专利号:US-3698864-A 优先权日:1969-05-28 标题 :Synthesis of tetrafluorohydrazine 发明人:GRAKAUSKAS VYTAUTAS 权利人:AEROJET GENERAL CO 摘要:THIS PATENT DESCRIBES A NOVEL PROCESS FOR THE IN SITU PREPARATION OF TETRAFLUOROHYDRAZINE WHICH COMPRISES PASSING FLUORINE INTO AN AQUEOUS SOLUTION OF AN ALKYL CARBAMATE OF THE FORMULA: R-OOC-NH2 WHEREIN R EQUALS ALKYL, AND AN OXIDIZING AGENT, AND COLLECTING THE TETRAFLUOROHYDRAZINE REACTION PRODUCT.
专利号:US-6258981-B1 优先权日:1999-02-17 标 题 :Catalytic oxidation of hydrocarbons 发明人:RICHARDSON DAVID; XU CHENG; ABBOUD KHALIL 权利人:UNIV FLORIDA 摘要:Disclosed are catalysts useful for catalyzing the synthesis of adipic acid from cyclohexane and oxygen. Also disclosed are methods of making the catalysts, methods of using the catalysts to catalyze the production of adipic acid from cyclohexane and oxygen, and kits containing the catalysts.
专利号:US-5670698-A 优先权日:1996-08-19 标 题:Synthesis of 1-acetoxy-2-methylnaphthalene 发明人:LIM MU-ILL; PAN YUH-GUO; STASAITIS LINAS; ANDERSON JAMES 权利人:BRISTOL MYERS SQUIBB CO 摘要:A one pot process is provided in which a Mannich base of the formula 5 is reacted with acetic anhydride to produce a diacetate derivative. Without any intermediate isolation, the derivative is hydrogenated to produce a reaction mixture containing 1-acetoxy-2-methylnaphthalene which is readily precipitated from the reaction mixture by addition of water. ##STR1##
专利号:US-7977269-B2 优先权日:2005-07-21 标 题:Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization 发明人:SMALL BROOKE L; CARNEY MICHAEL 权利人:CHEVRON PHILLIPS CHEMICAL CO 摘要:Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.
专利号:US-7728161-B2 优先权日:2005-07-21 标题:Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization 发明人:SMALL BROOKE L; CARNEY MICHAEL 权利人:CHEVRON PHILLIPS CHEMICAL CO 摘要:Methods for making α-diimine metal complexes are described. The methods comprise forming an α-diimine metal complex imine bond in the presence of a metal salt or an α-acylimine metal complex. The method is particularly using for the production of α-diimine metal complexes having two different α-diimine nitrogen groups. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins.
专利号:EP-1904509-B1 优先权日:2005-07-21 标题:Diimine metal complexes, synthesis, and use in oligomerization and polymerization 发明人:SMALL BROOKE L; CARNEY MICHAEL 权利人:CHEVRON PHILLIPS CHEMICAL CO 摘要:Methods for making α-diimine metal complexes are disclosed. The methods comprise forming an α-diimine metal complex imine bond in the presence of a metal salt or an ce-acylimine metal complex. The method is particularly using for the production of α-diimine metal complexes having two different α-diimine nitrogen groups. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins. Novel α-diimine metal complexes, particularly iron complexes are disclosed. The α-diimine metal complexes are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex, α-diimine metal complexes having two different α-diimine nitrogen groups may be produced. The α-diimine metal complexes are useful for polymerizing or oligomerizing olefins. Processes to polymerize or oligomerize olefins by contacting olefins with α-diimine metal complexes are disclosed. In particular, alpha olefins can be produced in high selectivity by contacting ethylene with selected α-diimine metal complexes.
参考文献:10.1007/s00232-003-0614-2 摘要:Castelli L, Tanzi F, Taglietti V, Magistretti J. Cu 2+ , Co 2+ , and Mn 2+ Modify the Gating Kinetics of High-Voltage-Activated Ca 2+ Channels in Rat Palaeocortical Neurons. Journal of Membrane Biology. 2003 Oct 01;195(3):121–36. doi: 10.1007/s00232-003-0614-2.