CAS: 14251-72-0; N,N,N-Trimethylbutan-1-Aminium Chloride

相似化合物

10108-86-8 10108-87-9 112-02-7

上下游产品

CAS号109-69-3 1-氯丁烷 | CAS号75-50-3 三甲胺 | CAS号106-98-9 正丁烯 | CAS号34557-54-5 methane | CAS号927-62-8 N,N-二甲基丁胺 | CAS号75-50-3 三甲胺

氯丁烷,三甲胺 以 甲醇 用作溶剂,化学反应 24.0H,反应生成丁基三甲基氯化铵
参考文献:极性基团xviii.关于n-氯胺氯化的机理:分子间和分子内的抽象
标题:极性基团xviii.关于n-氯胺氯化的机理:分子间和分子内的抽象
摘要:使用六氯丙酮中的分子氯或15%cd 3 Co 2 D / 85%h 2 So 4对-丁基,-戊基和-己基三甲基氯化铵进行光氯化描述了在酸性溶剂中使用n-氯二甲基胺或使用n-氯二甲基胺.铵基团对取代位点具有很强的极性导向作用.发现在极性更强的质子溶剂中这种作用更为明显.N-氯二甲基胺试剂生成了二甲基铵基团,其反应显示出对吸氢的极性敏感性与氯原子相似,但具有更高的仲/伯选择性.从n-氯代-己基甲胺和n-氯代-己胺的自光氯化反应获得的异构体分布的比较酸溶剂中的-戊基甲胺具有通过n-氯二甲基胺氯化铵盐而获得的分布模式,这表明n-氯胺的自氯化反应通过先前提出的分子内氢提取机理进行的.
Doi:10.1016/s0040-4020(01)97198-4

专利信息

专利号:US-2008214386-A1
优先权日:2004-03-01
标题:Catalyst for Cyclic Carbonate Synthesis
发明人：TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
权利人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
摘要:Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.