CAS: 489-41-8; (1Ar,4R,4Ar,7R,7As,7Bs)-1,1,4,7-Tetramethyldecahydro-1H-Cyclopropa[e]Azulen-4-Ol

该化合物是一种自然产生的有机化合物,被归类为一种血清酒精,主要来自各种植物来源,特别是某些物种的基本油类.Globulol的特点是其独特的花粉和木香芳香,使其在香味和口味工业中具有价值.该化合物具有复杂的分子结构,有助于其独特的感官特性.从物理特征来看,它一般是一种无色的黄色液体,在室温下,它一般是浅色的黄色液体.Globulol在有机溶剂中表现出中等溶性,在水中不易溶性.其化学反应包括氧化的可能性以及与其他功能组的互动,这可能导致各种衍生物的形成.此外,已经对其潜在的生物活动,包括抗微生物和抗炎特性进行了研究,但还需要进一步研究,以充分理解其治疗用途.

英文名称(1Ar,4R,4Ar,7R,7As,7Bs)-1,1,4,7-Tetramethyldecahydro-1H-Cyclopropa[e]Azulen-4-Ol
中文名称(-)-蓝桉醇
IUPAC名称(1aR,4R,4aR,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol
其它别名Globulol; (1Ar,4R,4Ar,7R,7As,7Bs)-Decahydro-1,1,4,7-Tetramethyl-1H-Cycloprop[e]Azulen-4-Ol
CAS编号489-41-8
MFCD编号:MFCD00042615
EINECS号:207-696-7
FDA UNII编号:G66H9XM0JK
分子式:C15H26O分子量:222.37
产品CID: 1479822
产品分类天然产物 → 倍半萜

相似结构搜索
产品信息参考;;
InChIKey: AYXPYQRXGNDJFU-QTPLKFIXSA-N
InChI=1S/C15H26O/c1-9-5-6-10-12(9)13-11(14(13,2)3)7-8-15(10,4)16/h9-13,16H,5-8H2,1-4H3/t9-,10-,11-,12-,13-,15-/m1/s1
计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数*

MSDS等安全信息

危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
安全声明H303+H313+H333
WGK Germany3

上下游产品

alloaromadendrene R)-4c-phenylcarbamoyloxy-1.1.4t.7c-tetramethyl-(1arH.4atH.7atH.7bcH)-decahydro-1H-cycloprop[e]-azulene(1aR)-4c-phenylcarbamoyloxy-1.1.4t.7c-tetramethyl-(1arH.4atH.7atH.7bcH)-decahydro-1H-cycloprop[e]-azulene ledene (+)-aromadendrene Aphidicolin

合成工艺路线路线简述

489-39-4 = 489-41-8 + 88728-58-9
反应条件:1.1 Reagents: Sodium Bicarbonate,Methyl 4-Nitrobenzenesulfonate Catalysts: Iron(Iii) Acetylacetonate Solvents: Methanol; Rt -> 0 °C1.2 Reagents: Phenylsilane; 0 °C -> Rt; 12 H,Rt
标题:Fe-Catalyzed Anaerobic Mukaiyama-Type Hydration Of Alkenes Using Nitroarenes
作者:Bhunia,Anup; Bergander,Klaus; Daniliuc,Constantin Gabriel; Studer,Armido
参考文献:Angewandte Chemie 日期:2021 卷标:60(15) 页码:8313-8320

📜(1S,2S,4R,7R,8R,11R)-3,3,11-Trimethyl-7-Hydroxymethyl-Tricyclo<6.3.0.02,4>Undecan-7-Ol置于吡啶,Lithium Aluminium Tetrahydride体系中,用四氢呋喃作为反应溶剂,化学反应 3.0H,反应生成 (-)-蓝桉醇
参考文献:Hydroxylation Of Aromadendrane Derivatives By Mucor Plumbeus†
标题:Hydroxylation Of Aromadendrane Derivatives By Mucor Plumbeus†
摘要:7α-羟基和7α,15-二羟基-芳香树脂烷被铅霉有效地在c-14位进行羟基化,同时保留相邻的环丙烷环.
DOI:10.1039/a605991K

海关参考信息

2905122000-异丙醇
2905143000-叔丁醇
2905141000-异丁醇
2905142000-仲丁醇
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-9474270-B2
优先权日:2001-05-08
标题 :Methods and compositions for controlling pests
发明人：SPOONER-HART ROBERT NEIL; BASTA ALBERT HABIB
权利人:BIO-GENE TECH LTD; BIOPROSEPECT LTD; UNIV OF WESTERN SYDNEY
摘要:The present invention is directed to pest-controlling compositions comprising as active ingredients one or more Î²-diones, particularly Î²-diketones and Î²-triketones, and to the use of these compositions inter alia for preventing, eradicating, destroying, repelling or mitigating harmful, annoying or undesired pests including insects, arachnids, helminths, molluscs, protozoa and viruses. The present invention is further directed to processes of preparing Î²-diones by de novo synthesis or from natural sources such as volatile oil-bearing plants from families including Alliaceae, Apiaceae, Asteraceae, Cannabinaceae, Lamiaceae, Pteridaceae, Myrtaceae, Myoporaceae, Proteaceae, Rutaceae and Zingiberaceae.