- 英文名称(2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-Yl (4R,4As,6Ar,9S,11Ar,11Bs)-9-(((2S,3R,4S,5S,6R)-4,5-Dihydroxy-6-(Hydroxymethyl)-3-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)Tetrahydro-2H-Py
- 中文名称甜菊糖
- IUPAC名称(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl (4R,4aS,6aR,9S,11aR,11bS)-9-(((2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-3-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)tetrahydro-2H-pyran-2-yl)oxy)-4,11b-dimethyl-8-methylenetetradecahydro-6a,9-methanocyclohepta[a]naphthalene-4-carboxylate
- 其它别名Stevioside; Steviosin; Rebaudin; Unii-0Yon5Mxj9P; 0Yon5Mxj9P; Diterpene Glycoside; Stevibioside; (-)-Stevioside; Stevian 50
- CAS编号57817-89-7
- MFCD编号:MFCD00079561
- EINECS号:260-975-5
- FDA UNII编号:0YON5MXJ9P
- 分子式:C38H60O18
- 分子量:804.88
- 产品CID: 1553262
- 产品分类食品添加剂 → 甜味剂

物理性质
- 熔点198°C
- 沸点963.3±65.0 °C(预测)
- 闪点290.3 °C
- 密度1.53±0.1 g/cm3(预测)
- pKa:12.51±0.70(预测)
- PSA:294.98
- LogP:4.440 (est)
- 折射率-39.3 ° (C=6, H2O)
- 溶解性DMSO:可溶,25mg/mL,澄清
- 外观形态white powder
- 储存条件0-6 °C
- 产品应用该品有清凉甜味,甜度约为蔗糖的200-300倍.浓度高时略有苦味,甜味在口中不易消失.该品是天然甜味剂中最接近蔗糖的一种.作为抵热量食品甜味剂,兼有降备压作用.往往与柠檬酸钠并用,以改甜味.作为蔗糖的代糖剂,最大代用量不宜超过1/3,以免后味.按GB2760-86规定,可用于液体和固体饮料,糖果及糕点用量按正常生产需要.本品的缺点是分子量大,渗透性差.小鼠及大鼠经口毒性LD50>8.2g/kg.
- 性质描述白色至微黄色结晶性粉.熔点198°C.1g该品可溶于800ml水,微溶于乙醇.此旋光率[α]20/D为-39.3°(C=5.7,H2O).在空气中迅速汲湿.耐高温,在酸性及碱性溶液中比较稳定.
欧盟法规
C&L通报REACH预注册上下游产品
60H82O29C60H82O29 13-O-[3,4,6-tri-O-acetyl-β-D-glucopyranosyl(1-2α')-3',4',6'-tri-O-acetyl-β-D-glucopyranosyl]ent-caur-16-en-19-oic acid 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide UDP-glucoseisosteviol 37H58O19C37H58O19 steviolbioside steviol 13-O-[β-D-Heptaacetylsophorosyl]-Ent-Kauren-19-Oic Acid置于四丁基溴化铵,Sodium Methylate,三丁基氧化锡体系中,用 甲醇 作为反应溶剂,化学反应 83.0H,反应生成 甜菊糖
参考文献:甜菊糖的全合成
标题:甜菊糖的全合成
摘要:通过应用糖苷的立体选择方法将甜菊醇2转化为甜菊糖苷1.
DOI:10.1016/0040-4020(80)80136-0
专利信息
专利号:WO-2024042405-A1
优先权日:2022-08-26
标 题:Compositions and methods for the synthesis of bio-based polymers
发明人:OLIVEIRA ANA; CAPÊTO ANA PAULA; PINTADO MANUELA
权利人:AMYRIS BIO PRODUCTS PORTUGAL UNIPESSOAL LTDA; UNIV CATOLICA PORTUGUESA
摘要:The present disclosure provides compositions and methods for the synthesis of bio-based polymers (e.g., polyurethanes and polyesters) from secondary materials produced during a fermentation process. The disclosure also features intermediates produced during these processes, as well as compositions containing the same.
专利号:US-2017204442-A1
优先权日:2014-05-29
标题 :Enzymatic synthesis of soluble glucan fiber
发明人:DICOSIMO ROBERT; CHENG QIONG; ELIOT ANDREW C; OUWEHAND ARTHUR; PAYNE MARK S; YOU ZHENG
权利人:DU PONT
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:US-10907185-B2
优先权日:2014-05-29
标 题 :Enzymatic synthesis of soluble glucan fiber
发明人:CHENG QIONG; DICOSIMO ROBERT; OUWEHAND ARTHUR; YOU ZHENG; LAI JIAN PING; YU ZHEYONG; ZHANG ZHENGHONG
权利人:DUPONT IND BIOSCIENCES USA LLC
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:US-2017198323-A1
优先权日:2014-05-29
标题:Enzymatic synthesis of soluble glucan fiber
发明人:CHENG QIONG; DICOSIMO ROBERT; OUWEHAND ARTHUR; YOU ZHENG; PAYNE MARK S; PRASAD JAHNAVI CHANDRA
权利人:DU PONT
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:US-2017198322-A1
优先权日:2014-05-29
标题:Enzymatic synthesis of soluble glucan fiber
发明人:CHENG QIONG; DICOSIMO ROBERT; ELIOT ANDREW C; OUWEHAND ARTHUR; ROESCH BRIAN MICHAEL; ROTHMAN STEVEN CARY; RUEBLING-JASS KRISTIN; YOU ZHENG
权利人:DU PONT
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
专利号:US-12110347-B2
优先权日:2014-05-29
标 题:Enzymatic synthesis of soluble glucan fiber
发明人:CHENG QIONG; DICOSIMO ROBERT; OUWEHAND ARTHUR; YOU ZHENG; PAYNE MARK S; LAI JIAN PING; RUEBLING-JASS KRISTIN; ROTHMAN STEVEN CARY
权利人:NUTRITION & BIOSCIENCES USA 4 INC
摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.