CAS: 34902-57-3; Oxacyclohexadecen-2-One

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    专利号:US-5936100-A
    优先权日:1996-12-16
    标 题:Synthesis of functionalized macrocycles by ring closing metathesis
    发明人:FUERSTNER ALOIS; LANGEMANN KLAUS; KINDLER NICOLE
    权利人:STUDIENGESELLSCHAFT KOHLE MBH
    摘要:The invention concerns an improved process for the preparation of macrocyclic products with 12 or more ring atoms containing one or more polar functional groups on the ring and/or one or more heteroatoms within the ring by ring closing metathesis (RCM) of suitably substituted diene precursors even if the substrates are devoid of any kind of conformational preorganization. Metal carbene complexes of Ru, Mo, W, Re, Os, which are tolerant towards the respective functional group and can either be isolated or prepared in situ are used as catalysts or catalyst precursors. Preferred catalysts or catalyst precursors are ruthenium complexes of the general type XX1LL1Ru=CRR1, wherein X, X1=halogen, L, L1=trialkylphosphine, R, R1=H, Ph, CH=CPh2 denote the most preferred embodiment. The process can be applied to the synthesis of olfactory compounds, perfumary ingredients, pheromones, crown ethers, antibiotics and pharmaceuticals for human and veterinary medicine.

    专利号:US-2010055750-A1
    优先权日:2008-09-03
    标 题:Polyester synthesis
    发明人:WOSNICK JORDAN H
    权利人:XEROX CORP
    摘要:The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners. In embodiments, crystalline copolymers, which are polyesters, may be synthesized from lactones, cyclic anhydrides, cyclic carbonates, and combinations thereof. These crystalline copolymers, in turn, may be utilized in the synthesis of toner particles.

    专利号:WO-2024126092-A1
    优先权日:2022-12-14
    标题:Method for producing 5-hmf by converting a syrup in a non-aqueous solvent with extraction of the syrup water upstream of the synthesis
    发明人:BOURAS MERIEM; DANG THI BICH NGOC; FERNANDEZ ESPADA PASTOR MARIA; LORCET HÉLÈNE; PAGOT ALEXANDRE; BREUIL PIERRE-ALAIN
    权利人:IFP ENERGIES NOW
    摘要:The present invention relates to a method for producing a 5-hydroxymethylfurfural (5-HMF) solution, comprising a step a) of bringing a feedstock comprising a hexose into contact with a synthesis solvent and an acid dehydration catalyst, said step being performed at a temperature of between 30 and 200°C, preferably between 50 and 180°C, more preferably between 70 and 150°C and very preferably between 90 and 130°C, and at a pressure of between 0.001 MPa and 10 MPa, preferably between 0.001 MPa and 5 MPa, more preferably between 0.01 MPa and 1 MPa, obtaining a reaction medium and concomitantly extracting the water from the reaction medium, in order to obtain a synthesis effluent comprising 5-HMF and synthesis solvent.

    专利号:WO-2024126091-A1
    优先权日:2022-12-14
    标 题:Method for producing 5-hmf via conversion of sugar in a non-aqueous solvent with water extraction during synthesis
    发明人:BOURAS MERIEM; DANG THI BICH NGOC; FERNANDEZ ESPADA PASTOR MARIA; LARMIER KIM; LORCET HÉLÈNE; PAGOT ALEXANDRE
    权利人:IFP ENERGIES NOW
    摘要:The present invention relates to a method for producing a solution of 5-hydroxymethylfurfural (5-HMF), the method comprising a step a) of bringing a feedstock comprising a hexose into contact with a synthesis solvent and a dehydration acid catalyst, carried out at a temperature of between 30 and 200°C, preferably between 50 and 180°C, more preferably between 70 and 150°C and very preferably between 90 and 130°C, and at a pressure of between 0.001 MPa and 10 MPa, preferably between 0.001 MPa and 5 MPa, and more preferably between 0.01 MPa and 1 MPa, obtaining a reaction medium and concomitantly extracting the water from the reaction medium, to obtain a synthesis effluent comprising 5-HMF and synthesis solvent.

    专利号:US-2023024035-A1
    优先权日:2021-07-07
    标题 :Zero-copy sparse matrix factorization synthesis for heterogeneous compute systems
    发明人:THUERCK DANIEL; WEBER NICOLAS
    权利人:NEC Laboratories Europe GmbH
    摘要:A system, method, and computer-readable medium for synthesizing zero-copy sparse matrix factorization operations in heterogeneous compute systems are provided. The system includes a host and an accelerator device. The host device is configured to divide an input matrix into a plurality of blocks which are transferred to a memory of the accelerator device. The host device is also configured to generate at least one index buffer that includes pointers to the block in the accelerator's memory, where each index buffer represents a frontal matrix associated with a matrix decomposition algorithm. The host processor is configured to receive one or more kernels configured to process the index buffer(s) on an accelerator device. The index buffers are processed by the accelerator device and the modified block data is written back to a memory of the host device to generate a factorized output matrix.

    专利号:EP-4634165-A1
    优先权日:2022-12-14
    标 题 :Method for producing 5-hmf via conversion of sugar in a non-aqueous solvent with water extraction during synthesis
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