CAS: 918-84-3; 3-Chloro-3-Methylpentane

该化合物是一种卤代烷,含有分子式C6H13Cl,该化合物的特点是其氯和甲基替代成分在五角骨的三级碳中具有独特的回活性,在有机合成中具有独特的回活性,是生产药品,农用化学品和特殊化学品,特别是核生殖替代和消化反应的多种媒介.第三氯通过 Grignard或混合反应,增强了其形成碳-碳联结的效用.在受控条件下,其明确界定的结构和稳定性使其适合精确的合成应用.由于易燃性和潜在的健康危害,需要妥善处理.

结构式图片

相似化合物

6223-78-5 43197-78-0 4325-48-8

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报

上下游产品

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合成工艺路线路线简述

  • 616-12-6 = 918-84-3
    反应条件:1.1 Reagents: Chlorotrimethylsilane,Water
    标题:Trimethylchlorosilane And Water. Convenient Reagents For The Regioselective Hydrochlorination Of Olefins
    作者:Boudjouk,Philip; Kim,Beon-Kyu; Han,Byung-Hee
    参考文献:Synthetic Communications 日期:1996 卷标:26(18) 页码:3479-3484]

    = 918-84-3
    反应条件:1.1 Reagents: Hydrochloric Acid
    标题:Catalyst-Free Process For The Continuous Preparation Of Branched Alkyl Halides By The Addition Reaction Of Branched Alkenes With Hydrogen Halides
    参考文献:European Patent Organization]

    = 918-84-3
    反应条件:1.1 Reagents: Hydrochloric Acid,Sodium Chloride Solvents: Water1.2 Catalysts: Tetrabutylammonium Chloride,Silver (Nanoparticle Ag Supported On Agcl),Silver Chloride; 6 H,Rt
    标题:Process For Selective Halogenation Of Tertiary Hydrogen In Alkanes
    参考文献:China]

    = 918-84-3
    反应条件:1.1 Reagents: Hydrochloric Acid
    标题:Synthesis Of Selectively Deuterated 3-Methylpentanes
    作者:Ohta,Nobuaki; Ninomiya,Hirobumi; Ichikawa,Takahisa
    参考文献:Hiroshima Daigaku Kogakubu Kenkyu Hokoku 日期:1984 卷标:32(2) 页码:141-4]

    507-40-4 = 918-84-3 [标题:Reaction Conditions
    标题:Trialkylborane-Induced Chlorinations Of Alkane With Chlorine,Tert-Butyl Hypochlorite And N-Chlorosuccinimide
    作者:Hoshi,Masayuki; Masuda,Yuzuru; Arase,Akira
    参考文献:Chemistry Letters 日期:1984 卷标:(2) 页码:195-8]

    = 918-84-3
    反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water; 20 Min,0.22 Mpa,85 °C
    标题:Preparation Of Halogenated Hydrocarbons In Continuous Flow Microchannel Reactor
    参考文献:China]

    = 918-84-3 [标题:Reaction Conditions
    标题:An N-Heterocyclic Carbene-Based Nickel Catalyst For The Kumada-Tamao-Corriu Coupling Of Aryl Bromides And Tertiary Alkyl Grignard Reagents
    作者:Ando,Shin; Mawatari,Mai; Matsunaga,Hirofumi; Ishizuka,Tadao
    参考文献:Tetrahedron Letters 日期:2016 卷标:57(30) 页码:3287-3290]

    922-62-3 = 918-84-3 [标题:Reaction Conditions
    标题:Synthesis By Addition To π-Type C-C Bonds
    作者:Roy,K.-M.
    参考文献:Science Of Synthesis 日期:2007 卷标:35 页码:103-115]

    = 918-84-3 + 4737-41-1 + 62168-41-6 + 25346-31-0 + 3814-34-4 + 24319-09-3 + 62016-93-7 + 51116-73-5
    反应条件:1.1 Reagents: Bromotrichloromethane,2769993-47-5 Solvents: Nitromethane; 5 Min,Rt; Cooled; 24 H,28 °C
    标题:Taming The Chlorine Radical: Enforcing Steric Control Over Chlorine-Radical-Mediated C-H Activation
    作者:Gonzalez,Miguel I.; Gygi,David; Qin,Yangzhong; Zhu,Qilei; Johnson,Elizabeth J.; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2022 卷标:144(3) 页码:1464-1472]

