CAS: 7768-28-7; 2-(2-Hydroxyethyl)Phenol

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2,3-二氢苯并呋喃置于双氧水,C18H26Br2N2Ni,Sodium Hydroxide,Zinc Dibromide,锌体系中,用 甲苯 作为反应溶剂,化学反应 24.0H,反应生成 邻羟基苯乙醇
参考文献:硼通过锌/镍串联催化插入烷基醚键中
标题:硼通过锌/镍串联催化插入烷基醚键中
摘要:轻度的在烷基醚中裂解碳-氧(c-O)键的方法可通过精心设计这些稳固且易于获得的前体来简化化学合成.在这里,我们报道二溴硼烷在镍催化剂和锌还原剂的存在下与烷基醚反应,从而将硼插入到c-O键中.随后的反应性可以影响环醚的氧-氮取代或一碳同系化,并更广泛地简化了生物活性化合物的制备.机理研究揭示了通过锌/镍串联催化的裂解-然后反弹的途径.
DOI:10.1126/science.Abg5526

专利信息

专利号:US-6717016-B2
优先权日:2002-01-31
标题:Phosphine compound, transition metal complex containing the same phosphine compound as ligand and asymmetric synthesis catalyst containing the complex
发明人：SHIMIZU HIDEO; SAITO TAKAO
权利人:TAKASAGO PERFUMERY CO LTD
摘要:A phosphine compound of formula (1) n and a phosphine compound of formula (2) n a transition metal complex having the phosphine compound as a ligand and a catalyst for asymmetric hydrogenation including the transition metal complex.

专利号:CN-109988213-A
优先权日:2017-12-29
标 题 :A kind of compound for polypeptide liquid phase synthesis carrier and preparation method and use thereof