CAS: 1586-73-8; Tris(Trimethylsilyl)Amine

该化合物是合成化学和材料科学中广泛使用的高度多用途有机硅化合物,其主要优点包括:具有很强的悬浮特性,能够有效解质和保护敏感功能群体;该化合物具有极佳的热稳定性和低核分裂性,在无水和无氧环境中是有益的;它是合成硅-硝基框架的前体,也是金属氨化物的制剂;其挥发性有利于净化过程,而与一系列溶剂的兼容性则增强了其在各种应用中的效用,包括催化和半导体制造.

结构式图片

相似化合物

15933-59-2 21331-86-2 1586-72-7

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

chloro-trimethyl-silane lithium hexamethyldisilazane bis(trimethylsilyl)carbodi-imide tetrahydrofuranN-(Difluorphosphoryl)bis(trimethyl)silylamin N'-tosyl-N-(trimethylsilyl)sulfur diimide N,N'-bis(trimethylsilyl)sulfurdiimide 1,1-diphenyl-2,2,2-trifluoroethanol

合成工艺路线路线简述

  • 合成目标产物 Nonamethyltrisilazane 主要起始原料 Chlorotrimethylsilane
  • (文献来源)合成步骤主要原料 Chlorotrimethylsilane
📜甲基三氯硅烷置于氯化氮,三(二甲胺基)膦体系中,用 乙醚,甲苯 用作溶剂,化学反应 0.5H,以40%的收率获得三(三甲基硅)胺
参考文献:Shaposhnikov,S. I.; Koidan,G. N.; Marchenko,A. P.,Journal Of General Chemistry Of The Ussr,1985,Vol. 55,# 5,P. 963-966
标题:Shaposhnikov,S. I.; Koidan,G. N.; Marchenko,A. P.,Journal Of General Chemistry Of The Ussr,1985,Vol. 55,# 5,P. 963-966

专利信息


专利号:US-7615169-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-7927516-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-9944532-B2
优先权日:2013-10-22
标 题 :Solid source and method for the synthesis of silicon-containing precursors for chemical vapor deposition
发明人:SCARLETE MIHAI; AKTIK CETIN
权利人:SOCPRA SCIENCE ET GENIE S E C; UNIV DE BISHOP; SOCPRA SCIENCE ET GENIE S E C
摘要:The present document described a solid source and a method for synthesis of silicon-containing precursors for chemical vapor deposition. The solid source comprises a solid polysilane; an energy coupling agent distributed in the solid polysilane; and hydrogen, mixed with the solid polysilane and the energy coupling agent distributed in the solid polysilane, in a necessary amount to satisfy a hydrogen deficiency during a hydrogenolysis reaction.

专利号:US-2025197431-A1
优先权日:2023-12-15
标 题:Methods and systems for forming a layer comprising silicon and composition and synthesis of silicon precursor
发明人:ROMERO PATRICIO EDUARDO; VERVUURT RENÉ HENRICUS JOZEF; DEZELAH CHARLES; PORE VILJAMI J
权利人:ASM IP HOLDING BV
摘要:Disclosed are methods and systems for forming a silicon-containing layer on a substrate. Further disclosed are composition and synthesis of silicon-containing precursor. The methods for forming a silicon-containing layer comprise executing a plurality of deposition cycles. A deposition cycle comprises a first precursor pulse that comprises exposing the substrate to a first precursor. The first precursor comprises a molecule comprising a P—Si bond. A deposition cycle further comprises a plasma pulse that comprises exposing the substrate to a plasma treatment. The plasma treatment comprises generating a plasma.

专利号:EP-0364340-B1
优先权日:1988-10-05
标题:Method for the synthesis of sulfonyl imides
摘要:Method for the synthesis of sulfonylimidides having the formula M((RSO2)2N)y, whrein M is a metal or an ammonium radical quaternary or not, the Rs, which may be identical or similar are organic monovalent radicals, particularly hydrocarbyles and preferably perfluorohydrocarbyles, in C1 to C12, and y is the valence of M. On the one hand, a silazane component selected amongst the silazane compounds M(((R2)3Si)2N)y or the associations of a silazane derivative A((R2)3Si)2N or a fluoride M1Fz of low cross-linking energy is reacted with, on the other hand, at least one sulfonic halogenite component consisting of a sulfonyl fluoride RSO2F or in the association of a sulfonyl chloride RSO2Cl with a fluoride M1Fz, M, R and y having the above-mentionned significations, M1 being selected amongst the Ms and being optionally identical to M, z being the valence of M1 and R2 representing an alkyl in C1 to C4. The imidides obtained for which the R2 are perfluorated radicals and M is an alkaline metal such as Li are usable in association with polyethers for the production of materials of the ionic conduction type for all solid generators in thin films.

专利号:US-5256821-A
优先权日:1988-10-05
标题:Method of synthesis of sulphonylimides
发明人:ARMAND MICHEL B
权利人:ELF AQUITAINE; HYDRO QUEBEC
摘要:Method for the synthesis of sulfonylimidides having the formula M((RSO 2 ) 2 N) y , wherein M is a metal or an ammonium radical quaternary or not, the Rs, which may be identical or similar are organic monovalent radicals, particularly hydrocarbyles and preferably perfluorohydrocarbyles, in C 1 to C 12 , and y is the valence of M. On the one hand, silazane component selected amongst the silazane compounds M(((R 2 ) 3 Si) 2 N) y or the associations of a silazane derivative A((R 2 ) 3 Si) 2 N or a fluoride M 1 F z of low cross-linking energy is reacted with, on the other hand, at least one sulfonic halogenite component consisting of a sulfonyl fluoride RSO 2 F or in the association of a sulfonyl chloride RSO 2 Cl with a fluoride M 1 F z , M, R and y having the above-mentioned significations, M being selected amongst the Ms and being optionally identical to M, z being the valence of M 1 and R 2 representing an alkyl in C 1 to C 4 . The imidides obtained for which the R 2 are perfluorated radicals and M is an alkaline metal such as Li are usable in association with polyethers for the production of materials of the ionic conduction type for all solid generators in thin films.

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合成参考文献


摘要:Regitz, M.; Bergsträßer, U., Science of Synthesis, (2001) 9, 145.
摘要:Prakash, G. K. S.; Hu, J., Science of Synthesis, (2005) 22, 624.
摘要:Kibayashi, C.; Yamazaki, N., Science of Synthesis, (2007) 30, 10.
摘要:Urgaonkar, S.; Verkade, J. G., Science of Synthesis, (2009) 42, 944.
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