CAS: 98-04-4; Trimethylphenylammonium (Iodide)

该化合物是一种四硝基铵盐,其结构特征是四硝基铵盐,包括附于三甲基酰胺组的苯环和碘化对子体.这种化合物一般是白色到白外晶状固体,由于碘的碘性质,在水和酒精等极地溶解剂中可以溶解.它经常被用作有机合成的阶段转移催化剂,便于反应剂在不易相干阶段之间转移.三甲基胺组的存在提高了它与各种子体互动的能力,使其在需要改进溶性或再活性的化学反应中具有价值.此外,它具有抗微生物特性,可以用于各种用途,包括药物和生物化学化学用途.在处理这种化合物时,应当注意安全防范措施,因为四硝基盐可能是刺激剂,并可能对环境造成危害.

英文名称Trimethylphenylammonium (Iodide)
中文名称三甲基苯基碘化铵
IUPAC名称N,N,N-trimethylbenzenaminium iodide
其它别名Trimethylphenylammonium iodide; N,N,N-Trimethylanilinium iodide
CAS编号98-04-4
MFCD编号:MFCD00011791
EINECS号:202-630-3
FDA UNII编号:4O888XQ7FP
分子式:C9H14IN
分子量:263.12
产品CID: 2485192
产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

相似结构搜索
产品信息参考;;;;
InChIKey: KKLAORVGAKUOPZ-UHFFFAOYSA-M
InChI=1S/C9H14N.HI/c1-10(2,3)9-7-5-4-6-8-9;/h4-8H,1-3H3;1H/q+1;/p-1…
计算化学: 氢键受体数*氢键供体数0.0可旋转键数1.0

MSDS等安全信息

GHS象形图
GHS符号GHS07 & GHS05;
注释: Exclamation mark & Corrosion
危险类别特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼损伤类别1
急性毒性类别3(吸入)
急性毒性类别3(经皮)
急性毒性类别3(经口)
严重眼刺激类别2
警示词Danger(危险)
危险描述H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H318 |造成严重眼损伤.
H331 |吸入会中毒.
H311 |皮肤接触会中毒.
H301 |吞咽会中毒.
H319 |造成严重眼刺激.
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P361+P364-P362+P364-P405-P501
危险等级6.1
UN编号2811.0
危险品标志Xi
包装等级Ⅲ
安全声明26-36/39-37/39
危险类别码36/37/38-41
WGK Germany3.0

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

N-((furan-2-yl)methyl)-N-methylbenzenamine acetone methyl iodide diethyl etherN,N-dimethyl-anilineN,N-dimethyl-aniline N,N,2,6-tetramethylaniline phenyltrimethylammonium chloride trimethylphenylammonium hydroxide

合成工艺路线路线简述

[4-(二甲基氨基)苯基]锂以乙醚,乙醇作为反应溶剂,化学反应生成苯基三甲基碘化铵
参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.2,1.1.2.11,Page 339-345
标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.2,1.1.2.11,Page 339-345

专利信息

专利号:US-6861535-B2
优先权日:2000-12-01
标题:Cyclization method for the synthesis of pyrrolidine derivative compounds
发明人：BULLIARD MICHEL; LABOUE BLANDINE; PLUVIE JEAN-FRANCOIS; ROUSSIASSE SONIA; PINTUS TONY
权利人:PPG SIPSY
摘要:A method for preparing pyrrolidine derivatives comprising cyclizing a compound of formula (I): n n nin the presence of: a) a catalyst, b) a primary amine and c) a base, in a solvent to obtain pyrrolidine derivative of formula (II) below:

专利号:EP-3567040-B1
优先权日:2013-06-24
标题 :Method for the preparation of intermediates useful for the synthesis of [1,2,4]-triazolo[4,3-a]pyridines

专利号:US-2004034235-A1
优先权日:2000-12-01
标题 :Cyclization method for the synthesis of pyrrolidine derivative compounds

专利号:US-2008214386-A1
优先权日:2004-03-01
标题:Catalyst for Cyclic Carbonate Synthesis
发明人：TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
权利人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
摘要:Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.

专利号:EP-3567040-A1
优先权日:2013-06-24
标题 :Method for the preparation of intermediates useful for the synthesis of [1,2,4]-triazolo[4,3-a]pyridines