CAS: 114027-39-3; (3S,3'R,3A'S,6'S,8A'S,9'R)-2'-Ethyl-9'-Hydroxy-1-Methoxy-3A',4',8',8A'-Tetrahydro-3'H,6'H-Spiro[indoline-3,7'-[3,6]Methanooxepino[4,3-B]Pyrrol]-2-One
该化合物是一种自然产生的藻类,产自以其潜在药理特性而闻名的Gelemium植物.该化合物具有一个复杂的结构,其特征是引信环系统,这是许多藻类的典型特征.它在第14个位置上拥有一个氢氧(-OH)功能组,有助于其化学反应和生物活动.这个氢氧基基组的存在可能会提高其在极地溶剂中的溶解性,影响其与生物目标的相互作用.14-Hydroxygelnicine已经就其对...
- 英文名称(3S,3'R,3A'S,6'S,8A'S,9'R)-2'-Ethyl-9'-Hydroxy-1-Methoxy-3A',4',8',8A'-Tetrahydro-3'H,6'H-Spiro[indoline-3,7'-[3,6]Methanooxepino[4,3-B]Pyrrol]-2-One
- 中文名称胡蔓藤碱
- IUPAC名称(3S,3'R,3a'S,6'S,8a'S,9'R)-2'-ethyl-9'-hydroxy-1-methoxy-3a',4',8',8a'-tetrahydro-3'H,6'H-spiro[indoline-3,7'-[3,6]methanooxepino[4,3-b]pyrrol]-2-one
- 其它别名Humantenidine; 14-Hydroxygelsenicine; 14-Hydroxyhumantenmine; Kumantenidine; Spiro[3H-Indole-3,7'(6'H)-[3,6]Methano[3H]Oxepino[4,3-B]Pyrrol]-2(1H)-One, 2'-Ethyl-3'A,4',8',8'A-Tetrahydro-9'-Hydroxy-1-Methoxy-, (3S,3'R,3'As,6'S,8'As,9'R)-
- CAS编号114027-39-3
- MFCD编号:MFCD26406066
- 分子式:C19H22N2O4分子量:342.39
- 产品CID: 172568
- 产品分类天然产物 → 生物碱
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2905122000-异丙醇
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合成参考文献
参考文献:10.1016/s0040-4039(00)82877-4
摘要:Ponglux D, Wongseripipatana S, Takayama H, Ogata K, Aimi N, Sakai S. A new class of indole alkaloid ‘elegansamine’ constructed from a monoterpenoid indole alkaloid and an iridoid. Tetrahedron Letters. 1988;29(42):5395–6. doi: 10.1016/s0040-4039(00)82877-4.
参考文献:10.1016/s0040-4020(01)86012-9
摘要:Ponglux D, Wongseripipatana S, Subhadhirasakul S, Takayama H, Yokota M, Ogata K, Phisalaphong C, Aimi N, Sakai S. Studies on the indole alkaloids of gelsem1um elegans (thailand): structure elucidation and proposal of biogenetic route. Tetrahedron. 1988;44(16):5075–94. doi: 10.1016/s0040-4020(01)86012-9.
参考文献:10.1002/hlca.200900094
摘要:Zhang B, Chou G, Wang Z. Two New 11‐Hydroxy‐Substituted Gelsedine‐Type Indole Alkaloids from the Stems of Gelsemium elegans. Helvetica Chimica Acta. 2009 Sep;92(9):1889–94. doi: 10.1002/hlca.200900094.
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