CAS: 2478-38-8; 1-(4-Hydroxy-3,5-Dimethoxyphenyl)Ethanone

该化合物是植物生物技术和分子生物学中广泛使用的一种酚类化合物,因为它是农业除虫剂媒介基因变异的强大诱导剂,其主要优势在于它能够激活农用菌中的病毒基因表达,提高T-DNA向植物细胞转移的效率.这种特性使得基因工程应用不可或缺,特别是在耐热植物物种中.还研究了丙烯的抗氧化剂和植物防御机制中的信号功能.它具有很高的纯度和稳定性,是实验室使用的可靠试剂,可以确保转化协议和植物化学研究产生可复制的结果.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号1136-86-3 3',4',5'-三甲氧基苯乙酮 | CAS号33900-62-8 4-(1-羟乙基)-2,6-二甲氧基苯酚 | CAS号944-99-0 2,6-二甲氧基苯乙酸酯 | CAS号871798-98-0 3,3'-dimethoxy-... | CAS号14059-92-8 4-乙基-2,6-二甲氧基苯酚 | CAS号39151-19-4 3,5-二甲氧基苯乙酮 | CAS号51149-28-1 2-bromo-1-(4-hy... | CAS号91-10-1 2,6-二甲氧基酚/紫丁香醇 | CAS号14059-92-8 4-乙基-2,6-二甲氧基苯酚 | CAS号2151-18-0 巴诺尔 | CAS号28294-47-5 4'-ACETOXY-3',5... | CAS号7404-35-5 6-脱氧-ALPHA-D-吡喃... | CAS号141243-24-5 3,5-Dimethoxy-4... | CAS号83-87-4 α,β-D-五乙酸葡萄糖 | CAS号86402-42-8 3,5-dimethoxy-4... | CAS号25878-60-8 1,2,3,4,6-D-葡萄糖五乙酸酯 | CAS号77439-76-0 3-氯-4-(二氯甲基)-5-...

合成工艺路线路线简述

  • 合成目标产物 Acetosyringone 主要起始原料 Phenol, 4-Ethenyl-2,6-Dimethoxy-
  • (文献来源)合成步骤主要原料 Phenol, 4-Ethenyl-2,6-Dimethoxy-
2,6-二甲氧基苯酚置于吡啶,三氯化铝,硝基苯,苯体系中,化学反应生成乙酰丁香酮
参考文献:木质素及相关化合物的研究;枫木的高压加氢.
标题:木质素及相关化合物的研究;枫木的高压加氢.
摘要:
Doi:10.1021/ja01181A021

海关参考信息

专利信息


专利号:US-10801033-B2
优先权日:2016-04-05
标题 :Recombinant polynucleotide involved in lactone synthesis and process for synthesis of lactones thereof
发明人:GUPTA VIDYA SHRIKANT; DESHPANDE ASHISH BALWANT; OAK PRANJALI SUDHIR; GIRI ASHOK PRABHAKAR
权利人:COUNCIL SCIENT IND RES
摘要:The present invention provides the polynucleotide encoding enzyme involved in lactone synthesis and a process for synthesis of lactones using said polynucleotides. The invention also provides recombinant plasmid expression vector comprising said polynucleotide sequence. The recombinant protein encoded by said polynucleotides leads to synthesis of lactones having flavour peculiar to Alphonso mangoes.

专利号:US-2024110196-A1
优先权日:2022-08-29
标题 :Use of multigene stacking method in synthesis of nervonic acid in brassica napus
发明人:LIU FANG; WANG PANDI; WU GANG; XIONG XIAOJUAN
权利人:OIL CROPS RES INSTITUTE CAAS
摘要:The present disclosure relates to use of a multigene stacking method in synthesis of nervonic acid in Brassica napus. The present disclosure provides a multigene co-expression plant vector, including an initial backbone of pBWA(V)BII and multiple exogenous gene expression cassettes. The present disclosure further provides two plant vectors applicable to genetic transformation, including a three-gene co-expression plant vector and a five-gene co-expression plant vector. In the present disclosure, after the three-gene co-expression plant vector and the five-gene co-expression plant vector are separately transferred into the Brassica napus, the nervonic acid (NA) with a high content is synthesized in the Brassica napus through multigene co-expression. An NA ratio can be significantly increased combined with a higher seed oil content and a greater field seed yield. The plant vector realizes efficient synthesis of NA in oil crops, obtains NA-rich seed oil, and increases an added value of edible oil.

专利号:WO-2025104067-A1
优先权日:2023-11-14
标题 :Use of a heterogeneous copper/zinc catalyst for continuous, gas-phase synthesis of methyl isobutyl ketone and/or methyl isobutyl carbinol by hydrogenation of mesityl oxide
发明人:RUPPIN CHRISTOPHE
权利人:ARKEMA FRANCE
摘要:The present invention relates to the use of a catalyst comprising a mixture of copper and zinc for continuous, gas-phase synthesis of methyl isobutyl ketone (MIBK) and/or methyl isobutyl carbinol (MIBC) from mesityl oxide. The invention also relates to a synthesis method comprising the following sequence of steps: continuous injection of the reagents in gas form through a reactor; hydrogenation reaction under pressure of hydrogen and at a temperature of between 120 and 250°C in the presence of the catalyst; condensation of the stream from the reactor and separation of the gas stream from the liquid stream; and purification of the liquid stream in order to separate the methyl isobutyl ketone and/or the methyl isobutyl carbinol.

