CAS: 88054-24-4; Deepoxydeoxynivalenol

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CAS号51481-10-8 脱氧瓜萎镰菌醇 | CAS号51550-28-8 Trichothec-9-en...

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  • 51481-10-8 = 88054-24-4
    反应条件:1.1 Reagents: Pyridine Solvents: Acetic Anhydride2.1 Reagents: Hydrogen Bromide Solvents: Acetic Acid,Water3.1 Reagents: Acetic Acid,Zinc Solvents: Acetic Acid4.1 Reagents: Sodium Ethoxide Solvents: Ethanol
    标题:Chemical Deoxygenation Of The Epoxide Moiety In Deoxynivalenol (Vomitoxin)
    作者:King,Russell R.; Et Al
    参考文献:Canadian Journal Of Chemistry 日期:1985 卷标:63(5) 页码:1089-92]

    97186-99-7 = 88054-24-4
    反应条件:1.1 Reagents: Sodium Ethoxide Solvents: Ethanol
    标题:Chemical Deoxygenation Of The Epoxide Moiety In Deoxynivalenol (Vomitoxin)
    作者:King,Russell R.; Et Al
    参考文献:Canadian Journal Of Chemistry 日期:1985 卷标:63(5) 页码:1089-92]

    97186-97-5 = 88054-24-4
    反应条件:1.1 Reagents: Acetic Acid,Zinc Solvents: Acetic Acid2.1 Reagents: Sodium Ethoxide Solvents: Ethanol
    标题:Chemical Deoxygenation Of The Epoxide Moiety In Deoxynivalenol (Vomitoxin)
    作者:King,Russell R.; Et Al
    参考文献:Canadian Journal Of Chemistry 日期:1985 卷标:63(5) 页码:1089-92]

    97186-95-3 = 88054-24-4
    反应条件:1.1 Reagents: Hydrogen Bromide Solvents: Acetic Acid,Water2.1 Reagents: Acetic Acid,Zinc Solvents: Acetic Acid3.1 Reagents: Sodium Ethoxide Solvents: Ethanol
    标题:Chemical Deoxygenation Of The Epoxide Moiety In Deoxynivalenol (Vomitoxin)
    作者:King,Russell R.; Et Al
    参考文献:Canadian Journal Of Chemistry 日期:1985 卷标:63(5) 页码:1089-92
📜3α,7α,15-Triacetoxy-13-Bromo-12-Hydroxytrichothec-7-En-8-One置于sodium Ethanolate,锌体系中,用 乙醇,溶剂黄146 作为反应溶剂,化学反应 0.33H,反应生成 去环氧-脱氧雪腐镰刀菌烯醇
参考文献:King,Russell R.; Greenhalgh,Roy,Canadian Journal Of Chemistry,1985,Vol. 63,P. 1089-1092
标题:King,Russell R.; Greenhalgh,Roy,Canadian Journal Of Chemistry,1985,Vol. 63,P. 1089-1092

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专利信息


专利号:ZA-200502624-B
优先权日:2002-10-30
标题 :Method for the synthesis of a bifunctional complex.

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主要参考文献


1: Pierron A, Bracarense APFL, Cossalter AM, Laffitte J, Schwartz-Zimmermann HE, Schatzmayr G, Pinton P, Moll WD, Oswald IP. Deepoxy-deoxynivalenol retains some immune-modulatory properties of the parent molecule deoxynivalenol in piglets. Arch Toxicol. 2018 Aug 31. doi: 10.1007/s00204-018-2293-x. [Epub ahead of print] doi: 10.1016/j.chroma.2018.04.067. Epub 2018 May 1. pii: E963. doi: 10.3390/molecules23040963. Review. pii: E152. doi: 10.3390/toxins10040152.
5: Vidal A, Claeys L, Mengelers M, Vanhoorne V, Vervaet C, Huybrechts B, De Saeger S, De Boevre M. Humans significantly metabolize and excrete the mycotoxin deoxynivalenol and its modified form deoxynivalenol-3-glucoside within 24 hours. Sci Rep. 2018 Mar 27;8(1):5255. doi: 10.1038/s41598-018-23526-9.
6: Papageorgiou M, Wells L, Williams C, White K, De Santis B, Liu Y, Debegnach F, Miano B, Moretti G, Greetham S, Brera C, Atkin SL, Hardie LJ, Sathyapalan T. Assessment of Urinary Deoxynivalenol Biomarkers in UK Children and Adolescents. Toxins (Basel). 2018 Jan 23;10(2). pii: E50. doi: 10.3390/toxins10020050.

合成参考文献


参考文献:10.1016/j.jchromb.2011.06.036
摘要:De Baere S, Goossens J, Osselaere A, Devreese M, Vandenbroucke V, De Backer P, Croubels S. Quantitative determination of T-2 toxin, HT-2 toxin, deoxynivalenol and deepoxy-deoxynivalenol in animal body fluids using LC-MS/MS detection. J Chromatogr B Analyt Technol Biomed Life Sci. 2011 Aug 15;879(24):2403–15. doi: 10.1016/j.jchromb.2011.06.036.
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