专利号:US-3956184-A 优先权日:1974-04-24 标题:Method of preparing silver catalyst for synthesis of formaldehyde by oxidizing methyl alcohol 发明人:KRUGLIKOV ANATOLY ABRAMOVICH; YAKOVENKO ZEMFIRA IVANOVNA; ROZNINA MARINA IVANOVNA; ROGACHEVA ANNA MALOFEEVNA; BELOUSOV GERMAN IVANOVICH 权利人:KRUGLIKOV ANATOLY ABRAMOVICH; YAKOVENKO ZEMFIRA IVANOVNA; ROZNINA MARINA IVANOVNA; ROGACHEVA ANNA MALOFEEVNA; BELOUSOV GERMAN IVANOVICH 摘要:The method of preparing a silver catalyst for synthesis of formaldehyde by oxidizing methyl alcohol which consists in that a carrier is impregnated with an aqueous or an aqueous-alcohol solution containing complex ions of silver having the general formula [Ag(X) n ] + or [Ag(Y) 2 ] - , where X is ammonia, ethylenediamine, triethylenetetramine or triaminotriethylamine, Y is a thiocyanate, cyanide, acetate, or hydroxyl ion, and n is 1 or 2. The impregnated carrier is processed, at a temperature of from 10° - 100°C, with a reducing agent taken in the quantity sufficient to reduce the silver completely from said ion. The thus-prepared catalyst is dried at a temperature of from 80° to 400°C. It is recommended that the catalyst be washed with water before drying. The thus-prepared catalyst has a highly developed active surface with a small content of silver (the specific surface of the catalyst is 0.7 - 7 square meters per gram, with the metal silver content of the catalyst being from 5 - 10 per cent by weight). The catalyst is highly active and has good selectivity in the process of formaldehyde synthesis from methyl alcohol. The yield of formaldehyde with the proposed catalyst is from 75 - 80 per cent, calculating with reference to the passed methyl alcohol, with the selectivity of the process being from 89 - 95 per cent.
专利号:US-6355455-B1 优先权日:1997-07-09 标题 :Method for enzymatic synthesis of sucrose esters 发明人:PAULY GILLES; ENGASSER JEAN-MARC; GHOUL MOHAMMED 权利人:SEROBIOLOGIQUES LAB SA 摘要:A method for the enzymatic synthesis of sucrose ester, comprises introducing, in an adapted reactor and so as to form a reaction medium, predetermined amounts of an organic solvent, a sugar or a sugar derivative, a compound donor of acyl groups and an enzymatic catalyst, the amount of at least one constituent of the reaction mixture being deficient, in controlled addition during the reaction of additional amounts of the deficient constituent(s), and finally purifying the resulting sucrose esters at least by separating the fine enzymatic particles from the solvent.
专利号:WO-2015036637-A1 优先权日:2013-09-13 标题:Method for the synthesis of kojibiose and the application thereof in the production of food and pharmaceutical compositions 发明人:DIEZ MUNICIO MARINA; MORENO ANDUJAR FRANCISCO JAVIER; HERRERO CALLEJA MIGUEL; MONTILLA CORREDERA ANTONIA 权利人:CONSEJO SUPERIOR INVESTIGACION 摘要:The invention relates to a method for the synthesis of kojibiose, characterised by its simplicity and high yield, using a starting reaction mixture containing, as the main compound thereof, the trisaccharide 2-α-D-glucopyranosyl-lactose, O-β-D-galactopyranosyl-(1→4)-O-[α-D-glucopyranosyl- (1→2)]-β-D-glucopyranose, and leucrose, lactose, fructose, glucose and saccharose, said method comprising steps of fermentation, hydrolysis and purification, allowing the production of a disaccharide with high added value, such as kojibiose, in a cost-effective manner. The invention also relates to the kojibiose produced by means of the method according to the invention, and to the use of same in the production of prebiotic food compositions in order to prevent pathologies relating to the gastrointestinal system, and pharmaceutical compositions for treating viral-type diseases or for delaying the digestion of carbohydrates.
专利号:US-2006030625-A1 优先权日:2004-08-06 标 题 :Dietary neurotransmitter precursors for balanced synthesis of neurotransmitters 发明人:HART CHERYLE RAM; GROSSMAN RONALD S; RAM HERBERT 权利人:HART CHERYLE RAM; GROSSMAN RONALD S; RAM HERBERT 摘要:Dietary supplements for treating a neurotransmitter deficiency include one or more precursors of the deficient neurotransmitter and a cofactor for activating in vivo enzymatic synthesis of the deficient neurotransmitter. The dietary supplements can also include an appropriate neurotransmitter, such as an amino acid. When administered through the oral mucosa, increases in levels of the deficient neurotransmitters and relief from deficiency symptoms are obtained.
专利号:US-7960578-B2 优先权日:2007-03-21 标题:Method for the synthesis of peptides without solvent 发明人:MARTINEZ JEAN; LAMATY FREDERIC; DECLERCK VALERIE 权利人:CENTRE NAT RECH SCIENT; UNIV MONTPELLIER I 摘要:The disclosure relates to a method for the synthesis of a compound of the formula (I) in which: n is an integer higher than or equal to 1; Rb and each Rn are independently a hydrogen atom, a C 1 -C 6 arylalkyl group or a C 1 -C 6 alkyl group substituted or not by an aryl group, —COOH, C 1 -C 6 , —COO-(alkyl), —CONH 2 , —SH, heteroaryl, —NH 2 , —NHC(NH)(NH 2 ), C 1 -C 6 -s-(alkyl), —OH or phenol; Ra is a N-protective group; Rc is a ORd group in which Rd is a C 1 -C 6 alkyl group or a NReRf group in which Re and Rf Re independently an N-protective group.
专利号:US-5808019-A 优先权日:1994-12-19 标题 :Intermediate compounds for the synthesis of glycolipids 发明人:HASEGAWA AKIRA; KISO MAKOTO; ISOGAI YUKIHIRO; KITAMURA SEIICHI; UEDA HIROSHI 权利人:TOA BOSHOKU KABUSHIKI KAISHA 摘要:The invention provides important intermediate compounds for the synthesis of acidic glycolipids which are identical with the glycolipid antigens isolated from the acidic glycolipid fractions of peripheral nerve and embryonic central nervous system and preparation methods thereof. By the adoption of the present intermediate compounds, sulfation of 3-hydroxyl group of end glucuronic acid portion of the acidic glycolipid can be quite easily carried out and total synthetic yield be greatly improved.
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