CAS: 629-63-0; Tetradecanenitrile

该化合物是分子式C14H27N的饱和性脂硝酸盐,其特点是碳氢化合物链长和极地硝酸盐功能组,使其成为有机合成的多功能中间体,主要优点包括:在标准条件下保持稳定,精确反应的纯度高,以及作为脂肪酸衍生物,表面活性剂和特殊化学物质的前体的效用.其疏水性及其与非极溶剂的兼容性进一步增强了其在工业和研究环境中的可适用性. Ttradcaniterile因其在恐吓,氢化和其他微粒特定转化过程中的一贯性能而受到重视.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

tetradecanamide n-tetradecanoic acid 1-Bromotetradecane 1-iodo-n-undecane°Ctadecan-5-one pentadecan-2-one heptadecan-4-one 1-phenyl-tetradecan-1-one

合成工艺路线路线简述

    📜1-十五醇置于2,3'-联吡啶,Ammonium Hydroxide,Copper(L) Iodide,2,2,6,6-四甲基哌啶氧化物,氧气体系中,用 乙腈 作为反应溶剂,化学反应 24.0H,以90%的收率获得产物十四腈
    参考文献:Highly Practical Synthesis Of Nitriles And Heterocycles From Alcohols Under Mild Conditions By Aerobic Double Dehydrogenative Catalysis
    标题:Highly Practical Synthesis Of Nitriles And Heterocycles From Alcohols Under Mild Conditions By Aerobic Double Dehydrogenative Catalysis
    摘要:A Mild,Aerobic,Catalytic Process For Obtaining Nitriles Directly From Alcohols And Aqueous Ammonia Is Described. The Reaction Proceeds Via A Dehydrogenation Cascade Mediated By Catalytic Cui,Bpy,And Tempo In The Presence Of O-2. The Substrate Scope Is Broad Including Various Functionalized Aromatic And Aliphatic Alcohols. This Protocol Enabled The One-Pot Synthesis Of Various Biaryl Heterocycles Directly From Commercially Available Alcohols.
    DOI:10.1021/ol400459Y

    海关参考信息

    专利信息


    专利号:US-4219684-A
    优先权日:1979-04-02
    标 题 :Synthesis of alcohols by hydroformylation with nitrile promoter
    发明人：IMAI TAMOTSU
    权利人:UOP INC
    摘要:Alcohols may be synthesized by reacting an olefinic compound, carbon monoxide and hydrogen in the presence of a Group VIII organometallic complex catalyst at reaction conditions which include a temperature in the range of from about 50° to about 250° C. and a pressure in the range of from about 10 to about 300 atmospheres. In addition, the reaction is also effected in the presence of a promoter compound comprising a nitrile.

    专利号:GB-2049673-A
    优先权日:1979-04-02
    标题:Synthesis of Alcohols

    专利号:CN-107141405-B
    优先权日:2017-05-24
    标题:A kind of latent thiol-containing self-crosslinkable resin, its cured product, and synthesis method

    专利号:CN-107141405-A
    优先权日:2017-05-24
    标 题 :A kind of latent mercaptan-containing self-crosslinkable resin, its cured product, and synthesis method

    专利号:CN-107033330-A
    优先权日:2017-05-24
    标 题:A kind of latent thiol group-containing resin, its cured product with epoxy resin, and its synthesis method

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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Muna ZA, Doudin K, Songstad J, Ulvik RJ, Berge RK. Tetradecylthioacetic acid inhibits the oxidative modification of low density lipoprotein and 8-hydroxydeoxyguanosine formation in vitro. Arterioscler Thromb Vasc Biol. 1997 Nov;17(11):3255-62.

    合成参考文献


    摘要:Thomas, E. J., Science of Synthesis, (2003) 5, 3.
    摘要:Jończyk, A.; Kowalkowska, A., Science of Synthesis, (2006) 8, 1169.
    摘要:Subramanian, L. R., Science of Synthesis, (2004) 19, 79.
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