专利号:US-4468523-A 优先权日:1982-06-16 标题 :Synthesis of dialkyl oxalates by the heterogeneously catalyzed oxidative carbonylation of alcohols 发明人:LEONARD JOHN J; SOFRANKO JOHN A 权利人:ATLANTIC RICHFIELD CO 摘要:Synthesis of dialkyl oxalates by the oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with vanadium in the oxide (V 2 O 5 , V 2 O 4 , V 2 O 3 ) form and titanium or a non-hydrolyzable salt thereof, said catalyst being present in a heterogeneous phase.
专利号:US-4447638-A 优先权日:1982-08-02 标 题 :Preparation of dialkyl oxalates by the oxidative carbonylation of alcohols with a heterogeneous Pd-V-P-Ti containing catalyst system 发明人:GAFFNEY ANNE M; SOFRANKO JOHN A 权利人:ATLANTIC RICHFIELD CO 摘要:Synthesis of dialkyl oxalates by the heterogeneous catalyzed oxidative carbonylation of liquid monohydric saturated alcohols of from 1 to 20 carbon atoms with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a catalytic amount of a catalyst comprising palladium or a salt thereof in combination with a crystalline vanadium-phosphorus-titanium containing compound.
专利号:US-9079164-B2 优先权日:2012-03-26 标题:Single reaction synthesis of texturized catalysts 发明人:WOODFIELD BRIAN F; SMITH STACEY; SELCK DAVID; BARTHOLOMEW CALVIN H; MA XUCHU; XU FEN; OLSEN REBECCA E; ASTLE LYNN 权利人:UNIV BRIGHAM YOUNG 摘要:Methods are described for making a texturized catalyst. The textural promoter may be a high-surface area, high-porosity, stable metal oxide support. The catalyst is manufactured by reacting catalyst precursor materials and support materials in a single, solvent deficient reaction to form a catalyst. The catalyst may be particles or a coating or partial coating of a support surface.
专利号:UA-79539-U 优先权日:2012-10-26 标 题:METHOD OF ELECTROCHEMICAL SYNTHESIS OF CRYSTALLINE TITANIUM SULPHATE (III)
专利号:US-2013267411-A1 优先权日:2012-03-26 标题 :Single reaction synthesis of texturized catalysts
专利号:WO-2020124467-A1 优先权日:2018-12-20 标 题:Oxalate material, preparation method, use, lithium-ion battery cathode material and lithium-ion battery 发明人:TANG YONGBING; YAO WENJIAO; ZHOU XIAOLONG 权利人:SHENZHEN INST ADV TECH 摘要:The present application relates to the technical field of batteries, and relates to an oxalate material, a preparation method, a use, a lithium-ion battery cathode material and a lithium-ion battery. The oxalate material of the present application comprises the following chemical compositions: Li2TMC4O8, wherein TM is a transition metal having charge of plus two. The oxalate material is a polyanionic-based cathode material having dual electrochemical activities and can be used as a lithium-ion battery cathode active material in a lithium-ion battery. With respect to existing lithium-ion battery cathode materials, the present application provides a designing and preparation method for a cathode material having a good safety and high capability. Besides, the synthesis method for the cathode active material is convenient, rapid and safe and all materials are cheap and easily obtained; and the cathode active material is important for optimizing battery material synthesis technique and reducing electrode material preparation cost.
参考文献:10.1007/s10661-018-6697-0 摘要:Ahmadzadeh S, Dolatabadi M. In situ generation of hydroxyl radical for efficient degradation of 2,4-dichlorophenol from aqueous solutions. Environmental Monitoring and Assessment. 2018 May 10;190(6):340. doi: 10.1007/s10661-018-6697-0.