful in methods of treatment and as components of an immunogenic composition.

专利号:US-6444268-B2
优先权日:1998-09-01
标题 :Functionalization of substrate surfaces with silane mixtures
发明人：LEFKOWITZ STEVEN M; FULCRAND GERALDINE; DELLINGER DOUGLAS J; HOTZ CHARLES Z
权利人:AGILENT TECHNOLOGIES INC
摘要:Low surface energy functionalized surfaces on solid supports are provided by treating a solid support having hydrophilic moieties on its surface with a derivatizing composition containing a mixture of silanes. A first silane provides the desired reduction in surface energy, while the second silane enables functionalization with molecular moieties of interest, such as small molecules, initial monomers to be used in the solid phase synthesis of oligomers, or intact oligomers. Molecular moieties of interest may be attached through cleavable sites. Derivatizing compositions for carrying out the surface functionalization process are provided as well.

专利号:US-2019181348-A1
优先权日:2017-09-27
标题 :Branch point effect on structure and electronic properties of conjugated polymers
发明人：BRIDGES COLIN R; WANG MING; FORD MICHAEL J; BAZAN GUILLERMO C; SEGALMAN RACHEL A
权利人:UNIV CALIFORNIA
摘要:Synthesis of lyotropic semiconducting polymers having novel side chains enabling control over crystalline fraction, crystalline orientation, and the unit cell (specifically the Ï€-stacking distance). Moving the branch point in the side chain further from the conjugated backbone not only retains the lyotropic liquid crystalline behavior as observed by UV-vis and POM, but also achieves reduced Ï€-stacking distance. This results in higher charge carrier mobility, reaching (in one or more examples) a mobility of at least 0.41 cm 2 V −1 s −1 when the polymers were non-aligned.

专利号:WO-2010113188-A1
优先权日:2009-03-31
标题 :Fluorurated siliconic polymer, synthesis method and use
发明人：CAPORICCIO GERARDO; MANIERO FRANCESCO; BEVILACQUA MARCO
权利人:MAFLON S R L; CAPORICCIO GERARDO; MANIERO FRANCESCO; BEVILACQUA MARCO
摘要:The present invention relates to a fluorurated siliconic polymer with controlled molecular weight and viscosity having a structure composed by means of the chaining of oligo-dialkylsiloxane building-blocks having a limited and selected molecular weight and alternated mainly with siloxane units containing a fluorurated substituent and - to a marginal degree - inert siloxane units or substituted by unsaturated groups. When the latter are present -they are used for subsequent reactions of clamping or cross-linking. The present invention relates, moreover, to a synthesis method of the mentioned polymer and its use.

专利号:US-2022355262-A1
优先权日:2019-07-22
标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites
发明人：SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI
权利人:KROSSLINKER PTE LTD
摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.