2,3-二氯-1-丙醇置于甲醇,Sodium Hydrogensulfide体系中,化学反应生成 2,3-二巯基-1-丙醇 参考文献:Ing,Journal Of The Chemical Society,1948,P. 1394 标题:Ing,Journal Of The Chemical Society,1948,P. 1394
专利号:US-9920160-B2 优先权日:2014-09-03 标题 :Method for synthesis of polymer containing multiple epoxy groups 发明人:GAO CHAO; ZHENG YAOCHEN; PENG LI; CAI SHENGYING; WENG ZHULIN 权利人:UNIV ZHEJIANG 摘要:A method for a synthesis of a polymer containing multiple epoxy groups includes steps of: under protection of nitrogen or argon, with a photosensitive free radical initiator under an ultraviolet light irradiation, initiating a mixture of a dithiol compound and alkynyl glycidyl ether or other alkynyl-containing compounds to proceed a thiol-yne polymerization, so as to obtain the polymer. The number of the epoxy groups is able to be adjusted through changing a type of a dithiol monomer, a mixing ratio of the dithiol monomer, and a mixing ratio between the alkynyl glycidyl ether and other alkynyl compounds. The present invention has advantages of: fast reaction, convenient process, easy post-processing, a large number of the epoxy groups, and adjustable and controllable content. The obtained polymer has a wide potential application in fields of coating, adhesive, ink, encapsulating material, resin for composite material, additive, high performance material, function material, and so on.
专利号:US-2024197774-A1 优先权日:2021-04-16 标 题:Synthesis of Antimicrobial PVP-coated Bismuth Nanoparticles 发明人:LOPEZ-RIBOT JOSE; VAZQUEZ-MUNOZ ROBERTO 权利人:UNIV TEXAS 摘要:Described herein is a facile, fast, and economical method for the synthesis of BAL-mediated PVP-BiNPs, using basic laboratory instruments and reagents readily available in most laboratories.
专利号:US-6281372-B1 优先权日:1999-02-26 标 题 :Process for synthesis of vinyl esters from butene oligomers 发明人:WIESE KLAUS-DIETHER; OLBRICH PAUL; GABRIEL JUERGEN 权利人:OXENO OLEFINCHEMIE GMBH 摘要:A process for the synthesis of vinyl esters from butene oligomers, wherein butenes are oligomerized, the butene oligomers are separated from the oligomerized mixture, the butene oligomers are converted to carboxylic acids which are longer by one carbon atom, and the resulting carboxylic acids are converted to the corresponding vinyl esters. The butene oligomers are in particular dibutene, tributene and tetrabutene. The invention also relates to the use of the vinyl esters as plasticizers or as comonomers in polymerization reactions.
专利号:WO-2025017286-A1 优先权日:2023-07-14 标 题 :Novel synthesis of colloidal quantum dot ink and applications in semiconductor devices 发明人:VASHISHTHA PARTH; HE XIN; MEHTA JOSHUA; LIU JUNPENG; VO CONG-DUAN 权利人:QUANTUM SCIENCE LTD 摘要:The present invention provides a method for producing a nanocrystal composition comprising an inorganic ligand via a one-pot synthesis. The present invention also provides nanocrystals comprising novel inorganic ligands and the use of these nanocrystals. The present invention further provides the use of the novel inorganic ligands in the preparation of nanocrystals.
专利号:US-4426542-A 优先权日:1981-04-22 标题 :Synthesis of plasticizer and detergent alcohols 发明人:BARKER GEORGE E; FORSTER DENIS 权利人:MONSANTO CO 摘要:A preparation of a plasticizer alcohol, consisting of predominantly 2-propylheptanol, from linear butenes is described in which oxo product of the butenes is aldoled to condense n-pentaldehyde therein with very little cross-aldolization followed by hydrogenation to obtain the 2-propylheptanol with very small 2-propyl-4-methyl hexanol content. The alcohol product as phthalate ester has excellent plasticizer properties. Also processes are described for converting other olefins to alcohols by oxo, aldol and hydrogenation reactions, with particular attention to converting hexenes obtained by propylene dimerization to C14 alcohols suitable for preparation of detergents.
专利号:US-8138272-B2 优先权日:2006-05-22 标 题:Preparation of polymer conjugates of therapeutic, agricultural, and food additive compounds 发明人:KONRADI ANDREI W; SMITH JENIFER L 权利人:KONRADI ANDREI W; SMITH JENIFER L; ELAN PHARM INC 摘要:This invention provides an improved synthesis of polymer conjugates of formula (I), n nof agricultural, therapeutic, and food additive compounds. In particular, a process is described for the preparation of conjugates by treating primary or secondary alcohol substituents of active compounds with polymeric nucleophiles using “Mitsunobuâ€? or related reaction conditions.
1: Tian R, Shi R. Dimercaprol is an acrolein scavenger that mitigates acrolein- mediated PC-12 cells toxicity and reduces acrolein in rat following spinal cord injury. J Neurochem. 2017 Jun;141(5):708-720. doi: 10.1111/jnc.14025. Epub 2017 May 3. 2: Mückter H, Liebl B, Reichl FX, Hunder G, Walther U, Fichtl B. Are we ready to replace dimercaprol (BAL) as an arsenic antidote? Hum Exp Toxicol. 1997 Aug;16(8):460-5. doi: 10.1177/096032719701600807. 1(6700):199-200. 3(3):76. 41(3):378-83. doi: 10.1067/mem.2003.72. 2(5816):748-9. doi: 10.1136/bmj.2.5816.748. 7: MONTUSCHI E. Mercuric chloride poisoning treated with dimercaprol. Br Med J. 1953 Sep 5;2(4835):545. doi: 10.1136/bmj.2.4835.545.
合成参考文献
摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#04985 摘要:Quarterly Journal of Pharmacy & Pharmacology., 21(364), 1948 摘要:Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie., 223(408), 1954 [] 摘要:Annales Pharmaceutiques Francaises., 5(172), 1947 摘要:Browning, E. Toxicity of Industrial Metals. 2nd ed. New York: Appleton-Century-Crofts, 1969., p. 315