    = 918-84-3
    反应条件:1.1 Reagents: Chlorotrimethylsilane1.2 Reagents: Dimethyl Sulfoxide
    标题:Conversion Of Alcohols To Chlorides By Tmscl And Dmso
    作者:Snyder,Dudley C.
    参考文献:Journal Of Organic Chemistry 日期:1995 卷标:60(8) 页码:2638-9]

    = 918-84-3
    反应条件:1.1 Reagents: (T-4)-Dichloro(1,10-Phenanthroline-Kn1,Kn10)Copper,1-Azido-1,2-Benziodoxol-3(1H)-One Solvents: 1,2-Dichloroethane; 48 H,Rt
    标题:Site Selective Chlorination Of C(Sp3)-H Bonds Suitable For Late-Stage Functionalization
    作者:Fawcett,Alexander; Keller,M. Josephine; Herrera,Zachary; Hartwig,John F.
    参考文献:Angewandte Chemie 日期:2021 卷标:60(15) 页码:8276-8283]

    = 918-84-3
    反应条件:1.1 Reagents: Hydrochloric Acid
    标题:Study Of Organic Oxides. Xxxix. Reaction Of Unsaturated α-Oxides With Group Ii A Organometallic Compounds
    作者:Razina,R. S.; Kulina,L. A.; Al'Bitskaya,V. M.
    参考文献:Zhurnal Obshchei Khimii 日期:1979 卷标:49(5) 页码:1047-50]

    = 918-84-3 [标题:Reaction Conditions
    标题:Studies On Sulfochlorination Of Paraffins. Ix. Characteristics Of The Sulfochlorination Of Branched-Chain Paraffins
    作者:Estel,D.; Mateew,K.; Pritzkow,W.; Schmidt-Renner,W.
    参考文献:Journal Fuer Praktische Chemie (Leipzig) 日期:1981 卷标:323(2) 页码:262-8]

    = 918-84-3 [标题:Reaction Conditions
    标题:Trialkylborane-Induced Chlorination Of Alkanes With Iodobenzene Dichloride
    作者:Arase,Akira; Hoshi,Masayuki; Masuda,Yuzuru
    参考文献:Chemistry Letters 日期:1979 卷标:(8) 页码:961-4]

    = 918-84-3 + 25346-32-1
    反应条件:1.1 Reagents: Zinc Chloride; 10 H,25 °C
    标题:Use Of Compositions Obtained By Calcing Particular Metal-Accumulating Plants For Implementing Catalytical Reactions
    参考文献:European Patent Organization]

    = 918-84-3 + 4325-48-8
    反应条件:1.1 Catalysts: Zinc Chloride; 10 H,25 °C
    标题:Use Of Metal-Accumulating Plants For The Preparation Of Catalysts That Can Be Used In Chemical Reactions
    参考文献:World Intellectual Property Organization]

    = 918-84-3
    反应条件:1.1 Reagents: Acetic Acid,Iron Chloride (Fecl3),1-Butanaminium,N,N,N-Tributyl-,(T-4)-Nitridotrioxoosmate(1-) (1:1) Solvents: Dichloromethane,Water; 30 S,23 °C
    标题:Fecl3-Activated Oxidation Of Alkanes By [os(N)O3]-
    作者:Yiu,Shek-Man; Wu,Zhi-Biao; Mak,Chi-Keung; Lau,Tai-Chu
    参考文献:Journal Of The American Chemical Society 日期:2004 卷标:126(45) 页码:14921-14929]

    = 918-84-3 + 4737-41-1 + 24319-09-3 + 62016-93-7
    反应条件:1.1 Reagents: (Trifluoromethyl)Benzene,Cesium Carbonate,N-Chloro-N-(1,1-Dimethylethyl)-3,5-Bis(Trifluoromethyl)Benzamide Catalysts: Benzoyl Peroxide; Rt -> 65 °C; 7 H,65 °C; Rt -> 65 °C; 17 H,65 °C
    标题:Reagent-Dictated Site Selectivity In Intermolecular Aliphatic C-H Functionalizations Using Nitrogen-Centered Radicals
    作者:Carestia,Anthony M.; Ravelli,Davide; Alexanian,Erik J.
    参考文献:Chemical Science 日期:2018 卷标:9(24) 页码:5360-5365]

