CAS: 88189-03-1; Bismuth(Iii) Trifluoromethanesulfonate

该化合物是其二甲基混合物中心与三氟甲烷硫酸盐(Triflate)离子体相协调的无机化合物,一般是白色的脱白固体,以其在极地有机溶剂中的溶性而著称.三氟乙烷磺酸特性突出,使其在各种有机反应中起到催化剂作用,特别是在合成复杂分子方面.三氟化物组增强了其再活动性和稳定性,使其能够参与电益替代和其他变异.此外,二氟化物通常被视为重金属催化剂的毒性较低替代品,这增加了其在工业和实验室环境中的吸引力.应谨慎处理该化合物,同时注意所有化学物质,并观察适当的安全措施,以尽量减少接触.

结构式图片

相似化合物

62086-04-8 34946-82-2 2926-27-4

欧盟法规

C&L通报

合成工艺路线路线简述

  • 1493-13-6 = 88189-03-1
    反应条件:1.1 Reagents: Triphenylbismuth; -60 °C; 15 Min,-60 °C; -60 °C -> Rt; 3 H,Rt
    标题:Reactivity Of Tern(Sime3)Bicl2-Synthesis Of An Aminobismuthenium Cation And Tern(Sime3)Bi(N3)2
    作者:Bresien,Jonas; Et Al
    参考文献:Organometallics 日期:2018 卷标:37(15) 页码:2571-2580]

    1493-13-6 = 88189-03-1
    反应条件:1.1 Reagents: Triphenylbismuth Solvents: Toluene
    标题:Aldehyde Bis-Arylation By Metal Triflates Including Bismuth Triflate Powder
    作者:Torisawa,Yasuhiro; Et Al
    参考文献:Organic Process Research & Development 日期:2001 卷标:5(1) 页码:84-88]

    1493-13-6 = 88189-03-1
    反应条件:1.1 Reagents: Bismuth,Oxygen Solvents: Dimethyl Sulfoxide; 100 °C
    标题:Mechanistic Aspects Of The Bismuth-Catalysed Oxidation Of Epoxides To α-Diketones
    作者:Antoniotti,Sylvain; Et Al
    参考文献:European Journal Of Organic Chemistry 日期:2004 卷标:(16) 页码:3459-3464]

    1493-13-6 = 88189-03-1
    反应条件:1.1 Reagents: (3-Mercaptopropyl)Trimethoxysilane,Silica Solvents: Toluene; 24 H,Reflux1.2 Solvents: Diethyl Ether,Dichloromethane; 24 H,Rt1.3 Reagents: Hydrogen Peroxide Solvents: Methanol; 24 H,Reflux1.4 Reagents: Bismuth Trichloride Solvents: Acetonitrile; 24 H,Reflux; Reflux -> Rt1.5 Solvents: Dichloromethane; 12 H,Rt1.6 Solvents: Water; Rt
    标题:Bismuth Sulfonate Immobilized On Silica Gel For Allylation Of Aldehydes And Synthesis Of Homoallylic Amines
    作者:Sreekanth,Pentlavalli; Et Al
    参考文献:Catalysis Letters 日期:2004 卷标:96(3-4) 页码:201-204

专利信息


专利号:WO-2023233371-A1
优先权日:2022-06-03
标 题:A continuous flow process for synthesis of organic azides
发明人:GNANAPRAKASAM BOOPATHY; PANDEY AKANKSHA M; MONDAL SHANKHAJIT
权利人:INDIAN INSTITUTE OF SCIENCE EDUCATION AND RES PUNE IISER PUNE
摘要:The present disclosure relates generally to the field of synthetic organic chemistry. More specifically, the disclosure is directed to a continuous flow process for synthesis of azides from alcohols and peroxides, wherein the process comprises azidation with trimethylsilyl azide and a catalyst Amberlyst-15. It is a non-hazardous, mild and controlled reaction giving good yields of azides. The azides can be further employed for synthesis of medicinally and industrially useful chemicals.

专利号:US-8642766-B2
优先权日:2008-05-05
标题 :Synthesis of (+) cortistatin A and related compounds
发明人:SHENVI RYAN A; GUERRERO CARLOS A; SHI JUN; LI CHUANG-CHUANG; BARAN PHIL S
权利人:SHENVI RYAN A; GUERRERO CARLOS A; SHI JUN; LI CHUANG-CHUANG; BARAN PHIL S
摘要:An in vitro synthesis of (+) cortistatin A from readily available precursors is disclosed, as are the syntheses of related 17-aryl substituted compounds, the 17-aryl substituted compounds themselves and novel compounds useful in their preparation.

