CAS: 15165-67-0; Dichlorprop-P

该化合物是一种多用途化学配方,主要用作有机合成和工业应用的中间体.它由二氯丙烷异构体组成,具有有利的溶解性,适合粘合剂,涂料和专用清洁配方.它表明在标准储存条件下具有稳定性,与一系列有机化合物相容.它受控制的反作用允许在化学工艺中,包括氯化反应和聚合物生产中精确应用.产品通常以标准化浓度供应,以确保工业使用的一致性.由于卤化性质,应当遵循适当的处理程序.

结构式图片

相似化合物

25140-86-7 15165-69-2 98919-13-2

欧盟法规

统一分类与标签REACH注册ECHA物质工作场所安全标识要求欧盟农药活性物质ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号120-36-5 2,4-滴丙酸 | CAS号23844-57-7 dichlorprop-methyl | CAS号58048-38-7 2-(2,4-dichloro... | CAS号62784-66-1 二-1-萘甲醇 | CAS号1356837-79-0 (R,S)-2-(2,4-di...

合成工艺路线路线简述

    📜2,4-二氯酚置于bode's Catalyst,Palladium 10% On Activated Carbon,氢气,Caesium Carbonate,N,N'-二环己基碳二亚胺,Sodium Hydroxide体系中,用 四氢呋喃,乙醇,二氯甲烷 用作溶剂,化学反应 66.0H,反应生成(R)-2-(2,4-二氯苯氧基)丙酸
    参考文献:通过卡宾催化的动态动力学拆分和酯交换获得光学富集的 α-芳氧基羧酸酯.
    标题:通过卡宾催化的动态动力学拆分和酯交换获得光学富集的 α-芳氧基羧酸酯.
    摘要:光学活性α-芳氧基羧酸及其衍生物是重要的功能分子.这里公开了一种卡宾催化的动态动力学拆分和酯交换反应,用于以高达 99% 的收率和 99:1 的 Er 值获得这类分子.将手性卡宾催化剂添加到酯底物中会产生两种非对映体唑鎓酯中间体,它们可以快速彼此差向异构化,从而实现有效的动态动力学拆分.我们反应中的光学富集酯产物可以快速转化为手性除草剂和其他生物活性分子.
    Doi:10.1021/acs.Orglett.0C00748

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:ES-2717283-T3
    优先权日:2012-07-24
    标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Angela Schaner, Et Al. Determination Of Chlorinated Acid Herbicides In Vegetation And Soil By Liquid Chromatography/electrospray-Tandem Mass Spectrometry. J Aoac Int. 2007 Sep-Oct;90(5):1402-10.
    [参考文献]: Arthur W Garrison, Et Al. Analysis Of The Enantiomers Of Chiral Pesticides And Other Pollutants In Environmental Samples By Capillary Electrophoresis. Methods Mol Biol. 2008:384:157-70.
    [参考文献]: C Caballo, Et Al. Stereoselective Quantitation Of Mecoprop And Dichlorprop In Natural Waters By Supramolecular Solvent-Based Microextraction, Chiral Liquid Chromatography And Tandem Mass Spectrometry. Anal Chim Acta. 2013 Jan 25:761:102-8.
    [参考文献]: Christiane Hoppe-Jones, Et Al. The Role Of Microbial Adaptation And Biodegradable Dissolved Organic Carbon On The Attenuation Of Trace Organic Chemicals During Groundwater Recharge. Sci Total Environ. 2012 Oct 15:437:137-44.
    [参考文献]: Emeline L Maillet, Et Al. Phenoxy Herbicides And Fibrates Potently Inhibit The Human Chemosensory Receptor Subunit T1R3. J Med Chem. 2009 Nov 12;52(21):6931-5.

    合成参考文献


    参考文献:10.1007/s00253-003-1511-4
    摘要:Mller TA, Kohler H-E. Chirality of pollutants effects on metabolism and fate. Applied Microbiology and Biotechnology. 2004 Apr 01;64(3):300–16. doi: 10.1007/s00253-003-1511-4.
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