专利号:US-8008005-B2
优先权日:2001-05-18
标题 :Method for the synthesis of DNA sequences
发明人:BELSHAW PETER J; SUSSMAN MICHAEL J; CERRINA FRANCESCO; FLICKINGER SHANE T
权利人:WISCONSIN ALUMNI RES FOUND
摘要:A method is disclosed for the direct synthesis of double stranded DNA molecules of a variety of sizes and with any desired sequence. The DNA molecule to be synthesis is logically broken up into smaller overlapping DNA segments. A maskless microarray synthesizer is used to make a DNA microarray on a substrate in which each element or feature of the array is populated by DNA of a one of the overlapping DNA segments. The DNA segments are released from the substrate and held under conditions favoring hybridization of DNA, under which conditions the segments will spontaneously hybridize together to form the desired DNA construct. This method makes possible the remote assembly of DNA sequence, through a process analogous to facsimile transmission of documents, since the information on DNA to be made can be transmitted remotely to an instrument which can then synthesize any needed DNA sequence from the information.

专利号:US-11466283-B2
优先权日:2016-08-18
标 题:Plants and methods for increasing and decreasing synthesis of cannabinoids
发明人:ROSCOW ROBERT F
权利人:CANOPY GROWTH CORP
摘要:This disclosure relates to new plants and methods for increasing and decreasing synthesis of cannabinoids. The plants disclosed herein comprise unnatural ratios and concentrations of cannabinoids in plants of genus Cannabis . The methods disclosed herein comprise manipulating the biosynthetic pathway of cannabinoids to produce plants of genus Cannabis with unnatural ratios and concentrations of cannabinoids.

专利号:US-12264143-B2
优先权日:2020-12-17
标 题:Synthesis of cannabinoids and cannabinoid precursors, and related compounds, formulations, and methods of use
发明人:SAMMIS GLENN M; ROGGEN MARKUS
权利人:NALU BIO INC
摘要:Methods are provided for the synthesis of cannabinoids, including cannabidiol (CBD), cannabinol (CBN), cannabichromene (CBC), cannabidiolic acid (CBDA), cannabigerol (CBG), cannabigerolic acid (CBGA), cannabidivarin (CBDV), cannabidibutol (CBD-C4), dihydrocannabidiol (DCBD), tetrahydrocannabivarin (THCV), analogs thereof, and precursors to the foregoing. One method employs phloroglucinol or a phloroglucinol analog as a starting material. The syntheses are stereospecific, efficient, selective, and cost-effective, with little or no potential for generation of THC ((−)-trans-Δ9-tetrahydro-cannabinol) or any other psychoactive side product. Telescoped syntheses are also provided, as are new cannabinoids, pharmaceutical formulations, and methods of use.
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主要参考文献


1: Negrel J, Javelle F, Wipf D. Detection of an O-methyltransferase synthesising acetosyringone in methyl jasmonate-treated tobacco cell-suspensions cultures. Phytochemistry. 2014 Mar;99:52-60. doi: 10.1016/j.phytochem.2013.12.013. Epub 2014 Jan 17. doi: 10.1590/S1415-475738420150026. Epub 2015 Nov 3.
3: Srinivasan R, Gothandam KM. Synergistic Action of D-Glucose and Acetosyringone on Agrobacterium Strains for Efficient Dunaliella Transformation. PLoS One. 2016 Jun 28;11(6):e0158322. doi: 10.1371/journal.pone.0158322. eCollection 2016.
4: Kim Y, Miyashita M, Miyagawa H. Early signaling events induced by the peptide elicitor PIP-1 necessary for acetosyringone accumulation in tobacco cells. Biosci Biotechnol Biochem. 2016 Jun;80(6):1054-7. doi: 10.1080/09168451.2016.1151342. Epub 2016 Feb 29. doi: 10.1002/elps.201600126. Epub 2016 Aug 2.

合成参考文献


参考文献:10.1007/s10529-010-0220-1
摘要:Zhang C, Zhao H, Liu Y, Li Q, Liu X, Tan H, Yuan C, Dong Y. Isolation and characterization of a novel glycogen synthase kinase-3 gene, GmGSK, in Glycine max L. that enhances abiotic stress tolerance in Saccharomyces cerevisiae. Biotechnol Lett. 2010 Jun;32(6):861–6. doi: 10.1007/s10529-010-0220-1.
参考文献:10.1371/journal.pone.0021622
摘要:Sarrion-Perdigones A, Falconi EE, Zandalinas SI, Juárez P, Fernández-del-Carmen A, Granell A, Orzaez D. GoldenBraid: An Iterative Cloning System for Standardized Assembly of Reusable Genetic Modules. PLoS ONE. 2011 Jul 07;6(7):e21622. doi: 10.1371/journal.pone.0021622.
参考文献:10.1016/j.plantsci.2011.05.011
摘要:Karthikeyan A, Pandian SK, Ramesh M. Agrobacterium-mediated transformation of leaf base derived callus tissues of popular indica rice (Oryza sativa L. sub sp. indica cv. ADT 43). Plant Sci. 2011 Sep;181(3):258–68. doi: 10.1016/j.plantsci.2011.05.011.
参考文献:10.1093/jxb/err209
摘要:Singh AP, Tripathi SK, Nath P, Sane AP. Petal abscission in rose is associated with the differential expression of two ethylene-responsive xyloglucan endotransglucosylase/hydrolase genes, RbXTH1 and RbXTH2. Journal of Experimental Botany. 2011 Jul 15;62(14):5091–103. doi: 10.1093/jxb/err209.
参考文献:10.1007/s11033-011-1200-9
摘要:Yang J, Liu S, Yang X, Zhang M. Chloroplast-located BjFer1 together with anti-oxidative genes alleviate hydrogen peroxide and hydroxyl radical injury in cytoplasmic male-sterile Brassica juncea. Molecular Biology Reports. 2011 Jul 20;39(4):4169–76. doi: 10.1007/s11033-011-1200-9.
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