专利号:US-10280189-B2
优先权日:2012-07-17
标题:Method for the synthesis of aminoalkylenephosphonic acid
发明人:BURCK SEBASTIAN; LECLERCQ CEDRIC NICOLAS; NOTTE PATRICK
权利人:MONSANTO TECHNOLOGY LLC
摘要:A method for the synthesis of an aminoalkylenephosphonic acid or its phosphonate esters including the following steps: a) forming, in the presence of an aldehyde or ketone and an acid catalyst, a reaction mixture by mixing a compound having at least one HNR 1 R 2 moiety or a salt thereof, with a compound having one or more P—O—P anhydride moieties, the moieties having one P atom at the oxidation state (+III) and one P atom at the oxidation state (+III) or (+V), wherein the ratio of moles of aldehyde or ketone to N—H moieties is 1 or more and wherein the ratio of N—H moieties to P—O—P anhydride moieties is 0.3 or more, and b) recovering the resulting aminoalkylenephosphonic acid having compound or its phosphonate esters.

专利号:US-9676799-B2
优先权日:2012-07-17
标 题 :Method for the synthesis of N-(phosphonomethyl)glycine
发明人:BURCK SEBASTIAN; BRUYNEEL FREDERIC; NOTTE PATRICK
权利人:STRAITMARK HOLDING AG
摘要:A method for the synthesis of N-(phosphonomethyl)glycine or one of its derivatives selected from the group consisting of its salts, its phosphonate esters, or its phosphonate ester salts, which includes the steps of: a) forming, in the presence an acid catalyst, a reaction mixture having 2,5-diketopiperazine, formaldehyde and a compound including one or more P-0-P anhydride moieties, the moieties having one P atom at the oxidation state (+III) and the other P atom at the oxidation state (+III) or (+V), to form N,N′-bisphosphonomethyl-2,5-diketopiperazine, its mono- to tetra phosphonate esters, the dehydrated forms of N,N′-bisphosphonomethyl-2,5-diketopiperazine and the phosphonate esters of its dehydrated forms; and b) hydrolyzing the N,N′-bisphosphonomethyl-2,5-diketopiperazine, its dehydrated forms or their phosphonate esters to obtain N-(phosphonomethyl)glycine or one of its derivatives selected from the group consisting of its salts, its phosphonate esters and its phosphonate ester salts.

专利号:US-10464958-B2
优先权日:2012-07-17
标题 :Method for the synthesis of alpha-aminoalkylenephosphonic acid
发明人:NOTTE PATRICK; COGELS SAMUEL; BURCK SEBASTIAN
权利人:MONSANTO TECHNOLOGY LLC
摘要:The present invention is related to a new method for the synthesis of alpha-aminoalkylenephosphonic acid or its phosphonate esters comprising the steps of forming a reaction mixture by mixing a P—O—P anhydride moiety comprising compound, having one P-atom at the oxidation state (+III) and the other P-atom at the oxidation state (+III) or (+V), an aminoalkanecarboxylic acid and an acid catalyst, wherein said reaction mixture comprises an equivalent ratio of alpha-aminoalkylene carboxylic acid to P—O—P anhydride moieties of at least 0.2, and recovering the resulting alpha-aminoalkylene phosphonic acid compound or an ester thereof from the reaction mixture.

专利号:US-9150599-B2
优先权日:2012-07-17
标 题 :Method for the synthesis of N-(phosphonomethyl)glycine
发明人:BURCK SEBASTIAN; NOTTE PATRICK
权利人:STRAITMARK HOLDING AG
摘要:A method for the synthesis of N-(phosphonomethyl) glycine or one of its derivatives selected from the group of its salts, its phosphonate esters and its phosphonate ester salts, including the steps of: a) forming a reaction mixture having an acid catalyst, N,N′-bis(carboxymethyl)-2,5-diketopiperazine and a compound having one or more P—O—P anhydride moieties, wherein the moieties have one P atom at the oxidation state (+III) and the other P atom at the oxidation state (+III) or (+V), to form N,N′-bis(phosphonomethyl)-2,5-diketopiperazine, its dehydrated forms or their phosphonate esters; b) hydrolyzing the reaction mixture to form N-(phosphonomethyl)glycine or one of its derivatives selected from the group consisting of its salts, its phosphonate esters and its phosphonate ester salts.
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合成参考文献


参考文献:10.1002/chem.200600385
摘要:Kobayashi S, Ogawa C. New entries to water-compatible Lewis acids. Chemistry. 2006 Aug 07;12(23):5954–60. doi: 10.1002/chem.200600385.
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