CAS: 4542-77-2; 2,6-Bis(Bromomethyl)Naphthalene

相似化合物

939-26-4 58791-49-4 3163-27-7

上下游产品

2.6-dimethylnaphthalene naphthalene-2,6-dimethanol dimethyl 2,6-naphthalenedicarboxylate 2,6-Bis-acetoxymethyl-naphthalin 2,6-naphthalenedicarbaldehyde cis,cis-2.6-Bis(p-methylstyryl)naphthalen cis,trans-2.6-Bis(p-methylstyryl)naphthalen

📜2,6-二甲基萘置于n-溴代丁二酰亚胺(Nbs),偶氮二异丁腈体系中,用 四氯化碳 作为反应溶剂,化学反应生成 2,6-双(溴甲基)萘
参考文献:Molecular Recognition In Ternary Complexes Ofγ-Cyclodextrin With Naphthalenedicarboxylate Ions And A Space-Regulator Ion
标题:Molecular Recognition In Ternary Complexes Ofγ-Cyclodextrin With Naphthalenedicarboxylate Ions And A Space-Regulator Ion
摘要:在碱性d2O中,γ-环糊精(γ-Cd)与2,6-萘二甲酸根离子(2,6-Ndc)的络合反应在加入2,6-双(1-吡啶基甲基)萘二溴化物(2,6-Pmn)作为空间调节剂后得到了极大增强.通过1H NMR光谱法,结合诱导圆二色光谱和紫外吸收光谱的测量,证实了γ-Cd,2,6-Ndc和2,6-Pmn之间形成1:1:1的三元络合物.通过曲线拟合法分析了在过量2,6-Pmn和ndc区域异构体存在的情况下γ-Cd质子的化学位移(δ)变化,从而得到了ndc与γ-Cd-2,6-Pmn二元络合物的结合常数(k6).k6值按1,5-Ndc < 1,4-Ndc < 1,8-Ndc < 1,3-Ndc < 1,6-Ndc < 2,3-Ndc < 2,7-Ndc < 2,6-Ndc的顺序增加,表明γ-Cd与2,6-Pmn的二元络合物能够识别ndc的分子结构.γ-Cd空腔和2
DOI:10.1246/bcsj.71.2323

专利信息

专利号:US-6495710-B2
优先权日:2000-01-14
标题:Synthesis and use of dimethyl 1,5-naphthalenedicarboxlyates and intermediates therefrom
发明人：MACEK JOHN A; ROSEN BRUCE I; HOLZHAUER JUERGEN K; BRAMLET JOHN S; LILLWITZ LARRY D; SCHNEIDER DAVID J; LANG LAWRENCE L; PASCHKE EDWARD E; WEIS JOHN M; VISWANATH YENAMANDRA; SAKELLARIDES STEFANOS L
权利人:BP CORP NORTH AMERICA INC
摘要:The synthesis of dimethyl-1,5-naphthalenedicarboxylate and polymers and articles formed therefrom is disclosed, as well as applications for dimethyl-1,5-naphthalenedicarboxylate, its corresponding acid 1,5-NDA, and various synthesis intermediates.

专利号:KR-20030044364-A
优先权日:2001-11-29
标 题 :Novel phase transfer catalyst and its application for the synthesis of α-amino acid

专利号:US-2001031852-A1
优先权日:2000-01-14
标 题 :Synthesis and use of dimethyl 1,5-naphthalenedicarboxylates and intermediates therefrom

专利号:EP-1368297-A2
优先权日:2000-01-14
标题:Synthesis and use of dimethyl-1,5-naphthalenedicarboxylates and intermediates therefrom

专利号:JP-2004501862-A
优先权日:2000-01-14
标题 :Synthesis and use of intermediates from dimethyl-1,5-naphthalenedicarboxylate and dimethyl 1,5-naphthalenedicarboxylate

专利号:MX-PA02006832-A
优先权日:2000-01-14
标 题:SYNTHESIS AND USE OF THE 1,5-NAFTALENODICARBOXILATOS DIMETILICOS AND ITS INTERMEDIARIES.