CAS: 155645-89-9; Silver Oxide
- 英文名称Silver Oxide
- 中文名称氧化银(II)
- IUPAC名称oxosilver
- 其它别名Sildate; Tetrasil; tetrasilver tetroxide
- CAS编号155645-89-9
- 分子式:Ag4O4-4分子量:495.4704
- 产品CID: 772522
- 产品分类无机化工 → 无机盐 → 胶态贵金属及其化合物
- 相似结构搜索
- InChIKey: RARXNJBGGSMBMG-UHFFFAOYSA-N
- 1S/4Ag.4O/q4*+1;4*-2
- 计算化学: 氢键受体数1.0氢键供体数*可旋转键数*
MSDS等安全信息
- 警示词Danger
- 危险描述H272 (97.8%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]
H315 (89.1%): Causes skin irritation [Warning Skin corrosion/irritation]
H319 (89.1%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335 (87%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation] - 防范说明P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501
- 安全声明Metallic silver is oxidized and may deposit in the tissues, causing arygria. The silver ion is known to inhibit glutathione peroxidase and NA+,K+-ATPase activity, disrupting selenium-catalyzed sulfhydryl oxidation-reduction reactions and intracellular ion concentrations, respectively. Silver nanoparticles are believed to disrupt the mitochondrial respiratory chain, causing oxidative stress, reduced ATP synthesis, and DNA damage. (L808, A243, A244, A245, A246)
- 危险类别码A silver(I)-silver(III) oxide; A strong oxidizing agent; A severe skin, eye, respiratory tract, and mucous membrane irritant; [Merck Index] An oxidizing agent that may cause fire on contact with combustible materials; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Silver.
合成工艺路线路线简述
📜氧气,银 以 Gaseous Matrix 用作溶剂,化学反应生成氧化银(II)
参考文献:The Millimeter Wave Spectrum Of Silver Monoxide,Ago
标题:The Millimeter Wave Spectrum Of Silver Monoxide,Ago
摘要:The Pure Rotational Spectra Of Ago107 And Ago109 Were Recorded In The 117-380 Ghz Spectral Region Using A Dc-Sputtering Absorption Cell. The Ag107(I=1/2) And Ag109(I=1/2) Magnetic Hyperfine Parameters Are Interpreted In Terms Of Plausible Electronic Configuration Contributions To The X 2πi State. It Is Shown That The Determined Unusual Sign Of The λ-Doubling And Fermi Contact Parameters Implies That The X 2πi State Is Dominated By A Three Open Shell Configuration. A Comparison With Isovalent Cuo Is Made.
Doi:10.1063/1.476196