    = 918-84-3 + 4737-41-1 + 53521-23-6 + 53520-46-0 + 62016-93-7
    反应条件:1.1 Reagents: Carbon Tetrachloride,N-(1,1-Dimethylethyl)-N-[(1-Phenylethenyl)Oxy]-3,5-Bis(Trifluoromethyl)Benzamide Solvents: (Trifluoromethyl)Benzene; 16 H,Rt -> 60 °C
    标题:Diversification Of Aliphatic C-H Bonds In Small Molecules And Polyolefins Through Radical Chain Transfer
    作者:Fazekas,Timothy J.; Alty,Jill W.; Neidhart,Eliza K.; Miller,Austin S.; Leibfarth,Frank A.; Et Al
    参考文献:Science (Washington 日期:2022 卷标:375(6580) 页码:545-550
📜2-乙基丁酸乙酯置于盐酸,Zinc(II) Chloride体系中,化学反应生成 3-氯-3-甲基戊烷
参考文献:Whitmore; Karnatz,Journal Of The American Chemical Society,1938,Vol. 60,P. 2535
标题:Whitmore; Karnatz,Journal Of The American Chemical Society,1938,Vol. 60,P. 2535

海关参考信息

专利信息


专利号:US-9744391-B2
优先权日:2009-11-26
标 题:Use of metal-accumulating plants for implementing chemical reactions
发明人：GRISON CLAUDE; ESCARRE JOSE
权利人:CENTRE NAT RECH SCIENT; UNIV MONTPELLIER 2 SCIENCES ET TECHNIQUES
摘要:A method of implementing organic synthesis reactions uses a composition containing a metal catalyst originating from a calcined plant. The plants can be from the Brassicaceae, Sapotaceae and Convolvulaceae family, and the metal catalyst contains metal in the M(II) form such as zinc, nickel, manganese, lead, cadmium, calcium, magnesium or copper. Examples of the organic synthesis reactions include halogenations, electrophilic reactions, cycloadditions, transesterification reactions and coupling reactions, among others.

专利号:US-3801667-A
优先权日:1971-11-09
标题 :Cyclic isoprene process
发明人：SCHNEIDER A
权利人:SUN RESEARCH DEVELOPMENT
摘要:A MULTI-STEP SYNTHESIS FOR THE PRODUCTION OF ISOPRENE IS PROVIDED WHEREIN CERTAIN BY-PRODUCTION ARE RECYCLED IN ORDER TO ACHIEVE A BALANCED, ECONOMICAL PROCESS. THE PROCESS IS PRINCIPALLY CHARACTERIZED BY THE STEPS OF OXIDIZING ISOBUTANE TO FORM T-BUTYL HYDROPEROXIDE WHICH IS REACTED WITH PROPYLENE TO GIVE T-BUTYL ALCOHOL AND THE VALUABLE BY-PRODUCT PROPYLENE OXIDE. THE ALCOHOL, AFTER CONVERSION TO T-BUTYL CHLORIDE IS REACTED WITH METHYLPENTANES TO GIVE ISOBUTANE AND METHYLCHLOROPENTANES. THESE LATTER COMPOUNDS ARE THEN DEHYDROCHLORINATED TO YIELD HCL AND METHYLPENTENES WHICH ARE PYROLYZED TO FORM ISOPRENE. THE ISOBUTANE CO-PRODUCED WITH THE METHYLCHLOROLPENTANES IS DESIRABLY RECYCLED TO THE FIRST STAGE OXIDATION STEP, WHILE THE HCL FORMED IN THE NEXT-TO-LAST STEP MAY BE EMPLOYED IN THE FURTHER FORMATION OF T-BUTYL CHLORIDE.

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合成参考文献


摘要:Roy, K.-M., Science of Synthesis, (2007) 35, 107.
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