CAS: 78560-44-8; Trichloro(1H,1H,2H,2H-Heptadecafluorodecyl)Silane

上下游产品

CAS号21652-58-4 全氟辛基乙烯

1H,1H,2H-全氟-1-癸烯置于dihydrogen Hexachloroplatinate,三氯硅烷体系中,化学反应 70.0H,以86.5%的收率获得产物1H,1H,2H,2H-全氟癸基三氯硅烷
参考文献:金属有机物的合成和反应.十八.(1H,1H,2H,2H-多氟烷基)三甲氧基硅烷的合成及玻璃板的表面改性
标题:金属有机物的合成和反应.十八.(1H,1H,2H,2H-多氟烷基)三甲氧基硅烷的合成及玻璃板的表面改性
摘要:四种硅烷偶联剂,(1H,1H,2H,2H-多氟烷基)三甲氧基硅烷((1H,1H,2H,2H-二十碳氟十二烷基)三甲氧基硅烷,C10F21C2H4Si(och3)3,(1H,1H,2H,2H-十七氟癸基)三甲氧基硅烷,C8F17C2H4Si(och3)3,(1H,1H,2H,2H-十三氟辛基)三甲氧基硅烷,C6F13C2H4Si(och3)3和(1H,1H,2H,2H-九氟己基)三甲氧基硅烷,C4F9C2H4Si(och3)由三氯硅烷与相应的 1H,1H,2H-多氟-1-烯烃在六氯铂酸 (Iv) 存在下氢化硅烷化,然后与甲醇钠反应.尝试使用这些产品对玻璃板进行表面改性.通过测量水和油酸对改性玻璃板表面的接触角 θ (°),发现偶联剂具有高改性能力.
DOI:10.1246/bcsj.66.1754

专利信息

专利号:US-12134280-B2
优先权日:2021-04-02
标 题:Optical device with ordered scatterer arrays for secure identity and a method of producing the same
发明人：TAMULEVICIUS TOMAS; JUODENAS MINDAUGAS; TAMULEVICIENE ASTA; KLINAVICIUS TOMAS; TAMULEVICIUS SIGITAS
权利人:KAUNAS UNIV OF TECHNOLOGY
摘要:An optical device with ordered scatterer arrays for secure identity and a method of producing the sameThis invention discloses a method for configurable spatial control and modification of optically active resonantly coupled scatterer arrays to produce identifiable security features and a corresponding photonic secure identity device. The invention comprises at least the steps of (i) producing a deposition template from said master stamp, (ii) synthesis of a plasmonic particle colloid, (iii) producing an optically active, two-dimensional security tag template using self-assembly of said particles on said deposition template, (iv) producing a customized secure identity device from said security tag template by selective removal or modification of optical properties using ultrashort laser pulses. The produced customized plasmonic-photonic device can then be used as secure identity and anti-counterfeiting means. The device exploits customized spatial control and modification of optically active plasmonic particle arrays demonstrating surface lattice resonance optical signature to produce easily identifiable security features.

专利号:US-11599020-B2
优先权日:2019-03-27
标 题:Polymer-assisted synthesis of nanoparticles
发明人：MIRKIN CHAD A; CHEN PENGCHENG; LIU YUAN; DU JINGSHAN
权利人:UNIV NORTHWESTERN
摘要:A method of preparing a metal nanoparticle can include depositing an ink on a substrate using nanolithography to form a polymer reactor, wherein the ink comprises at least one metalloporphyrin functionalized polymer comprising a metal ion, porphyrin, and a polyethylene oxide polymer; and thermally annealing the polymer nanoreactor under conditions sufficient to form the nanoparticle. The thermal annealing can include a first stage that includes annealing the polymer nanoreactor at a temperature of about 100° C. to about 350° C. for a time sufficient to aggregate the metal ions in the polymer reactor, and a second stage that includes annealing the aggregated polymer nanoreactor at a temperature of about 500° C. to about 600° C. for a time sufficient to reduce the metal ion and decompose a polymer component of the polymer nanoreactor to thereby form the metal nanoparticle.

专利号:WO-2010113188-A1
优先权日:2009-03-31
标题 :Fluorurated siliconic polymer, synthesis method and use
发明人：CAPORICCIO GERARDO; MANIERO FRANCESCO; BEVILACQUA MARCO
权利人:MAFLON S R L; CAPORICCIO GERARDO; MANIERO FRANCESCO; BEVILACQUA MARCO
摘要:The present invention relates to a fluorurated siliconic polymer with controlled molecular weight and viscosity having a structure composed by means of the chaining of oligo-dialkylsiloxane building-blocks having a limited and selected molecular weight and alternated mainly with siloxane units containing a fluorurated substituent and - to a marginal degree - inert siloxane units or substituted by unsaturated groups. When the latter are present -they are used for subsequent reactions of clamping or cross-linking. The present invention relates, moreover, to a synthesis method of the mentioned polymer and its use.

专利号:US-9895673-B2
优先权日:2015-12-01
标题:Functionalized surfaces and preparation thereof
发明人：PECK BILL JAMES; INDERMUHLE PIERRE; MARSH EUGENE P; FERNANDEZ ANDRES; STERN DAVID
权利人:TWIST BIOSCIENCE CORP
摘要:Compositions, devices, methods and systems are provided for differential functionalization of a surface of a structure to support biopolymer synthesis. Provided herein are processes which include use of lamps, lasers, and/or microcontact printing to add functional groups to surfaces for the efficient and uniform synthesis of oligonucleic acids.

专利号:US-11779862-B2
优先权日:2017-02-24
标题:Composite for oil-water separation, synthesis methods and applications of same
发明人：KARABACAK TANSEL; SAADI NAWZAT SAEED; HASSAN LAYLAN BAPPER
权利人:UNIV ARKANSAS
摘要:Certain aspects of the invention relate to a method of synthesizing a composite usably for oil-water separation comprising surface nanostructuring a pristine powder or porous material to form a nanostructured powder or porous material having surfaces with nanoscale features; and coating single or multilayers of one or more low surface energy oligomers, polymers, or their composites with other materials on the surfaces of the nanostructured powder or porous material.

专利号:US-9923142-B2
优先权日:2016-05-31
标 题:Methods of graphene growth and related structures
发明人：CHEN MIIN-JANG; PAN SAMUEL C; HSIEH CHUNG-YEN
权利人:TAIWAN SEMICONDUCTOR MFG CO LTD; UNIV NAT TAIWAN
摘要:A method and structure for providing uniform, large-area graphene by way of a transfer-free, direct-growth process. In some embodiments, a SAM is used as a carbon source for direct graphene synthesis on a substrate. For example, a SAM is formed on an insulating surface, and a metal layer is formed over the SAM. The metal layer may serve as a catalytic metal, whereby the SAM is converted to graphene following an annealing process. The SAM is deposited using a VPD process (e.g., an ALD process and/or an MLD process). In some embodiments, a CNT having a controlled diameter may be formed on the surface of a nanorod by appropriately tuning the geometry of the nanorod. Additionally, in some embodiments, a curved graphene transistor may be formed over a curved oxide surface, thereby providing a band gap in a channel region of the graphene transistor.