CAS: 16292-17-4; Bis(4-Bromophenyl)Amine

相似化合物

2559740-62-2 54446-36-5 88280-58-4

上下游产品

CAS号122-39-4 二苯胺 | CAS号673-40-5 4-溴硼酸重氮苯四氟硼酸盐 | CAS号4051-56-3 N-Benzoyldiphen... | CAS号5149-12-2 N,N-bis(4-bromo... | CAS号5149-08-6 1,1-bis(4-bromo... | CAS号114687-18-2 | CAS号5467-74-3 4-溴苯硼酸 | CAS号106-40-1 对溴苯胺 | CAS号81090-53-1 4,4-二溴三苯胺 | CAS号6825-20-3 3,6-二溴咔唑 | CAS号102113-98-4 双(4-联苯基)胺 | CAS号499128-71-1 N,N-二(4-联苯基)-N-...

二苯胺置于n-溴代丁二酰亚胺(Nbs)体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 6.0H,以100%的收率获得二(4-溴苯基)胺
参考文献:寻找蓝调兄弟:作为固体魔蓝老化产物的四芳基联苯胺阳离子自由基的 X 射线晶体学/光谱表征†
标题:寻找蓝调兄弟:作为固体魔蓝老化产物的四芳基联苯胺阳离子自由基的 X 射线晶体学/光谱表征†
摘要:幻蓝(mb + ˙ Sbcl 6 −盐),即三-4-溴苯基铵阳离子自由基,是一种常规使用的单电子氧化剂,在储存时在固态下缓慢分解,形成所谓的"蓝兄弟",这通常使情况复杂化氧化过程的定量分析.在此,我们通过结合 Dft 和实验方法,包括分离tab + ˙ Sbcl 6 −及其x 射线晶体学表征.老化的幻蓝样品中tab的形成是通过一对mb的 Scholl 型偶联以及随后分子溴的损失而发生的.对这一事实的认识导致我们合理设计和合成了三(2-溴-4-叔丁基苯基)胺,被称为"布鲁斯表弟"( Bc : E Ox1 = 0.78 V Vs. Fc/fc +,λ Max ( Bc + ˙ ) = 805 Nm,ε Max = 9930 Cm-1 M-1 ),通过将空间要求较高的叔丁基置于芳环的对位,其氧化二聚作用受到显着阻碍.由三苯胺两步合成bc及其阳离子自由基 ( Bc + ˙ ) 的高稳定性保证
Doi:10.1039/c6Ob00140H

专利信息

专利号:WO-2018217538-A1
优先权日:2017-05-23
标题 :Synthesis of substituted acridines
发明人：FORT ERIC H; JAYE JOSEPH A; MCCORMICK GRANT M; BERGER KRISTEN E
权利人:UNIV OF ST THOMAS
摘要:Disclosed is a method of making substituted acridines. The method includes the step of reacting a bis(halophenyl) amine with an alkyne for a time and at a temperature to yield a substituted acridine.

专利号:US-6235871-B1
优先权日:1997-12-03
标题:Synthesis of oligoarylamines, and uses and reagents related thereto
发明人：SINGER ROBERT A; SADIGHI JOSEPH P; BUCHWALD STEPHEN L; MACKEWITZ THOMAS
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:The transition metal-catalyzed amination of aryl halides, in conjunction with an orthogonal protective group scheme, forms the basis of two routes to oligoaniline precursors. The oligoaniline precursors are soluble in a variety of common organic solvents, and are easily converted to the deprotected oligoanilines. The method allows the preparation of oligoanilines of even or odd chain lengths, and the incorporation of a variety of functional groups into the oligomers. Polyanilines of low polydispersity can also be prepared by this method.

专利号:WO-9928290-A1
优先权日:1997-12-03
标 题:Synthesis of oligoarylamines, and uses and reagents related thereto