CAS: 5994-61-6; 2,2'-((Phosphonomethyl)Azanediyl)Diacetic Acid

相似化合物

1071-83-6 2439-99-8 24569-83-3

上下游产品

CAS号31611-66-2 Ν,Ν-biscyanomet... | CAS号50-00-0 甲醛 | CAS号142-73-4 亚氨基二乙酸 | CAS号10294-56-1 亚磷酸 | CAS号1531623-12-7 N-hydroxymethyl... | CAS号77752-64-8 2-[4-(carboxyme... | CAS号110-88-3 三聚甲醛 | CAS号6290-05-7 亚氨基二乙酸二乙酯 | CAS号33454-80-7 2-[carboxymethy... | CAS号628-87-5 亚氨基二乙腈(IDAN) | CAS号64-18-6 甲酸 | CAS号1066-51-9 氨甲基膦酸 | CAS号35404-71-8 methylaminometh... | CAS号1071-83-6 草甘膦 | CAS号84767-96-4 N-Formyl-N-phos... | CAS号68-12-2 N,N-二甲基甲酰胺 | CAS号24569-83-3 草甘酸甲酯 | CAS号53792-63-5 N-(carboxymethy...

2-[(二(氰基甲基)氨基)甲基-(氰基甲基)氨基]乙腈 反应生成 双甘膦
参考文献:Hantz,Adam Andrei;Fenesan,Ioan;Mateicluc,Elena;Popeseu,Rodica;Salamon+
标题:Hantz,Adam Andrei;Fenesan,Ioan;Mateicluc,Elena;Popeseu,Rodica;Salamon+

专利信息

专利号:US-10364262-B2
优先权日:2012-07-17
标 题 :Method for the synthesis of N-phosphonomethyliminodiacetic acid
发明人：DEVAUX ALBERT; BURCK SEBASTIAN; NOTTE PATRICK
权利人:MONSANTO TECHNOLOGY LLC
摘要:A method for synthesis of N-phosphonoalkyliminodiacetic acid or derivatives thereof by forming a reaction mixture having an acid catalyst, a compound of the following general formula R1—CH2—NX—CH2—R2 and a compound having one or more P—O—P anhydride moieties to form a compound having a formula R1—CH2—N(—CH2PO3R32)(—CH2—R2) wherein in R1—CH2—NX—CH2—R2: X is —CH2—OH or —CH2—COOH; R1 and R2 are independently selected from the group consisting of nitrile, C1-C4 alkyl carboxylate, and carboxylic acid for when X is —CH2—OH, or R1 and R2 are both carbonyl groups linked by a hydrogen substituted nitrogen atom or a C1-C4-alkyl substituted nitrogen atom; and R3 is H, an alkyl group, or an aryl group; the anhydride moieties in the P—O—P anhydride compound have one P atom at the oxidation state (+III) and one P atom at the oxidation state (+III) or (+V); and 2) hydrolyzing the mixture to form N-phosphonomethyliminodiacetic acid or one of its derivatives.

专利号:US-10280189-B2
优先权日:2012-07-17
标题:Method for the synthesis of aminoalkylenephosphonic acid
发明人：BURCK SEBASTIAN; LECLERCQ CEDRIC NICOLAS; NOTTE PATRICK
权利人:MONSANTO TECHNOLOGY LLC
摘要:A method for the synthesis of an aminoalkylenephosphonic acid or its phosphonate esters including the following steps: a) forming, in the presence of an aldehyde or ketone and an acid catalyst, a reaction mixture by mixing a compound having at least one HNR 1 R 2 moiety or a salt thereof, with a compound having one or more P—O—P anhydride moieties, the moieties having one P atom at the oxidation state (+III) and one P atom at the oxidation state (+III) or (+V), wherein the ratio of moles of aldehyde or ketone to N—H moieties is 1 or more and wherein the ratio of N—H moieties to P—O—P anhydride moieties is 0.3 or more, and b) recovering the resulting aminoalkylenephosphonic acid having compound or its phosphonate esters.

专利号:US-10464958-B2
优先权日:2012-07-17
标题 :Method for the synthesis of alpha-aminoalkylenephosphonic acid
发明人：NOTTE PATRICK; COGELS SAMUEL; BURCK SEBASTIAN
权利人:MONSANTO TECHNOLOGY LLC
摘要:The present invention is related to a new method for the synthesis of alpha-aminoalkylenephosphonic acid or its phosphonate esters comprising the steps of forming a reaction mixture by mixing a P—O—P anhydride moiety comprising compound, having one P-atom at the oxidation state (+III) and the other P-atom at the oxidation state (+III) or (+V), an aminoalkanecarboxylic acid and an acid catalyst, wherein said reaction mixture comprises an equivalent ratio of alpha-aminoalkylene carboxylic acid to P—O—P anhydride moieties of at least 0.2, and recovering the resulting alpha-aminoalkylene phosphonic acid compound or an ester thereof from the reaction mixture.

专利号:US-9150599-B2
优先权日:2012-07-17
标 题 :Method for the synthesis of N-(phosphonomethyl)glycine
发明人：BURCK SEBASTIAN; NOTTE PATRICK
权利人:STRAITMARK HOLDING AG
摘要:A method for the synthesis of N-(phosphonomethyl) glycine or one of its derivatives selected from the group of its salts, its phosphonate esters and its phosphonate ester salts, including the steps of: a) forming a reaction mixture having an acid catalyst, N,N′-bis(carboxymethyl)-2,5-diketopiperazine and a compound having one or more P—O—P anhydride moieties, wherein the moieties have one P atom at the oxidation state (+III) and the other P atom at the oxidation state (+III) or (+V), to form N,N′-bis(phosphonomethyl)-2,5-diketopiperazine, its dehydrated forms or their phosphonate esters; b) hydrolyzing the reaction mixture to form N-(phosphonomethyl)glycine or one of its derivatives selected from the group consisting of its salts, its phosphonate esters and its phosphonate ester salts.

专利号:US-6118022-A
优先权日:1998-09-08
标 题 :Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
发明人：CULLEN BARRY A
权利人:HAMPSHIRE CHEMICAL CORP
摘要:A process for the preparation of phosphonomethylglycine in high yields is disclosed. In accordance with the process of the present invention, alkali metal IDA, such as disodium IDA, is reacted with a strong mineral acid, such as HCl, to convert the salt of IDA to IDA. The IDA is then converted to soluble IDA phosphite salt by the addition of phosphorous acid, and the alkali metal salt of the strong acid is precipitated. The phosphite salt of IDA is phosphonomethylated, such as by the addition of PCl3 and formaldehyde. Optionally, phosphorous trichloride can be hydrolyzed to provide the phosphorous acid source for phosphonomethylation of the phosphite salt.

专利号:US-6365772-B1
优先权日:1995-05-30
标题 :Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
发明人：CULLEN BARRY A; PARKER BRIAN A
权利人:HAMPSHIRE CHEMICAL CORP
摘要:A process for the preparation of phosphonomethylglycine in nearly quantitative yields which eliminates the use of a noble metal co-catalyst and its concomitant problems. The oxygen-containing gas is replaced with the much more chemically active hydrogen peroxide, which in combination with activated carbon, oxidizes the PMIDA to PMG in very high yield. The amount of oxidant allowed to react with PMIDA is a function of the concentration of oxygen in the gaseous reaction products, and is controlled by monitoring that concentration. In another embodiment, the oxidizing agent is an oxygen-containing gas. In either case, the concentration of oxygen in the gaseous reaction product is monitored to determine the end point of the reaction.